Lüttschwager, Nils O. B.

[["dc.bibliographiccitation.firstpage","2211"],["dc.bibliographiccitation.issue","14-15"],["dc.bibliographiccitation.journal","Molecular Physics"],["dc.bibliographiccitation.lastpage","2227"],["dc.bibliographiccitation.volume","111"],["dc.contributor.author","Luettschwager, Nils O. B."],["dc.contributor.author","Wassermann, Tobias N."],["dc.contributor.author","Coussan, Stephane"],["dc.contributor.author","Suhm, Martin A."],["dc.date.accessioned","2018-11-07T09:21:44Z"],["dc.date.available","2018-11-07T09:21:44Z"],["dc.date.issued","2013"],["dc.description.abstract","Tunnelling splittings in vibrationally excited malonaldehyde are derived from complementary FTIR and Raman spectra utilising jet cooling and matrix isolation. Values from 0 to 69 cm(-1) (i.e. from complete quenching of the proton tunnelling to an acceleration by a factor of 3) are firmly assigned, underscoring a strong coupling between hydrogen transfer and vibrational excitation. More tentative assignments involve even larger effects for the OO breathing vibration. The results are discussed with respect to the corresponding normal modes and compared to previous theoretical predictions."],["dc.identifier.doi","10.1080/00268976.2013.798042"],["dc.identifier.isi","000323879600031"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/8922"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/29178"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Taylor & Francis Ltd"],["dc.relation.issn","1362-3028"],["dc.relation.issn","0026-8976"],["dc.relation.orgunit","Institut für Physikalische Chemie"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Vibrational tuning of the Hydrogen transfer in malonaldehyde - a combined FTIR and Raman jet study"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","463-6"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Angewandte Chemie. International Edition"],["dc.bibliographiccitation.lastpage","466"],["dc.bibliographiccitation.volume","52"],["dc.contributor.author","Luettschwager, Nils O. B."],["dc.contributor.author","Wassermann, Tobias N."],["dc.contributor.author","Mata, Ricardo A."],["dc.contributor.author","Suhm, Martin A."],["dc.date.accessioned","2021-08-27T07:08:25Z"],["dc.date.available","2021-08-27T07:08:25Z"],["dc.date.issued","2013-01-02"],["dc.description.abstract","Mother of all folding: cold isolated linear alkanes C(n)H(2n+2) prefer an extended all-trans conformation before cohesive forces between the chain ends induce a folded hairpin structure for longer chains. It is shown by Raman spectroscopy at 100-150 K that the folded structure becomes more stable beyond n(C) = 17 or 18 carbon atoms. High-level quantum-chemical calculations yield n(C) = 17 ± 1 as the critical chain length."],["dc.identifier.doi","10.1002/anie.201202894"],["dc.identifier.pmid","22907923"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/9894"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/88879"],["dc.identifier.url","https://publications.goettingen-research-online.de/handle/2/65227"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.relation.eissn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.rights","CC BY 4.0"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","The last globally stable extended alkane"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.subtype","original_ja"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","482"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Angewandte Chemie"],["dc.bibliographiccitation.lastpage","485"],["dc.bibliographiccitation.volume","125"],["dc.contributor.author","Lüttschwager, Nils O. B."],["dc.contributor.author","Wassermann, Tobias N."],["dc.contributor.author","Mata, Ricardo A."],["dc.contributor.author","Suhm, Martin A."],["dc.date.accessioned","2019-07-09T11:54:57Z"],["dc.date.available","2019-07-09T11:54:57Z"],["dc.date.issued","2013"],["dc.description.abstract","Die Mutter aller Faltung: Kalte, isolierte lineare Alkane CnH2n+2 bevorzugen eine gestreckte all-trans-Konformation, bis Kohäsionskräfte zwischen den Kettenenden bei größerer Kettenlänge eine gefaltete Haarnadel-Struktur erzwingen. Mit Raman-Spektroskopie bei 100–150 K wird gezeigt, dass die gefaltete Struktur spätestens jenseits von nc=17 oder 18 Kohlenstoffatomen stabiler wird. Quantenchemische Rechnungen finden nc=17±1 als kritische Kettenlänge."],["dc.identifier.doi","10.1002/ange.201202894"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/9893"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60765"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Das letzte Alkan mit gestreckter Grundzustandskonformation"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]