Edelmann, Frank Thomas

[["dc.bibliographiccitation.firstpage","347"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","356"],["dc.bibliographiccitation.volume","411"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Pieper, Ursula"],["dc.contributor.author","Schmidt, Hans-Georg"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-26T07:40:17Z"],["dc.date.accessioned","2021-10-27T13:12:24Z"],["dc.date.available","2009-06-26T07:40:17Z"],["dc.date.available","2021-10-27T13:12:24Z"],["dc.date.issued","1991"],["dc.description.abstract","Das THF-Addukt des Decamethylsamarocens, Cp2 Sm(THF)2, reagiert mit Disulfiden, Diseleniden und Ditelluriden zu Organosamarium(III)komplexen, die eine Sm–E-Bindung enthalten (E = p. Se, Te). Die Molekülstrukturen der Komplexe Cp2 Sm(S2CNMe2) (1), Cp2 Sm[TeC6H2Me3-2,4,6](THF) (4) und Cp2 Sm[SeC6H2(CF3)3-2,4,6](THF) (5) wurden röntgenographisch bestimmt. Abstract: The THF adduct of decamethylsamarocene, CP2Sm(THF)2, reacts with disulfides, diselenides and ditellurides to give organosamarium(III) complexes containing a Sm---E bond (E = S, Se, Te). The molecular structures of the complexes CP2Sm(S2CNMe2) (1), Cp2Sm[TeC6H2Me3-2,4,6](THF) (4) and Cp2Sm[SeC6H2(CF3)3-2,4,6](THF) (5 have been determined by X-ray diffraction."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(91)83040-B"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3328"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91688"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Monomere Organosamarium(III) Chalkogenolate durch reduktive Spaltung von E–E-Bindungen (E = S, Se, Te)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","217"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","335"],["dc.bibliographiccitation.volume","414"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-25T08:13:02Z"],["dc.date.accessioned","2021-10-27T13:12:33Z"],["dc.date.available","2009-06-25T08:13:02Z"],["dc.date.available","2021-10-27T13:12:33Z"],["dc.date.issued","1991"],["dc.description.abstract","Die Molekülstruktur von Li[Ph2P(NSiMe3)2](THF)2 (2) wurde durch Röntgenstrukturanalyse bestimmt. Ein viergliedriger LiNPN-Ring bildet die zentrale Einheit des monomeren Moleküls. YbI2 reagiert mit zwei Äquivalenten Li[Ph2P(NSiMe3)2] (1) zum neuartigen Ytterbium(II)diiminophosphinat [Ph2P(NSiMe3)2]2Yb(THF)2 (3). Die analoge Reaktion von 1 mit SmI2 liefert das Samarium(III)derivat [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2 (4), dessen Struktur ebenfalls röntgenographisch bestimmt wurde. Abstract: The molecular structure of Li[Ph2P(NSiMe3)2](THF)2 (2) has been determined by an X-ray diffraction study. A four-membered LiNPN ring forms the central unit of the monomeric molecule. YbI2 reacts with two equivalents of Li[Ph2P(NSiMe3)2] (1) to give the novel ytterbium(II)diiminophosphinate [Ph2P(NSiMe3)2]2Yb(THF)2 (3). A similar reaction of 1 with SmI2 affords the samarium(III) derivative [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2 (4) whose structure has also been determined by an X-ray diffraction study."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(91)86331-J"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3325"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91702"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Diiminophosphinate des Lithiums, Samariums und Ytterbiums: Molekülstrukturen von Li[Ph2P(NSiMe3)2](THF)2 und [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","315"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","326"],["dc.bibliographiccitation.volume","415"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-25T08:07:43Z"],["dc.date.accessioned","2021-10-27T13:11:55Z"],["dc.date.available","2009-06-25T08:07:43Z"],["dc.date.available","2021-10-27T13:11:55Z"],["dc.date.issued","1991"],["dc.description.abstract","Li[Me2Si(OtBu)(NtBu)] (1) reagiert mit YbI2 zum Ytterbium(II)alkoxysilylamid [Me2Si(OtBu(NtBu)]2Yb(THF)2 (2). Die analoge Reaktion von 1 mit SmI2 liefert das Samarium(III)derivat [Me2Si(OtBu)(NtBu)]2Sm(μ-I)2Li(THF)2 (3). Däruber hinaus wird die Darstellung von [Me2Si(O)tBu)(NtBu)] Nd (4) und [Me2Si(OtBu)(NtBu)]2Yb(μ-Cl)2Li(THF)2 (5) beschrieden. Die Molekülstrukturen von 4 und 5 wurden röntgenographisch bestimmt. Abstract: Li[Me2Si(OtBu)(NtBu)](1) reacts with YbI2 to give the ytterbium(II)alkoxysilylamide [Me2Si(OtBu)-(NtBu)]2Yb (THF)2 (2). The analogous reactio of 1 with SmI2 yields the samarium(III) derivative [Me2Si(OtBu)(NtBu)]2Sm(μ-I)2Li(THF)2 (3). Moreover, the preparation of [Me2Si(OtBu)(NtBu)]3Nd (4) and [Me2Si(OtBu)(NtBu)]2Yb(μ-Cl)2Li(THF)2 (5) is described. The molecular structures of 4 and 5 have been determined by X-ray crystallography."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(91)80131-3"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3324"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91639"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Alkoxysilylamide des Neodyms, Samariums und Ytterbiums: Viergliedrige anorganische Ringsysteme in der Lanthanidchemie"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]