Müller, Peter

[["dc.bibliographiccitation.artnumber","PII S0022-328X(01)01451-6"],["dc.bibliographiccitation.firstpage","25"],["dc.bibliographiccitation.issue","1-2"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","42"],["dc.bibliographiccitation.volume","649"],["dc.contributor.author","Belzner, Johannes"],["dc.contributor.author","Dehnert, Uwe"],["dc.contributor.author","Schär, Dirk"],["dc.contributor.author","Rohde, Bernhard"],["dc.contributor.author","Müller, Peter"],["dc.contributor.author","Usón, Isabel"],["dc.date.accessioned","2018-11-07T10:30:37Z"],["dc.date.available","2018-11-07T10:30:37Z"],["dc.date.issued","2002"],["dc.description.abstract","Silylenes 2 or 4, generated by thermolysis of cyclotrisilanes 1 and 3, were inserted into the Si-Cl or Si-H bonds of monosilanes to yield a variety of disilanes. which can be further functionalized subsequently. In a few cases, trisilanes are accessible by the reaction of I with disilanes. The reaction of a metalated silane with a chlorosilane is an alternative method for the formation of Si-Si bonds, which turned out to be especially useful for the synthesis of bulkily substituted disilanes. Some of the new dichlorodiand trisilanes themselves serve as thermal precursors of silylenes 2 or 4, the extrusion of which can be catalyzed by 1 or 3 in certain cases. (C) 2002 Elsevier Science B.V. All rights reserved."],["dc.identifier.doi","10.1016/S0022-328X(01)01451-6"],["dc.identifier.isi","000175170600005"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/43907"],["dc.language.iso","en"],["dc.notes.status","final"],["dc.notes.submitter","Najko"],["dc.relation.issn","0022-328X"],["dc.title","Synthesis of di- and trisilanes with potentially chelating substituents"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]