Herbst-Irmer, Regine

[["dc.bibliographiccitation.firstpage","14968"],["dc.bibliographiccitation.issue","24"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","14978"],["dc.bibliographiccitation.volume","56"],["dc.contributor.author","Koehne, Ingo"],["dc.contributor.author","Graw, Nico"],["dc.contributor.author","Teuteberg, Thorsten"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2020-12-10T15:22:37Z"],["dc.date.available","2020-12-10T15:22:37Z"],["dc.date.issued","2017"],["dc.identifier.doi","10.1021/acs.inorgchem.7b02276"],["dc.identifier.eissn","1520-510X"],["dc.identifier.issn","0020-1669"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/73474"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.title","Introducing NacNac-Like Bis(4,6-isopropylbenzoxazol-2-yl)methanide in s-Block Metal Coordination"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1417"],["dc.bibliographiccitation.issue","7"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","1423"],["dc.bibliographiccitation.volume","7"],["dc.contributor.author","Walfort, B."],["dc.contributor.author","Lameyer, L."],["dc.contributor.author","Weiss, W."],["dc.contributor.author","Herbst-Irmer, R."],["dc.contributor.author","Bertermann, R."],["dc.contributor.author","Rocha, J."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:11:46Z"],["dc.date.available","2018-11-07T09:11:46Z"],["dc.date.issued","2001"],["dc.description.abstract","Organolithium compounds play the leading role among the organometallic reagents in synthesis and in industrial processes. Up to date industrial application of methyllithium is limited because it is only soluble in diethyl ether, which amplifies various hazards in large-scale processes. However, most reactions require polar solvents like diethyl ether or TI-IF to disassemble parent organolithium oligomers. If classical bidentate donor solvents like TMEDA (TMEDA = N,N,N,N'tetramethyl- 1,2-ethanediamine) or DME (DME=1,2-dimethoxyethane) are added to methyllithium, tetrameric units are linked to form polymeric arrays that suffer from reduced reactivity and/or solubility. In this paper we present two different approaches to tune methyllithium aggregation. In [((MeLi)(4)(dem)(1.5)}(infinity)] (1; DEM - EtOCH2OEt, diethoxymethane) a polymeric architecture is maintained that forms microporous soluble aggregates as a result of the rigid bite of the methylene-bridged bidentate donor base DEM. Wide channels of 720 pm in diameter in the structure maintain full solubility as they are coated with lipophilic ethyl groups and filled with solvent. In compound 1 the long-range Li3CH3. . . Li interactions found in solid [{(MeLi)(4)}(infinity)] are maintained. A different approach was successful in the disassembly of the tetrameric architecture of [{(MeLi)(4)}(infinity)]. In the reaction of dilithium triazasulfite both the parent [(MeLi)(4)] tetramer and the [(Li-2[(NtBu)(3)S]}(2)] dimer disintegrate and recombine to give an MeLi monomer stabilized in the adduct complex [(thf)(3)Li3Me{(NtBu)(3)S}] (2). One side of the Lit triangle, often found in organolithium chemistry, is shielded by the tripodal triazasulfite, while the other face is mu (3)-capped by the methanide anion. This Li-3 structural motif is also present in organolithium tetramers and hexamers. All single-crystal structures have been confirmed through solid-state NMR experiments to be the same as in the bulk powder material."],["dc.identifier.doi","10.1002/1521-3765(20010401)7:7<1417::AID-CHEM1417>3.0.CO;2-Q"],["dc.identifier.isi","000167983700007"],["dc.identifier.pmid","11330894"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/26794"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","0947-6539"],["dc.title","[{(MeLi)(4)(dem)(1.5)}(infinity)] and [(thf)(3)Li3Me{(NtBu)(3)S}] - How to reduce aggregation of parent methyllithium"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","8551"],["dc.bibliographiccitation.issue","24"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","8555"],["dc.bibliographiccitation.volume","48"],["dc.contributor.author","Sarkar, Samir Kumar"],["dc.contributor.author","Siddiqui, Mujahuddin M."],["dc.contributor.author","Kundu, Subrata"],["dc.contributor.author","Ghosh, Munmun"],["dc.contributor.author","Kretsch, Johannes"],["dc.contributor.author","Stollberg, Peter"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Stückl, A. Claudia"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Schwederski, Brigitte"],["dc.contributor.author","Kaim, Wolfgang"],["dc.contributor.author","Ghorai, Sagar"],["dc.contributor.author","Jemmis, Eluvathingal D."],["dc.date.accessioned","2021-06-01T10:50:52Z"],["dc.date.available","2021-06-01T10:50:52Z"],["dc.date.issued","2019"],["dc.description.abstract","The synthesis and characterization of metal-free fluoroborylene [(Me-cAAC) 2 BF] ( 1 ) is reported."],["dc.description.abstract","Herein, we report the synthesis and characterization of the metal free low valent fluoroborylene [(Me-cAAC) 2 BF] ( 1 ) stabilized by cyclic (alkyl)(amino) carbene (cAAC). The fluoroborylene 1 is obtained by the reductive defluorination of Me-cAAC:BF 3 with 2.0 equivalents of KC 8 in the presence of 1.0 equivalent of Me-cAAC. Due to its highly electron rich nature, 1 underwent one-electron oxidation with 1.0 equivalent of lithium tetrakis(pentafluorophenyl)borate [LiB(C 6 F 5 ) 4 ] to form the radical cation [(Me-cAAC) 2 BF]˙ + [B(C 6 F 5 ) 4 ] − ( 2 ). DFT studies suggested that the lone pair of electrons is localized on the boron atom in 1 , which explains its unprecedented reactivity. Both compounds 1 and 2 were characterized by X-ray crystallography. The radical cation 2 was studied by EPR spectroscopy."],["dc.identifier.doi","10.1039/C9DT01899A"],["dc.identifier.eissn","1477-9234"],["dc.identifier.issn","1477-9226"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16434"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/86811"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.notes.intern","Merged from goescholar"],["dc.relation.eissn","1477-9234"],["dc.relation.issn","1477-9226"],["dc.rights","CC BY-NC 3.0"],["dc.rights.uri","https://creativecommons.org/licenses/by-nc/3.0"],["dc.title","Isolation of base stabilized fluoroborylene and its radical cation"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1801"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","1805"],["dc.bibliographiccitation.volume","52"],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Schwarzer, Martin C."],["dc.contributor.author","Frenking, Gernot"],["dc.contributor.author","Tkach, Igor"],["dc.contributor.author","Wolf, Hilke"],["dc.contributor.author","Kratzert, Daniel"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Niepoetter, Benedikt"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:30:22Z"],["dc.date.available","2018-11-07T09:30:22Z"],["dc.date.issued","2013"],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft [RO 224/60-1]; DNRF"],["dc.identifier.doi","10.1002/anie.201204487"],["dc.identifier.isi","000314650600037"],["dc.identifier.pmid","23280727"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/31289"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.relation.issn","1433-7851"],["dc.title","Conversion of a Singlet Silylene to a stable Biradical"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","967"],["dc.bibliographiccitation.issue","2"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","972"],["dc.bibliographiccitation.volume","60"],["dc.contributor.author","Jung, Jochen"],["dc.contributor.author","Legendre, Christina M."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2021-06-01T09:41:34Z"],["dc.date.available","2021-06-01T09:41:34Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1021/acs.inorgchem.0c03085"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/84963"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.relation.eissn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","Exchange Coupling in Binuclear Manganese and Cobalt Complexes with the Tetraimido Sulfate Anion [S(N t Bu) 4 ] 2–"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","7000"],["dc.bibliographiccitation.issue","10"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","7009"],["dc.bibliographiccitation.volume","58"],["dc.contributor.author","Paesch, Alexander N."],["dc.contributor.author","Kreyenschmidt, Anne-Kathrin"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2020-12-10T15:22:38Z"],["dc.date.available","2020-12-10T15:22:38Z"],["dc.date.issued","2019"],["dc.identifier.doi","10.1021/acs.inorgchem.9b00629"],["dc.identifier.eissn","1520-510X"],["dc.identifier.issn","0020-1669"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/73480"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.title","Side-Arm Functionalized Silylene Copper(I) Complexes in Catalysis"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","C755"],["dc.bibliographiccitation.issue","a2"],["dc.bibliographiccitation.journal","Acta Crystallographica Section A Foundations and Advances"],["dc.bibliographiccitation.lastpage","C755"],["dc.bibliographiccitation.volume","73"],["dc.contributor.author","Krause, Lennard"],["dc.contributor.author","Pöppler, Ann-Christin"],["dc.contributor.author","Brown, Steven P."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2020-12-10T18:26:03Z"],["dc.date.available","2020-12-10T18:26:03Z"],["dc.date.issued","2017"],["dc.identifier.doi","10.1107/S2053273317088192"],["dc.identifier.issn","2053-2733"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/75928"],["dc.notes.intern","DOI Import GROB-354"],["dc.title","SPAnPS – the radiant polymorphs"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4796"],["dc.bibliographiccitation.issue","14"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","4806"],["dc.bibliographiccitation.volume","138"],["dc.contributor.author","Neufeld, Roman"],["dc.contributor.author","Teuteberg, Thorsten L."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Mata, Ricardo A."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T10:15:33Z"],["dc.date.available","2018-11-07T10:15:33Z"],["dc.date.issued","2016"],["dc.description.abstract","Grignard reagents that are at the simplest level described as \"RMgX\" (where R is an organic substituent and X a halide) are one of the most widely utilized classes of synthetic reagents. Lately, especially Grignard reagents with amido ligands of the type R1R2NMgX, so-called Hauser bases, and their Turbo analogue R1R2NMgX center dot LiCI play an outranging role in modern synthetic chemistry. However, because of their complex solution behavior, where Schlenk-type equilibria are involved, very little is known about their structure in solution. Especially the impact of LiCl on the Schlenk-equilibrium was still obscured by complexity and limited analytical access. Herein, we present unprecedented insights into the solution structure of the Hauser base (Pr2NMgCl)-Pr-i 1 and the Turbo -Hauser base (Pr2NMgCl)-Pr-i center dot LiCl 2 at various temperatures in THE-d(8) solution by employing a newly elaborated diffusion ordered spectroscopy (DOSY) NMR method hand-in-hand with theoretical calculations."],["dc.description.sponsorship","DNRF [DNRF93]"],["dc.identifier.doi","10.1021/jacs.6b00345"],["dc.identifier.isi","000374274100015"],["dc.identifier.pmid","27011251"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/40832"],["dc.language.iso","en"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.relation.issn","0002-7863"],["dc.title","Solution Structures of Hauser Base (Pr2NMgCI)-Pr-i and Turbo-Hauser Base (Pr2NMgCl)-Pr-i center dot LiCI in THE and the Influence of LiCI on the Schlenk-Equilibrium"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.artnumber","acs.inorgchem.1c03714"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.contributor.author","Lüert, Daniel"],["dc.contributor.author","Kreyenschmidt, Anne-Kathrin"],["dc.contributor.author","Legendre, Christina M."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2022-04-01T10:01:39Z"],["dc.date.available","2022-04-01T10:01:39Z"],["dc.date.issued","2022"],["dc.identifier.doi","10.1021/acs.inorgchem.1c03714"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/105720"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-530"],["dc.relation.eissn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","A Sodium Sodate as Precursor for Lanthanide Bis(4- R -benzoxazol-2-yl)methanide Single-Molecule Magnets"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1774"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Angewandte Chemie / International Edition"],["dc.bibliographiccitation.lastpage","1776"],["dc.bibliographiccitation.volume","32"],["dc.contributor.author","Armstrong, David R."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Kuhn, Annja"],["dc.contributor.author","Moncrieff, David"],["dc.contributor.author","Paver, Michael A."],["dc.contributor.author","Russell, Christopher A."],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Wright, Dominic S."],["dc.date.accessioned","2019-07-09T11:52:15Z"],["dc.date.available","2019-07-09T11:52:15Z"],["dc.date.issued","1993"],["dc.description.abstract","A bent thallocene anion is found in complexes 1 and 2, which are prepared by the reaction of [CpTl] and [Cp2Mg] (for 1) or [CpLi] (for 2) and N,N,N,N,N-pentamethyldiethylenediamine (PMDETA). The [(5-Cp)2Tl]- anion is isoelectronic and isostructural with stannocene. Ab initio calculations show that the bent structure with CS symmetry is only marginally more stable than the linear conformer with D5h symmetry."],["dc.identifier.doi","10.1002/anie.199317741"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3390"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60132"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","The Bis(cyclopentadienyl)thallate(I) Anion Isoelectronic with Stannocene"],["dc.title.alternative","Bis(cyclopentadienyl)thallat(I), ein mit Stannocen isoelektronisches Anion"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]