Finger, Markus

[["dc.bibliographiccitation.firstpage","11581"],["dc.bibliographiccitation.issue","30"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","11591"],["dc.bibliographiccitation.volume","61"],["dc.contributor.author","van Alten, Richt S."],["dc.contributor.author","Wieser, Philipp A."],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Siewert, Inke"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2022-09-01T09:49:54Z"],["dc.date.available","2022-09-01T09:49:54Z"],["dc.date.issued","2022"],["dc.identifier.doi","10.1021/acs.inorgchem.2c00973"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/113570"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-597"],["dc.relation.eissn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","Halide Effects in Reductive Splitting of Dinitrogen with Rhenium Pincer Complexes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","469"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Inorganic Chemistry Frontiers"],["dc.bibliographiccitation.lastpage","477"],["dc.bibliographiccitation.volume","3"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Kasanmascheff, Müge"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2016-02-15T11:46:27Z"],["dc.date.accessioned","2021-10-27T13:12:29Z"],["dc.date.available","2016-02-15T11:46:27Z"],["dc.date.available","2021-10-27T13:12:29Z"],["dc.date.issued","2016"],["dc.description.abstract","The oxidative coupling of nitride ligands (N3−) to dinitrogen and its microscopic reverse, N2-splitting to nitrides, are important elementary steps in chemical transformations, such as selective ammonia oxidation or nitrogen fixation. Here an experimental and computational evaluation is provided for the homo- and heterocoupling of our previously reported iridium(IV) and iridium(V) nitrides [IrN(PNP)]n (n = 0, +1; PNP = N(CHCHPtBu2)2). All three formal coupling products [(PNP)IrN2Ir(PNP)]n (n = 0–+2) were structurally characterized. While the three coupling reactions are all thermodynamically feasible, homocoupling of [IrN(PNP)]+ is kinetically hindered. The contributing parameters to relative coupling rates are discussed providing qualitative guidelines for the stability of electron rich transition metal nitrides."],["dc.description.sponsorship","European Research Council [646747]"],["dc.identifier.doi","10.1039/c5qi00267b"],["dc.identifier.isi","000374011600004"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/12839"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91696"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU/N2 as Chemical Feedstock – Synthetic Nitrogen Fixation beyond Haber-Bosch/N2FEED"],["dc.relation.issn","2052-1553"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","iridium nitrido complexes; Coupling"],["dc.title","Coupling of terminal iridium nitrido complexes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","802"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","811"],["dc.bibliographiccitation.volume","37"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Bete, Sarah C."],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Volkmann, Christian"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2019-07-09T11:51:20Z"],["dc.date.available","2019-07-09T11:51:20Z"],["dc.date.issued","2017"],["dc.identifier.doi","10.1021/acs.organomet.7b00707"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16106"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/59928"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Four- and Five-Coordinate Osmium(IV) Nitrides and Imides: Circumventing the “Nitrido Wall”"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","830"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","834"],["dc.bibliographiccitation.volume","58"],["dc.contributor.author","Schendzielorz, Florian"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Krewald, Vera"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2020-01-14T13:35:36Z"],["dc.date.accessioned","2021-10-27T13:12:51Z"],["dc.date.available","2020-01-14T13:35:36Z"],["dc.date.available","2021-10-27T13:12:51Z"],["dc.date.issued","2018"],["dc.identifier.doi","10.1002/anie.201812125"],["dc.identifier.doi","10.1002/ange.201812125"],["dc.identifier.eissn","1521-3773"],["dc.identifier.issn","1433-7851"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17095"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91728"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.relation.issn","1433-7851"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","N2FEED"],["dc.subject.ddc","540"],["dc.title","Metal-Ligand Cooperative Synthesis of Benzonitrile by Electrochemical Reduction and Photolytic Splitting of Dinitrogen"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","23574"],["dc.bibliographiccitation.issue","52"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","23578"],["dc.bibliographiccitation.volume","59"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Wätjen, Florian"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-04-14T08:32:23Z"],["dc.date.available","2021-04-14T08:32:23Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1002/anie.202011750"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/83901"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.title","The Metaphosphite (PO 2 − ) Anion as a Ligand"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","10275"],["dc.bibliographiccitation.issue","44"],["dc.bibliographiccitation.journal","Chemical Science"],["dc.bibliographiccitation.lastpage","10282"],["dc.bibliographiccitation.volume","10"],["dc.contributor.author","Schluschaß, Bastian"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Franke, Alicja"],["dc.contributor.author","Herwig, Christian"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Ivanovic-Burmazovic, Ivana"],["dc.contributor.author","Limberg, Christian"],["dc.contributor.author","Schneider, Sven"],["dc.contributor.author","Telser, Joshua"],["dc.date.accessioned","2021-06-01T10:50:53Z"],["dc.date.available","2021-06-01T10:50:53Z"],["dc.date.issued","2019"],["dc.description.abstract","An N 2 -bridged ditungsten complex is presented that undergoes N 2 -splitting or hydrogen evolution upon protonation depending on the acid and reaction conditions. Spectroscopic, kinetic and computational results emphasize the impact of hydrogen bonding on the reaction selectivity."],["dc.description.abstract","Mo complexes are currently the most active catalysts for nitrogen fixation under ambient conditions. In comparison, tungsten platforms are scarcely examined. For active catalysts, the control of N 2 vs. proton reduction selectivities remains a difficult task. We here present N 2 splitting using a tungsten pincer platform, which has been proposed as the key reaction for catalytic nitrogen fixation. Starting from [WCl 3 (PNP)] (PNP = N(CH 2 CH 2 P t Bu 2 ) 2 ), the activation of N 2 enabled the isolation of the dinitrogen bridged redox series [(N 2 ){WCl(PNP)} 2 ] 0/+/2+ . Protonation of the neutral complex results either in the formation of a nitride [W(N)Cl( H PNP)] + or H 2 evolution and oxidation of the W 2 N 2 core, respectively, depending on the acid and reaction conditions. Examination of the nitrogen splitting vs. proton reduction selectivity emphasizes the role of hydrogen bonding of the conjugate base with the protonated intermediates and provides guidelines for nitrogen fixation."],["dc.identifier.doi","10.1039/C9SC03779A"],["dc.identifier.eissn","2041-6539"],["dc.identifier.issn","2041-6520"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16963"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/86812"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.notes.intern","Merged from goescholar"],["dc.relation.eissn","2041-6539"],["dc.relation.issn","2041-6520"],["dc.rights","CC BY 3.0"],["dc.rights.uri","https://creativecommons.org/licenses/by/3.0"],["dc.title","Selectivity of tungsten mediated dinitrogen splitting vs. proton reduction"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","14367"],["dc.bibliographiccitation.issue","19"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","14375"],["dc.bibliographiccitation.volume","59"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Oudsen, Jean-Pierre H."],["dc.contributor.author","Venderbosch, Bas"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Herwig, Christian"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Limberg, Christian"],["dc.contributor.author","Tromp, Moniek"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-04-14T08:31:55Z"],["dc.date.available","2021-04-14T08:31:55Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1021/acs.inorgchem.0c02134"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17871"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/83751"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","Examination of Protonation-Induced Dinitrogen Splitting by in Situ EXAFS Spectroscopy"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]