Rogge, Torben

[["dc.bibliographiccitation.firstpage","18795"],["dc.bibliographiccitation.issue","42"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","18803"],["dc.bibliographiccitation.volume","59"],["dc.contributor.author","Korvorapun, Korkit"],["dc.contributor.author","Moselage, Marc"],["dc.contributor.author","Struwe, Julia"],["dc.contributor.author","Rogge, Torben"],["dc.contributor.author","Messinis, Antonis M."],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2021-04-14T08:24:58Z"],["dc.date.available","2021-04-14T08:24:58Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1002/anie.202007144"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/81478"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.title","Regiodivergent C−H and Decarboxylative C−C Alkylation by Ruthenium Catalysis: ortho versus meta Position‐Selectivity"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.artnumber","15430"],["dc.bibliographiccitation.journal","Nature Communications"],["dc.bibliographiccitation.volume","8"],["dc.contributor.author","Li, Jie"],["dc.contributor.author","Korvorapun, Korkit"],["dc.contributor.author","De Sarkar, Suman"],["dc.contributor.author","Rogge, Torben"],["dc.contributor.author","Burns, David J."],["dc.contributor.author","Warratz, Svenja"],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2018-11-07T10:22:45Z"],["dc.date.available","2018-11-07T10:22:45Z"],["dc.date.issued","2017"],["dc.description.abstract","The full control of positional selectivity is of prime importance in C-H activation technology. Chelation assistance served as the stimulus for the development of a plethora of ortho-selective arene functionalizations. In sharp contrast, meta-selective C-H functionalizations continue to be scarce, with all ruthenium-catalysed transformations currently requiring difficult to remove or modify nitrogen-containing heterocycles. Herein, we describe a unifying concept to access a wealth of meta-decorated arenes by a unique arene ligand effect in proximity-induced ruthenium(II) C-H activation catalysis. The transformative nature of our strategy is mirrored by providing a step-economical entry to a range of meta-substituted arenes, including ketones, acids, amines and phenols-key structural motifs in crop protection, material sciences, medicinal chemistry and pharmaceutical industries."],["dc.identifier.doi","10.1038/ncomms15430"],["dc.identifier.isi","000402961800001"],["dc.identifier.pmid","28598411"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/14905"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/42331"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","PUB_WoS_Import"],["dc.publisher","Nature Publishing Group"],["dc.relation.issn","2041-1723"],["dc.rights.access","openAccess"],["dc.subject.ddc","540"],["dc.title","Ruthenium(II)-catalysed remote C-H alkylations as a versatile platform to meta-decorated arenes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1557"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","1560"],["dc.bibliographiccitation.volume","56"],["dc.contributor.author","Warratz, Svenja"],["dc.contributor.author","Burns, David J."],["dc.contributor.author","Zhu, Cuiju"],["dc.contributor.author","Korvorapun, Korkit"],["dc.contributor.author","Rogge, Torben"],["dc.contributor.author","Scholz, Julius"],["dc.contributor.author","Jooss, Christian"],["dc.contributor.author","Gelman, Dmitri"],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2018-11-07T10:27:57Z"],["dc.date.available","2018-11-07T10:27:57Z"],["dc.date.issued","2017"],["dc.description.abstract","Methods for positionally selective remote C-H functionalizations are in high demand. Herein, we disclose the first heterogeneous ruthenium catalyst for meta-selective C-H functionalizations, which enabled remote halogenations with excellent site selectivity and ample scope. The versatile heterogeneous Ru@SiO2 catalyst was broadly applicable and could be easily recovered and reused, which set the stage for the direct fluorescent labeling of purines. In contrast to palladium, rhodium, iridium, or cobalt complexes, solely the ruthenium catalysis manifold provided access to meta-halogenated purine derivatives, illustrating the unique power of ruthenium C-H activation catalysis."],["dc.identifier.doi","10.1002/anie.201609014"],["dc.identifier.isi","000394998300019"],["dc.identifier.pmid","28044396"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/43323"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","PUB_WoS_Import"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C01 Hydrid-Anordnungen für die Untersuchung photo-induzierter mehrstufiger katalytischer Prozesse"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.relation.orgunit","Institut für Materialphysik"],["dc.title","meta-C-H Bromination on Purine Bases by Heterogeneous Ruthenium Catalysis"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.subtype","original_ja"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.journal","Synthesis"],["dc.contributor.author","Korvorapun, Korkit"],["dc.contributor.author","Samanta, Ramesh C."],["dc.contributor.author","Rogge, Torben"],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2021-06-01T09:41:48Z"],["dc.date.available","2021-06-01T09:41:48Z"],["dc.date.issued","2021"],["dc.description.abstract","Abstract Synthetic transformations of otherwise inert C–H bonds have emerged as a powerful tool for molecular modifications during the last decades, with broad applications towards pharmaceuticals, material sciences, and crop protection. Consistently, a key challenge in C–H activation chemistry is the full control of site-selectivity. In addition to substrate control through steric hindrance or kinetic acidity of C–H bonds, one important approach for the site-selective C–H transformation of arenes is the use of chelation-assistance through directing groups, therefore leading to proximity-induced ortho-C–H metalation. In contrast, more challenging remote C–H activations at the meta- or para-positions continue to be scarce. Within this review, we demonstrate the distinct character of ruthenium catalysis for remote C–H activations until March 2021, highlighting among others late-stage modifications of bio-relevant molecules. Moreover, we discuss important mechanistic insights by experiments and computation, illustrating the key importance of carboxylate-assisted C–H activation with ruthenium(II) complexes. 1 Introduction 2 Stoichiometric Remote C–H Functionalizations 3 meta-C–H Functionalizations 4 para-C–H Functionalizations 5 meta-/ortho-C–H Difunctionalizations 6 Conclusions"],["dc.identifier.doi","10.1055/a-1485-5156"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/85047"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.relation.eissn","1437-210X"],["dc.relation.issn","0039-7881"],["dc.title","Remote C–H Functionalizations by Ruthenium Catalysis"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","886"],["dc.bibliographiccitation.issue","2"],["dc.bibliographiccitation.journal","ACS Catalysis"],["dc.bibliographiccitation.lastpage","892"],["dc.bibliographiccitation.volume","8"],["dc.contributor.author","Korvorapun, Korkit"],["dc.contributor.author","Kaplaneris, Nikolaos"],["dc.contributor.author","Rogge, Torben"],["dc.contributor.author","Warratz, Svenja"],["dc.contributor.author","Stückl, A. Claudia"],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2020-12-10T15:22:32Z"],["dc.date.available","2020-12-10T15:22:32Z"],["dc.date.issued","2018"],["dc.identifier.doi","10.1021/acscatal.7b03648"],["dc.identifier.eissn","2155-5435"],["dc.identifier.issn","2155-5435"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/73439"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.title","Sequential meta -/ ortho -C–H Functionalizations by One-Pot Ruthenium(II/III) Catalysis"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]