Krick, Marcel

[["dc.bibliographiccitation.firstpage","29724"],["dc.bibliographiccitation.issue","56"],["dc.bibliographiccitation.journal","RSC Advances"],["dc.bibliographiccitation.lastpage","29728"],["dc.bibliographiccitation.volume","4"],["dc.contributor.author","Schulte, Thorben R."],["dc.contributor.author","Krick, Marcel"],["dc.contributor.author","Asche, Carmen I."],["dc.contributor.author","Freye, Sabrina"],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T09:45:58Z"],["dc.date.available","2018-11-07T09:45:58Z"],["dc.date.issued","2014"],["dc.description.abstract","In order to gain a better understanding of the formation of interpenetrated double-cages [Pd4L8] from banana-shaped ligands and square-planar metal cations, our previously reported dibenzosuberone-based ligand was synthetically modified. We show that the formation of double-cages tolerates a wide range of suberone backbone modifications, as long as the ketone functionality is preserved. Reduction of this group to a CH2-bridge allowed us to form a monomeric [Pd2L4] cage, instead. PM6 and DFT calculations were performed to study the role of the carbonyl group in the formation of double-cages yielding results that are in good agreement with the experiments."],["dc.description.sponsorship","Fonds der Chemischen Industrie; DFG [CL 489/2-1]"],["dc.identifier.doi","10.1039/c4ra04679j"],["dc.identifier.isi","000339669800043"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/34759"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","2046-2069"],["dc.title","Subtle backbone modifications control the interpenetration of dibenzosuberone-based coordination cages"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]