Ackermann, Lutz

[["dc.bibliographiccitation.artnumber","15430"],["dc.bibliographiccitation.journal","Nature Communications"],["dc.bibliographiccitation.volume","8"],["dc.contributor.author","Li, Jie"],["dc.contributor.author","Korvorapun, Korkit"],["dc.contributor.author","De Sarkar, Suman"],["dc.contributor.author","Rogge, Torben"],["dc.contributor.author","Burns, David J."],["dc.contributor.author","Warratz, Svenja"],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2018-11-07T10:22:45Z"],["dc.date.available","2018-11-07T10:22:45Z"],["dc.date.issued","2017"],["dc.description.abstract","The full control of positional selectivity is of prime importance in C-H activation technology. Chelation assistance served as the stimulus for the development of a plethora of ortho-selective arene functionalizations. In sharp contrast, meta-selective C-H functionalizations continue to be scarce, with all ruthenium-catalysed transformations currently requiring difficult to remove or modify nitrogen-containing heterocycles. Herein, we describe a unifying concept to access a wealth of meta-decorated arenes by a unique arene ligand effect in proximity-induced ruthenium(II) C-H activation catalysis. The transformative nature of our strategy is mirrored by providing a step-economical entry to a range of meta-substituted arenes, including ketones, acids, amines and phenols-key structural motifs in crop protection, material sciences, medicinal chemistry and pharmaceutical industries."],["dc.identifier.doi","10.1038/ncomms15430"],["dc.identifier.isi","000402961800001"],["dc.identifier.pmid","28598411"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/14905"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/42331"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","PUB_WoS_Import"],["dc.publisher","Nature Publishing Group"],["dc.relation.issn","2041-1723"],["dc.rights.access","openAccess"],["dc.subject.ddc","540"],["dc.title","Ruthenium(II)-catalysed remote C-H alkylations as a versatile platform to meta-decorated arenes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1557"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","1560"],["dc.bibliographiccitation.volume","56"],["dc.contributor.author","Warratz, Svenja"],["dc.contributor.author","Burns, David J."],["dc.contributor.author","Zhu, Cuiju"],["dc.contributor.author","Korvorapun, Korkit"],["dc.contributor.author","Rogge, Torben"],["dc.contributor.author","Scholz, Julius"],["dc.contributor.author","Jooss, Christian"],["dc.contributor.author","Gelman, Dmitri"],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2018-11-07T10:27:57Z"],["dc.date.available","2018-11-07T10:27:57Z"],["dc.date.issued","2017"],["dc.description.abstract","Methods for positionally selective remote C-H functionalizations are in high demand. Herein, we disclose the first heterogeneous ruthenium catalyst for meta-selective C-H functionalizations, which enabled remote halogenations with excellent site selectivity and ample scope. The versatile heterogeneous Ru@SiO2 catalyst was broadly applicable and could be easily recovered and reused, which set the stage for the direct fluorescent labeling of purines. In contrast to palladium, rhodium, iridium, or cobalt complexes, solely the ruthenium catalysis manifold provided access to meta-halogenated purine derivatives, illustrating the unique power of ruthenium C-H activation catalysis."],["dc.identifier.doi","10.1002/anie.201609014"],["dc.identifier.isi","000394998300019"],["dc.identifier.pmid","28044396"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/43323"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","PUB_WoS_Import"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C01 Hydrid-Anordnungen für die Untersuchung photo-induzierter mehrstufiger katalytischer Prozesse"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.relation.orgunit","Institut für Materialphysik"],["dc.title","meta-C-H Bromination on Purine Bases by Heterogeneous Ruthenium Catalysis"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.subtype","original_ja"],["dspace.entity.type","Publication"]]