Ma, Xiaoli

[["dc.bibliographiccitation.firstpage","13520"],["dc.bibliographiccitation.issue","43"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","13524"],["dc.bibliographiccitation.volume","41"],["dc.contributor.author","Hao, Pengfei"],["dc.contributor.author","Yang, Zhi"],["dc.contributor.author","Ma, Xiaoli"],["dc.contributor.author","Wang, X."],["dc.contributor.author","Liu, Zhihong"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Sun, Kening"],["dc.contributor.author","Li, Jiarong"],["dc.contributor.author","Zhong, M."],["dc.date.accessioned","2018-11-07T09:14:53Z"],["dc.date.available","2018-11-07T09:14:53Z"],["dc.date.issued","2012"],["dc.description.abstract","The reactions of LAlH2 (L = HC(CMeNAr)(2), Ar = 2,6-iPr(2)C(6)H(3)) (1) with diphenylsilanediol, phenylphosphonic acid, diphenylphosphinic acid, and pyrocatechol afford compounds with the Al-O-X (X = Si, P, C) motif of composition [LAl(mu-O)](2)Si(Ph)(2) (2), [LAl(mu-O)](2)PO(Ph) (3), LAl[OPO(Ph)(2)](2) (4), and LAl(mu-O)(2)(o-C6H4) (5), respectively. Compound 2 contains the Al-O-Si-O-Al heterotrimetallic dioxide chain. Compound 3 features an Al(mu-O)](2)P four-membered ring, while compound 4 exhibits a P-O-Al-O-P chain structure. Compound 5 contains the benzo-aluminum-dioxide organic-inorganic hybrid five-membered ring. Complexes 2, 3, 4, and 5 were characterized by NMR, elementary analysis, and single-crystal X-ray diffraction."],["dc.identifier.doi","10.1039/c2dt31872e"],["dc.identifier.isi","000309885500038"],["dc.identifier.pmid","23018666"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/10212"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/27532"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9226"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Synthesis and characterization of compounds with the Al-O-X (X = Si, P, C) structural motif"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","11918"],["dc.bibliographiccitation.issue","51"],["dc.bibliographiccitation.journal","Chemistry – A European Journal"],["dc.bibliographiccitation.lastpage","11923"],["dc.bibliographiccitation.volume","25"],["dc.contributor.author","Shen, Qiumiao"],["dc.contributor.author","Ma, Xiaoli"],["dc.contributor.author","Li, Wenling"],["dc.contributor.author","Liu, Wenqing"],["dc.contributor.author","Ding, Yi"],["dc.contributor.author","Yang, Zhi"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2020-12-10T14:05:54Z"],["dc.date.available","2020-12-10T14:05:54Z"],["dc.date.issued","2019"],["dc.description.abstract","he effectivecatalytic activity of organoaluminumcompoundsfor the monohydroboration of carbodiimideshas beendemonstrated. Twoaluminumcomplexes,2and3,weresynthesizedandcharacterized.Theefficientcatalyticperformances of fouraluminum hydridecomplexes L1AlH2(L1=HC(CMeNAr)2,Ar=2,6-Et2C6H3;1), L2AlH2(NMe3)(L2=o-C6H4F(CH=N-Ar),Ar=2,6-Et2C6H3;2), L3AlH(L3=2,6-bis(1-methylethyl)-N-(2-pyridinylmethylene)phenylamine;3), andL4AlH(NMe3)(L4=o-C6H4(N-Dipp)(CH=N-Dipp),Dipp=2,6-iPr2C6H3;4), andan aluminum alkylcomplex L1AlMe2(5)wereusedfor the monohydroboration of carbodiimidesin-vestigatedundersolvent-free andmildconditions. Com-pounds1–3and5can produce monohydroboratedN-boryl-formamidine, whereas4can affordtheC-borylformamidineproduct. Asuggested mechanismof this reactionwas ex-plored, andthe aluminumformamidinate compound6wascharacterized by single-crystal X-ray,also astoichiometricre-actionwas investigated."],["dc.description.sponsorship","National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809"],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/100004807"],["dc.identifier.doi","10.1002/chem.201902000"],["dc.identifier.eissn","1521-3765"],["dc.identifier.issn","0947-6539"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16653"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/69699"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.relation.eissn","1521-3765"],["dc.relation.issn","1521-3765"],["dc.relation.issn","0947-6539"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","CC BY 4.0"],["dc.rights.access","openAccess"],["dc.rights.uri","https://creativecommons.org/licenses/by/4.0"],["dc.subject","carbodiimide; catalysts; hydroboration; organoaluminum"],["dc.subject.ddc","540"],["dc.title","Organoaluminum Compounds as Catalysts for Monohydroboration of Carbodiimides"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2010"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","2014"],["dc.bibliographiccitation.volume","50"],["dc.contributor.author","Ma, Xiaoli"],["dc.contributor.author","Yang, Zhi"],["dc.contributor.author","Wang, X."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Wu, Feng"],["dc.contributor.author","Zhu, Hongping"],["dc.date.accessioned","2018-11-07T08:58:14Z"],["dc.date.available","2018-11-07T08:58:14Z"],["dc.date.issued","2011"],["dc.description.abstract","The reaction of LAIH(2) (L = HC(CMeNAr)(2), Ar = 2,6-iPr(2)C(6)H(3)) (1) with 3-methylphenylboronic acid and 3-fluorophenylboronic acid resulted in the boroxine-linked aluminum compounds LAI[OB(3-CH3C6H4)](2)(mu-O) (2) and LAI[OB(3-PC6H4)](2)(mu-O) (3), respectively. LAI[OB(2-PhC6H4)(OH)](2) (4) was synthesized by the reaction of 1 with 2-biphenylboronic acid. Compound 4 is the intermediate analogue to those, which we postulated for the formation of 2 and 3. The reaction of 1 with 3-hydroxyphenylboronic acid resulted in the first metal benzoboroxole oxide LAI[OB(o-CH2O)C6H4](2) (5), which is formed from a compound with B-(OH)(2) and C-OH functionalities."],["dc.identifier.doi","10.1021/ic1022906"],["dc.identifier.isi","000287685600047"],["dc.identifier.pmid","21319772"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/9436"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/23591"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Synthesis of Boroxine-Linked Aluminum Complexes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.issue","37"],["dc.bibliographiccitation.journal","ChemistrySelect"],["dc.bibliographiccitation.volume","7"],["dc.contributor.affiliation","Ni, Congjian; 1\r\nSchool of Chemistry and Chemical Engineering\r\nBeijing Institute of Technology\r\nBeijing 100081 P. R. China"],["dc.contributor.affiliation","Ma, Xiaoli; 1\r\nSchool of Chemistry and Chemical Engineering\r\nBeijing Institute of Technology\r\nBeijing 100081 P. R. China"],["dc.contributor.affiliation","Yang, Zhi; 1\r\nSchool of Chemistry and Chemical Engineering\r\nBeijing Institute of Technology\r\nBeijing 100081 P. R. China"],["dc.contributor.affiliation","Roesky, Herbert W.; 2\r\nInstitute of Inorganic Chemistry\r\nGeorg-August-Universität\r\nTammannstrasse 4 D-37077 Göttingen Germany"],["dc.contributor.author","Ni, Congjian"],["dc.contributor.author","Ma, Xiaoli"],["dc.contributor.author","Yang, Zhi"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2022-11-28T09:43:04Z"],["dc.date.available","2022-11-28T09:43:04Z"],["dc.date.issued","2022-10-05"],["dc.date.updated","2022-11-27T10:11:18Z"],["dc.description.abstract","Abstract\r\nA simple, efficient, and economical method for the chemoselective hydroboration of isocyanates is reported. Commercially available NaH, at very low loadings, efficiently catalyzes the selective conversion of isocyanates to N‐boryl formamides, bis(boryl)hemiaminals, and N‐boryl methyl amines. NaH catalyzes isocyanates to controllably open the N=C bond to build an amide bond, and can also remove the C=O bond to obtain N‐boryl methyl amines. Both aliphatic and aromatic isocyanates can be quantitatively converted to the corresponding hydroboration products. Furthermore, there is excellent functional group selectivity over imines, nitriles, and olefins. Additionally, through in situ monitoring, a possible reaction mechanism is proposed. And the chemical intermediates generated by NaH and HBpin are responsible for all the reduction steps."],["dc.description.abstract","A simple, efficient, non‐transition metal, and economical method for chemoselective hydroboration of isocyanates catalyzed by commercially available reagents under low catalyst loading solvent‐free, and mild conditions. Aliphatic and aromatic isocyanates can be efficiently converted to the corresponding borohydride products.\r\n\r\nimage"],["dc.description.sponsorship","National Nature Science Foundation of China http://dx.doi.org/10.13039/501100001809"],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/501100001659"],["dc.identifier.doi","10.1002/slct.202202878"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/117307"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-605"],["dc.relation.eissn","2365-6549"],["dc.relation.issn","2365-6549"],["dc.rights","This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited."],["dc.rights.uri","http://creativecommons.org/licenses/by/4.0/"],["dc.title","Chemoselective Hydroboration of Isocyanates Catalyzed by Commercially Available NaH"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]