Reutzel, Marcel

[["dc.bibliographiccitation.firstpage","344004"],["dc.bibliographiccitation.issue","34"],["dc.bibliographiccitation.journal","Journal of Physics. Condensed Matter"],["dc.bibliographiccitation.volume","33"],["dc.contributor.affiliation","Adamkiewicz, A;"],["dc.contributor.affiliation","Bohamud, T;"],["dc.contributor.affiliation","Reutzel, M;"],["dc.contributor.affiliation","Höfer, U;"],["dc.contributor.affiliation","Dürr, M;"],["dc.contributor.author","Adamkiewicz, A"],["dc.contributor.author","Bohamud, T"],["dc.contributor.author","Höfer, U"],["dc.contributor.author","Dürr, M"],["dc.contributor.author","Reutzel, M"],["dc.date.accessioned","2021-08-12T07:45:11Z"],["dc.date.available","2021-08-12T07:45:11Z"],["dc.date.issued","2021"],["dc.date.updated","2022-02-09T13:18:46Z"],["dc.description.abstract","AbstractAtomic-scale chemical modification of surface-adsorbed ethyl groups on Si(001) was induced and studied by means of scanning tunneling microscopy. Tunneling at sample bias >+1.5 V leads to tip-induced C–H cleavage of a β-hydrogen of the covalently bound ethyl configuration. The reaction is characterized by the formation of an additional Si–H and a Si–C bond. The reaction probability shows a linear dependence on the tunneling current at 300 K; the reaction is largely suppressed at 50 K. The observed tip-induced surface reaction at room temperature is thus attributed to a one-electron excitation in combination with thermal activation."],["dc.description.sponsorship","Deutsche Forschungsgemeinschafthttps://doi.org/10.13039/501100001659"],["dc.identifier.doi","10.1088/1361-648X/ac0a1c"],["dc.identifier.eissn","1361-648X"],["dc.identifier.issn","0953-8984"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/88391"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-448"],["dc.publisher","IOP Publishing"],["dc.relation.eissn","1361-648X"],["dc.relation.issn","0953-8984"],["dc.rights.uri","https://creativecommons.org/licenses/by/4.0/"],["dc.title","Tip-induced β -hydrogen dissociation in an alkyl group bound on Si(001)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]