Würtele, Christian

[["dc.bibliographiccitation.firstpage","15271"],["dc.bibliographiccitation.issue","50"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","15275"],["dc.bibliographiccitation.volume","54"],["dc.contributor.author","Schiwek, Christoph"],["dc.contributor.author","Meiners, Jenni"],["dc.contributor.author","Foerster, Moritz"],["dc.contributor.author","Wuertele, Christian"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2018-11-07T09:47:37Z"],["dc.date.available","2018-11-07T09:47:37Z"],["dc.date.issued","2015"],["dc.description.abstract","The iridium dihydride [Ir(H)(2)(HPNP)](+) (PNP=N(CH2CH2PtBu2)(2)) reacts with O-2 to give the unusual, square-planar iridium(III) hydroxide [Ir(OH)(PNP)](+) and water. Regeneration of the dihydride with H-2 closes a quasi-catalytic synthetic oxygen-reduction reaction (ORR) cycle that can be run several times. Experimental and computational examinations are in agreement with an oxygenation mechanism via rate-limiting O-2 coordination followed by H-transfer at a single metal site, facilitated by the cooperating pincer ligand. Hence, the four electrons required for the ORR are stored within the two covalent M-H bonds of a mononuclear metal complex."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft [SCHN950/2]; COST action [CM1205]"],["dc.identifier.doi","10.1002/anie.201504369"],["dc.identifier.isi","000368057400052"],["dc.identifier.pmid","26511744"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/35152"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.title","Oxygen Reduction with a Bifunctional Iridium Dihydride Complex"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1782"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","1786"],["dc.bibliographiccitation.volume","55"],["dc.contributor.author","Schweizer, Julia I."],["dc.contributor.author","Scheibel, Markus G."],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Neumeyer, Felix"],["dc.contributor.author","Wuertele, Christian"],["dc.contributor.author","Kulminskaya, Natalia"],["dc.contributor.author","Linser, Rasmus"],["dc.contributor.author","Auner, Norbert"],["dc.contributor.author","Schneider, Sven"],["dc.contributor.author","Holthausen, Max C."],["dc.date.accessioned","2018-11-07T10:19:10Z"],["dc.date.available","2018-11-07T10:19:10Z"],["dc.date.issued","2016"],["dc.description.abstract","An experimental and theoretical study of the base-stabilized disilene 1 is reported, which forms at low temperatures in the disproportionation reaction of Si2Cl6 or neo-Si5Cl12 with equimolar amounts of NMe2Et. Single-crystal X-ray diffraction and quantum-chemical bonding analysis disclose an unprecedented structure in silicon chemistry featuring a dative Si -> Si single bond between two silylene moieties, Me2EtN -> SiCl2 -> Si(SiCl3)(2). The central ambiphilic SiCl2 group is linked by dative bonds to the amine donor and the bis(trichlorosilyl) silylene acceptor, which leads to push-pull stabilization. Based on experimental and theoretical examinations a formation mechanism is presented that involves an autocatalytic reaction of the intermediately formed anion Si(SiCl3)(3)(-) with neo-Si5Cl12 to yield 1."],["dc.identifier.doi","10.1002/anie.201510477"],["dc.identifier.isi","000369854000033"],["dc.identifier.pmid","26696311"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/41609"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.title","A Disilene Base Adduct with a Dative Si-Si Single Bond"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1054"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","Nature Chemistry"],["dc.bibliographiccitation.lastpage","1059"],["dc.bibliographiccitation.volume","12"],["dc.contributor.author","Sun, Jian"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Verplancke, Hendrik"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Hunger, David"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","van Slageren, Joris"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-04-14T08:24:29Z"],["dc.date.available","2021-04-14T08:24:29Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1038/s41557-020-0522-4"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17872"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/81300"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1755-4349"],["dc.relation.issn","1755-4330"],["dc.rights.access","openAccess"],["dc.subject.ddc","540"],["dc.title","A platinum(ii) metallonitrene with a triplet ground state"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","614"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","Nature Chemistry"],["dc.bibliographiccitation.lastpage","614"],["dc.bibliographiccitation.volume","13"],["dc.contributor.author","Sun, Jian"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Verplancke, Hendrik"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Hunger, David"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","van Slageren, Joris"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-06-01T10:50:39Z"],["dc.date.available","2021-06-01T10:50:39Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1038/s41557-020-00613-x"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/86740"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.relation.eissn","1755-4349"],["dc.relation.issn","1755-4330"],["dc.title","Publisher Correction: A platinum(ii) metallonitrene with a triplet ground state"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","10971"],["dc.bibliographiccitation.issue","32"],["dc.bibliographiccitation.journal","Angewandte Chemie. International Edition"],["dc.bibliographiccitation.lastpage","10974"],["dc.bibliographiccitation.volume","58"],["dc.contributor.author","Delony, Daniel"],["dc.contributor.author","Kinauer, Markus"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2020-12-10T14:05:38Z"],["dc.date.available","2020-12-10T14:05:38Z"],["dc.date.issued","2019"],["dc.identifier.doi","10.1002/anie.201905325"],["dc.identifier.eissn","1521-3773"],["dc.identifier.issn","1433-7851"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17097"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/69603"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.title","A Terminal Iridium Oxo Complex with a Triplet Ground State"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4325"],["dc.bibliographiccitation.issue","18"],["dc.bibliographiccitation.journal","Chemical Science"],["dc.bibliographiccitation.lastpage","4332"],["dc.bibliographiccitation.volume","9"],["dc.contributor.author","Kinauer, Markus"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Bamberger, Heiko"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Reijerse, Edward J."],["dc.contributor.author","Volkmann, Christian"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","van Slageren, Joris"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Schneider, Sven"],["dc.contributor.author","Holthausen, Max C."],["dc.date.accessioned","2021-06-01T10:50:50Z"],["dc.date.available","2021-06-01T10:50:50Z"],["dc.date.issued","2018"],["dc.description.abstract","An iridium( iii – v ) imido series has been isolated that features an iridium complex with an unprecedented triplet ground state."],["dc.description.abstract","The iridium( iii / iv / v ) imido redox series [Ir(N t Bu){N(CHCHP t Bu 2 ) 2 }] 0/+/2+ was synthesized and examined spectroscopically, magnetically, crystallographically and computationally. The monocationic iridium( iv ) imide exhibits an electronic doublet ground state with considerable ‘imidyl’ character as a result of covalent Ir–N t Bu bonding. Reduction gives the neutral imide [Ir(N t Bu){N(CHCHP t Bu 2 ) 2 }] as the first example of an iridium complex with a triplet ground state. Its reactivity with respect to nitrene transfer to selected electrophiles (CO 2 ) and nucleophiles (PMe 3 ), respectively, is reported."],["dc.identifier.doi","10.1039/C8SC01113C"],["dc.identifier.eissn","2041-6539"],["dc.identifier.issn","2041-6520"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/86803"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.relation.eissn","2041-6539"],["dc.relation.issn","2041-6520"],["dc.title","An iridium( iii / iv / v ) redox series featuring a terminal imido complex with triplet ground state"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","10966"],["dc.bibliographiccitation.issue","32"],["dc.bibliographiccitation.journal","Angewandte Chemie. International Edition"],["dc.bibliographiccitation.lastpage","10970"],["dc.bibliographiccitation.volume","58"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Hinz, Alexander"],["dc.contributor.author","Alig, Lukas"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Goicoechea, Jose M."],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2020-12-10T14:05:38Z"],["dc.date.available","2020-12-10T14:05:38Z"],["dc.date.issued","2019"],["dc.identifier.doi","10.1002/anie.201905130"],["dc.identifier.eissn","1521-3773"],["dc.identifier.issn","1433-7851"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17098"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/69602"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.title","Oxidative Coupling of Terminal Rhenium Pnictide Complexes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]