Edelmann, Frank Thomas

[["dc.bibliographiccitation.firstpage","1373"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","Chemische Berichte"],["dc.bibliographiccitation.lastpage","1375"],["dc.bibliographiccitation.volume","124"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2019-07-09T11:52:06Z"],["dc.date.available","2019-07-09T11:52:06Z"],["dc.date.issued","1991"],["dc.description.abstract","The tetranuclear complex [Cp Sm(-OC)2FeCp ]2 (3) has been prepared by reaction of Cp 2Sm(THF)2 with [Cp Fe(CO)2]2 and structurally characterized by single-crystal X-ray diffraction."],["dc.identifier.doi","10.1002/cber.19911240611"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3329"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60098"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Organolanthanid(II)-Chemie: Synthese und Struktur von [Cp2 Sm(-OC)2FeCp ]2"],["dc.title.alternative","Organolanthanide(II) Chemistry: Synthesis and Structure of [Cp*Sm(-OC)2FeCp*]2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","192"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","195"],["dc.bibliographiccitation.volume","11"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Bertel, Norbert"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2019-07-09T11:52:11Z"],["dc.date.available","2019-07-09T11:52:11Z"],["dc.date.issued","1992"],["dc.description.abstract","The molecular structures of (RF)2Zn( 3), (RF)2Cd(MeCN()4 a), and (RF)2Hg (5) have_b een determined by X-ray crystallography (RF = 2,4,6-tris(trifluoromethyl)phenyl). For 3: triclinic, P1, a = 8.339 (3) A, b = 9.064 (2) A, c = 13.499 (4) A, CY = 88.38 (3)O, @ = 87.79 (4)O, y = 76.85 (2)O, V = 992.6 (5) A3, 2 = 2,and R = 3.92%. For 4a: monoclinic, P21/c, a = 10.876 (3) A, b = 16.79 (1) A, c = 13.865 (5) A, @ = 112.81 = 15.294 (3) A, @ = 92.20 (3)O, V = 1066.3 (4) A3, Z = 2, and R = 5.73%. A characteristic structural feature of all three derivatives is weak metal-fluorine interactions. (R&Zn and (RJ2Cd(MeCN) represent the first examples of structurally characterized two- and three-coordinate monomeric diarylzinc and -cadmium."],["dc.identifier.doi","10.1021/om00037a037"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3342"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60107"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Main-group chemistry of the 2,4,6-tris(trifluoromethyl)phenyl substituent: x-ray crystal structures of [2,4,6-(CF3)3C6H2]2Zn, [2,4,6-(CF3)3C6H2]2Cd(MeCN) and [2,4,6-(CF3)3C6H3]2Hg"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","217"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","335"],["dc.bibliographiccitation.volume","414"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-25T08:13:02Z"],["dc.date.accessioned","2021-10-27T13:12:33Z"],["dc.date.available","2009-06-25T08:13:02Z"],["dc.date.available","2021-10-27T13:12:33Z"],["dc.date.issued","1991"],["dc.description.abstract","Die Molekülstruktur von Li[Ph2P(NSiMe3)2](THF)2 (2) wurde durch Röntgenstrukturanalyse bestimmt. Ein viergliedriger LiNPN-Ring bildet die zentrale Einheit des monomeren Moleküls. YbI2 reagiert mit zwei Äquivalenten Li[Ph2P(NSiMe3)2] (1) zum neuartigen Ytterbium(II)diiminophosphinat [Ph2P(NSiMe3)2]2Yb(THF)2 (3). Die analoge Reaktion von 1 mit SmI2 liefert das Samarium(III)derivat [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2 (4), dessen Struktur ebenfalls röntgenographisch bestimmt wurde. Abstract: The molecular structure of Li[Ph2P(NSiMe3)2](THF)2 (2) has been determined by an X-ray diffraction study. A four-membered LiNPN ring forms the central unit of the monomeric molecule. YbI2 reacts with two equivalents of Li[Ph2P(NSiMe3)2] (1) to give the novel ytterbium(II)diiminophosphinate [Ph2P(NSiMe3)2]2Yb(THF)2 (3). A similar reaction of 1 with SmI2 affords the samarium(III) derivative [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2 (4) whose structure has also been determined by an X-ray diffraction study."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(91)86331-J"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3325"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91702"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Diiminophosphinate des Lithiums, Samariums und Ytterbiums: Molekülstrukturen von Li[Ph2P(NSiMe3)2](THF)2 und [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2527"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Acta Crystallographica / C"],["dc.bibliographiccitation.lastpage","2529"],["dc.bibliographiccitation.volume","47"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Edelmann, Frank T."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2009-06-25T06:43:02Z"],["dc.date.accessioned","2021-10-27T13:11:52Z"],["dc.date.available","2009-06-25T06:43:02Z"],["dc.date.available","2021-10-27T13:11:52Z"],["dc.date.issued","1991"],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1107/S0108270191006352"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3320"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91634"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Structure of (Rf)2(Cl)SnIV(μ2-O)SnIV(Cl)(Rf)2; Rf = 2,4,6-tris(trifluoromethyl)phenyl"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","315"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","326"],["dc.bibliographiccitation.volume","415"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-25T08:07:43Z"],["dc.date.accessioned","2021-10-27T13:11:55Z"],["dc.date.available","2009-06-25T08:07:43Z"],["dc.date.available","2021-10-27T13:11:55Z"],["dc.date.issued","1991"],["dc.description.abstract","Li[Me2Si(OtBu)(NtBu)] (1) reagiert mit YbI2 zum Ytterbium(II)alkoxysilylamid [Me2Si(OtBu(NtBu)]2Yb(THF)2 (2). Die analoge Reaktion von 1 mit SmI2 liefert das Samarium(III)derivat [Me2Si(OtBu)(NtBu)]2Sm(μ-I)2Li(THF)2 (3). Däruber hinaus wird die Darstellung von [Me2Si(O)tBu)(NtBu)] Nd (4) und [Me2Si(OtBu)(NtBu)]2Yb(μ-Cl)2Li(THF)2 (5) beschrieden. Die Molekülstrukturen von 4 und 5 wurden röntgenographisch bestimmt. Abstract: Li[Me2Si(OtBu)(NtBu)](1) reacts with YbI2 to give the ytterbium(II)alkoxysilylamide [Me2Si(OtBu)-(NtBu)]2Yb (THF)2 (2). The analogous reactio of 1 with SmI2 yields the samarium(III) derivative [Me2Si(OtBu)(NtBu)]2Sm(μ-I)2Li(THF)2 (3). Moreover, the preparation of [Me2Si(OtBu)(NtBu)]3Nd (4) and [Me2Si(OtBu)(NtBu)]2Yb(μ-Cl)2Li(THF)2 (5) is described. The molecular structures of 4 and 5 have been determined by X-ray crystallography."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(91)80131-3"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3324"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91639"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Alkoxysilylamide des Neodyms, Samariums und Ytterbiums: Viergliedrige anorganische Ringsysteme in der Lanthanidchemie"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","144"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of the Chemical Society. Chemical communications"],["dc.bibliographiccitation.lastpage","146"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Edelmann, Frank Thomas"],["dc.contributor.author","Kottke, Thomas"],["dc.contributor.author","Roesky, Thomas"],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Whitmire, Kenton H."],["dc.date.accessioned","2009-06-29T08:46:42Z"],["dc.date.accessioned","2021-10-27T13:12:23Z"],["dc.date.available","2009-06-29T08:46:42Z"],["dc.date.available","2021-10-27T13:12:23Z"],["dc.date.issued","1991"],["dc.description.abstract","Na(OR)(thf)2]21, [K(OR)(thf)2(µ-thf)]22, [Na(SR)(thf)2·0.25thf]x3 and [K(SR)-(thf)]x4 were formed by the reaction of the appropriate combinations of 2,4,6-tris(trifluoromethyl)phenol (ROH) or 2,4,6-tris(trifluorornethyl)benzenethiol (RSH) with NaH or KH; compounds 1-4 have been characterised by NMR spectrosccpy and single crystal X-ray structure analysis, both phenoxides being dimeric whereas two distinct polymeric structural types are observed for the thiolates."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1039/C39910000144"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3341"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91686"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Comparison of the X-ray crystal structures of the sodium and potassium 2,4,6-tris(trifluoromethyl)phenoxides (RO–) and 2,4,6-tris(trifluoromethyl)benzenethiolates (RS–); [Na(OR)(thf)2]2, [K(OR)(thf)2(µ-thf)]2, [Na(SR)(thf)2·0.25thf]x and [K(SR)(thf)]x(thf = tetrahydrofuran)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]