Ma, Xiaoli

[["dc.bibliographiccitation.firstpage","11918"],["dc.bibliographiccitation.issue","51"],["dc.bibliographiccitation.journal","Chemistry – A European Journal"],["dc.bibliographiccitation.lastpage","11923"],["dc.bibliographiccitation.volume","25"],["dc.contributor.author","Shen, Qiumiao"],["dc.contributor.author","Ma, Xiaoli"],["dc.contributor.author","Li, Wenling"],["dc.contributor.author","Liu, Wenqing"],["dc.contributor.author","Ding, Yi"],["dc.contributor.author","Yang, Zhi"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2020-12-10T14:05:54Z"],["dc.date.available","2020-12-10T14:05:54Z"],["dc.date.issued","2019"],["dc.description.abstract","he effectivecatalytic activity of organoaluminumcompoundsfor the monohydroboration of carbodiimideshas beendemonstrated. Twoaluminumcomplexes,2and3,weresynthesizedandcharacterized.Theefficientcatalyticperformances of fouraluminum hydridecomplexes L1AlH2(L1=HC(CMeNAr)2,Ar=2,6-Et2C6H3;1), L2AlH2(NMe3)(L2=o-C6H4F(CH=N-Ar),Ar=2,6-Et2C6H3;2), L3AlH(L3=2,6-bis(1-methylethyl)-N-(2-pyridinylmethylene)phenylamine;3), andL4AlH(NMe3)(L4=o-C6H4(N-Dipp)(CH=N-Dipp),Dipp=2,6-iPr2C6H3;4), andan aluminum alkylcomplex L1AlMe2(5)wereusedfor the monohydroboration of carbodiimidesin-vestigatedundersolvent-free andmildconditions. Com-pounds1–3and5can produce monohydroboratedN-boryl-formamidine, whereas4can affordtheC-borylformamidineproduct. Asuggested mechanismof this reactionwas ex-plored, andthe aluminumformamidinate compound6wascharacterized by single-crystal X-ray,also astoichiometricre-actionwas investigated."],["dc.description.sponsorship","National Natural Science Foundation of China http://dx.doi.org/10.13039/501100001809"],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft http://dx.doi.org/10.13039/100004807"],["dc.identifier.doi","10.1002/chem.201902000"],["dc.identifier.eissn","1521-3765"],["dc.identifier.issn","0947-6539"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16653"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/69699"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.relation.eissn","1521-3765"],["dc.relation.issn","1521-3765"],["dc.relation.issn","0947-6539"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","CC BY 4.0"],["dc.rights.access","openAccess"],["dc.rights.uri","https://creativecommons.org/licenses/by/4.0"],["dc.subject","carbodiimide; catalysts; hydroboration; organoaluminum"],["dc.subject.ddc","540"],["dc.title","Organoaluminum Compounds as Catalysts for Monohydroboration of Carbodiimides"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]