Würtele, Christian

[["dc.bibliographiccitation.firstpage","51"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Zeitschrift für Hochschulentwicklung"],["dc.bibliographiccitation.lastpage","59"],["dc.bibliographiccitation.volume","7"],["dc.contributor.author","Blank, Jennifer"],["dc.contributor.author","Waitz, Thomas"],["dc.contributor.author","Würtele, Christian"],["dc.date.accessioned","2019-07-10T08:14:06Z"],["dc.date.available","2019-07-10T08:14:06Z"],["dc.date.issued","2012"],["dc.description.abstract","Seit Beginn des Bologna-Prozesses werden noch immer Modulpläne in verschiedenen universitären Fächern neu strukturiert und weiterentwickelt. Im Master-Studiengang Chemie an der Justus-Liebig-Universität Gießen wurde so das Projekt zum kompetenzorientierten Lernen durch Lehren in der Bioanorganik als neues Lehrformat etabliert. Die Lehrveranstaltung wurde erstmals im Sommersemester 2010 durchgeführt und bereits 2011 mit dem Hessischen Hochschulpreis für Exzellenz in der Lehre ausgezeichnet. Das besondere Merkmal des Projekts ist die Ausrichtung eines bioanorganischen Schülersymposiums, das eigenverantwortlich von den Studierenden des 2. Semesters im Master-Studiengang Chemie organisiert und durchgeführt wird. Zu diesem Symposium werden Leistungskurse Chemie und Biologie eingeladen. Durch das Prinzip des „shift from teaching to learning“ wird eine kooperative und konstruktive Auseinandersetzung mit den fachlichen Inhalten gewährleistet."],["dc.identifier.fs","593304"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/9518"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/61435"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","CC BY-NC-ND 3.0"],["dc.rights.uri","http://creativecommons.org/licenses/by-nc-nd/3.0"],["dc.subject.ddc","540"],["dc.title","Das „bioanorganische Schülersymposium“: Lernen durch Lehren an der Hochschule"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","5511"],["dc.bibliographiccitation.issue","40"],["dc.bibliographiccitation.journal","Chemical Communications"],["dc.bibliographiccitation.lastpage","5514"],["dc.bibliographiccitation.volume","53"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Bete, Sarah C."],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Volkmann, Christian"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2018-08-17T09:33:43Z"],["dc.date.accessioned","2021-10-27T13:12:42Z"],["dc.date.available","2018-08-17T09:33:43Z"],["dc.date.available","2021-10-27T13:12:42Z"],["dc.date.issued","2017"],["dc.description.abstract","Reduction of the pincer complex [OsIIICl2(PNP)] (PNP = N(CHCHPtBu2)2) affords the isolation and full characterization of an osmium(II) complex with square-planar coordination geometry, i.e. [OsIICl(PNP)]. Spectroscopic, structural and magnetic data in combination with multireference computations indicate strong temperature independent paramagnetism, which arises from an energetically well separated ground state that mixes with excited states through spin-orbit coupling."],["dc.identifier.doi","10.1039/C7CC01569K"],["dc.identifier.isi","000401602900006"],["dc.identifier.pmid","28405639"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/15307"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91714"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.notes.intern","In goescholar not merged with http://resolver.sub.uni-goettingen.de/purl?gs-1/15078 but duplicate"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.relation.eissn","1364-548X"],["dc.relation.issn","1359-7345"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","Complex; Square-Planar; Osmium(II)"],["dc.subject.ddc","540"],["dc.title","A Square-Planar Osmium(II) Complex"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","11417"],["dc.bibliographiccitation.issue","38"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","11420"],["dc.bibliographiccitation.volume","55"],["dc.contributor.author","Schendzielorz, Florian S."],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Volkmann, Christian"],["dc.contributor.author","Wuertele, Christian"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2018-11-07T10:08:36Z"],["dc.date.available","2018-11-07T10:08:36Z"],["dc.date.issued","2016"],["dc.description.abstract","Low-valent osmium nitrides are discussed as intermediates in nitrogen fixation schemes. However, rational synthetic routes that lead to isolable examples are currently unknown. Here, the synthesis of the square-planar osmium(IV) nitride [OsN(PNP)] (PNP=N(CH2CH2P(tBu)(2))(2)) is reported upon reversible deprotonation of osmium(VI) hydride [Os(N)H(PNP)](+). The Os-IV complex shows ambiphilic nitride reactivity with SiMe3Br and PMe3, respectively. Importantly, the hydrogenolysis with H-2 gives ammonia and the polyhydride complex [OsH4(HPNP)] in 80% yield. Hence, our results directly demonstrate the role of low-valent osmium nitrides and of heterolytic H-2 activation for ammonia synthesis with H-2 under basic conditions."],["dc.description.sponsorship","European Research Council (ERC) [646747]"],["dc.identifier.doi","10.1002/anie.201604917"],["dc.identifier.isi","000383748900015"],["dc.identifier.pmid","27529412"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/14023"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/39493"],["dc.notes.intern","Merged from goescholar"],["dc.notes.intern","In goescholar not merged with http://resolver.sub.uni-goettingen.de/purl?gs-1/15305 but duplicate"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","A Terminal Osmium(IV) Nitride: Ammonia Formation and Ambiphilic Reactivity"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","802"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","811"],["dc.bibliographiccitation.volume","37"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Bete, Sarah C."],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Volkmann, Christian"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2019-07-09T11:51:20Z"],["dc.date.available","2019-07-09T11:51:20Z"],["dc.date.issued","2017"],["dc.identifier.doi","10.1021/acs.organomet.7b00707"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16106"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/59928"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Four- and Five-Coordinate Osmium(IV) Nitrides and Imides: Circumventing the “Nitrido Wall”"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1054"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","Nature Chemistry"],["dc.bibliographiccitation.lastpage","1059"],["dc.bibliographiccitation.volume","12"],["dc.contributor.author","Sun, Jian"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Verplancke, Hendrik"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Hunger, David"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","van Slageren, Joris"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-04-14T08:24:29Z"],["dc.date.available","2021-04-14T08:24:29Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1038/s41557-020-0522-4"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17872"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/81300"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1755-4349"],["dc.relation.issn","1755-4330"],["dc.rights.access","openAccess"],["dc.subject.ddc","540"],["dc.title","A platinum(ii) metallonitrene with a triplet ground state"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","14482"],["dc.bibliographiccitation.issue","44"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","14487"],["dc.bibliographiccitation.volume","57"],["dc.contributor.author","Schneck, Felix"],["dc.contributor.author","Schendzielorz, Florian S."],["dc.contributor.author","Hatami, Nareh"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2019-07-09T11:51:20Z"],["dc.date.available","2019-07-09T11:51:20Z"],["dc.date.issued","2018"],["dc.identifier.doi","10.1002/anie.201803396"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16108"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/59930"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C07 Kontrolle Reaktivität hydridischer Photokatalysatoren"],["dc.relation.issn","1433-7851"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Photochemically Driven Reverse Water-Gas Shift at Ambient Conditions mediated by a Nickel Pincer Complex"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.subtype","original_ja"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","6338"],["dc.bibliographiccitation.issue","19"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","6341"],["dc.bibliographiccitation.volume","58"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Delony, Daniel"],["dc.contributor.author","Neben, Marc C."],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2019-07-09T11:51:54Z"],["dc.date.available","2019-07-09T11:51:54Z"],["dc.date.issued","2019"],["dc.description.abstract","The isolable complex [Os(PHMes )H(PNP)] (Mes =2,4,6-t Bu3 C6 H3 ; PNP=N{CHCHPt Bu2 }2 ) exhibits high phosphinyl radical character. This compound offers access to the phosphinidene complex [Os(PMes )H(PNP)] by P-H proton coupled electron transfer (PCET). The P-H bond dissociation energy (BDE) was determined by isothermal titration calorimetry and supporting DFT computations. The phosphinidene product exhibits electrophilic reactivity as demonstrated by intramolecular C-H activation."],["dc.identifier.doi","10.1002/anie.201901470"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16225"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60037"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.relation.issn","1433-7851"],["dc.rights","CC BY-NC-ND 4.0"],["dc.rights.uri","https://creativecommons.org/licenses/by-nc-nd/4.0"],["dc.subject.ddc","540"],["dc.title","Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","830"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","834"],["dc.bibliographiccitation.volume","58"],["dc.contributor.author","Schendzielorz, Florian"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Krewald, Vera"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2020-01-14T13:35:36Z"],["dc.date.accessioned","2021-10-27T13:12:51Z"],["dc.date.available","2020-01-14T13:35:36Z"],["dc.date.available","2021-10-27T13:12:51Z"],["dc.date.issued","2018"],["dc.identifier.doi","10.1002/anie.201812125"],["dc.identifier.doi","10.1002/ange.201812125"],["dc.identifier.eissn","1521-3773"],["dc.identifier.issn","1433-7851"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17095"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91728"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.relation.issn","1433-7851"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","N2FEED"],["dc.subject.ddc","540"],["dc.title","Metal-Ligand Cooperative Synthesis of Benzonitrile by Electrochemical Reduction and Photolytic Splitting of Dinitrogen"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.artnumber","1161"],["dc.bibliographiccitation.firstpage","1"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Nature Communications"],["dc.bibliographiccitation.lastpage","8"],["dc.bibliographiccitation.volume","9"],["dc.contributor.author","Schneck, Felix"],["dc.contributor.author","Ahrens, Jennifer"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Stückl, Andrea Claudia"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Schwarzer, Dirk"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2019-07-09T11:45:18Z"],["dc.date.available","2019-07-09T11:45:18Z"],["dc.date.issued","2018"],["dc.description.abstract","Direct hydrogenation of CO2 to CO, the reverse water-gas shift reaction, is an attractive route to CO2 utilization. However, the use of molecular catalysts is impeded by the general reactivity of metal hydrides with CO2. Insertion into M-H bonds results in formates (MO(O)CH), whereas the abnormal insertion to the hydroxycarbonyl isomer (MC(O)OH), which is the key intermediate for CO-selective catalysis, has never been directly observed. We here report that the selectivity of CO2 insertion into a Ni-H bond can be inverted from normal to abnormal insertion upon switching from thermal to photochemical conditions. Mechanistic examination for abnormal insertion indicates photochemical N-H reductive elimination as the pivotal step that leads to an umpolung of the hydride ligand. This study conceptually introduces metal-ligand cooperation for selectivity control in photochemical transformations."],["dc.identifier.doi","10.1038/s41467-018-03239-3"],["dc.identifier.pmid","29563551"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/15100"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/59204"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C07 Kontrolle Reaktivität hydridischer Photokatalysatoren"],["dc.relation.issn","2041-1723"],["dc.rights","CC BY 4.0"],["dc.rights.uri","https://creativecommons.org/licenses/by/4.0"],["dc.subject.ddc","540"],["dc.title","The elusive abnormal CO2 insertion enabled by metal-ligand cooperative photochemical selectivity inversion"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.subtype","original_ja"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4786"],["dc.bibliographiccitation.issue","15"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","4789"],["dc.bibliographiccitation.volume","55"],["dc.contributor.author","Klopsch, Isabel"],["dc.contributor.author","Kinauer, Markus"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Wuertele, Christian"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2018-11-07T10:15:40Z"],["dc.date.available","2018-11-07T10:15:40Z"],["dc.date.issued","2016"],["dc.description.abstract","About 20% of the ammonia production is used as the chemical feedstock for nitrogen-containing chemicals. However, while synthetic nitrogen fixation at ambient conditions has had some groundbreaking contributions in recent years, progress for the direct conversion of N-2 into organic products remains limited and catalytic reactions are unknown. Herein, the rhenium-mediated synthesis of acetonitrile using dinitrogen and ethyl triflate is presented. A synthetic cycle in three reaction steps with high individual isolated yields and recovery of the rhenium pincer starting complex is shown. The cycle comprises alkylation of a nitride that arises from N-2 splitting and subsequent imido ligand centered oxidation to nitrile via a 1-azavinylidene (ketimido) intermediate. Different synthetic strategies for intra- and intermolecular imido ligand oxidation and associated metal reduction were evaluated that rely on simple proton, electron, and hydrogen-atom transfer steps."],["dc.description.sponsorship","European Research Council (ERC) [646747]"],["dc.identifier.doi","10.1002/anie.201600790"],["dc.identifier.isi","000373615900030"],["dc.identifier.pmid","26948973"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/14025"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/40853"],["dc.notes.intern","Merged from goescholar"],["dc.notes.intern","In goescholar not merged with http://resolver.sub.uni-goettingen.de/purl?gs-1/15304 but duplicate"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Conversion of Dinitrogen into Acetonitrile under Ambient Conditions"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]