Würtele, Christian

[["dc.bibliographiccitation.firstpage","4325"],["dc.bibliographiccitation.issue","18"],["dc.bibliographiccitation.journal","Chemical Science"],["dc.bibliographiccitation.lastpage","4332"],["dc.bibliographiccitation.volume","9"],["dc.contributor.author","Kinauer, Markus"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Bamberger, Heiko"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Reijerse, Edward J."],["dc.contributor.author","Volkmann, Christian"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","van Slageren, Joris"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Schneider, Sven"],["dc.contributor.author","Holthausen, Max C."],["dc.date.accessioned","2021-06-01T10:50:50Z"],["dc.date.available","2021-06-01T10:50:50Z"],["dc.date.issued","2018"],["dc.description.abstract","An iridium( iii – v ) imido series has been isolated that features an iridium complex with an unprecedented triplet ground state."],["dc.description.abstract","The iridium( iii / iv / v ) imido redox series [Ir(N t Bu){N(CHCHP t Bu 2 ) 2 }] 0/+/2+ was synthesized and examined spectroscopically, magnetically, crystallographically and computationally. The monocationic iridium( iv ) imide exhibits an electronic doublet ground state with considerable ‘imidyl’ character as a result of covalent Ir–N t Bu bonding. Reduction gives the neutral imide [Ir(N t Bu){N(CHCHP t Bu 2 ) 2 }] as the first example of an iridium complex with a triplet ground state. Its reactivity with respect to nitrene transfer to selected electrophiles (CO 2 ) and nucleophiles (PMe 3 ), respectively, is reported."],["dc.identifier.doi","10.1039/C8SC01113C"],["dc.identifier.eissn","2041-6539"],["dc.identifier.issn","2041-6520"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/86803"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.relation.eissn","2041-6539"],["dc.relation.issn","2041-6520"],["dc.title","An iridium( iii / iv / v ) redox series featuring a terminal imido complex with triplet ground state"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]