Herbst-Irmer, Regine

[["dc.bibliographiccitation.firstpage","14968"],["dc.bibliographiccitation.issue","24"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","14978"],["dc.bibliographiccitation.volume","56"],["dc.contributor.author","Koehne, Ingo"],["dc.contributor.author","Graw, Nico"],["dc.contributor.author","Teuteberg, Thorsten"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2020-12-10T15:22:37Z"],["dc.date.available","2020-12-10T15:22:37Z"],["dc.date.issued","2017"],["dc.identifier.doi","10.1021/acs.inorgchem.7b02276"],["dc.identifier.eissn","1520-510X"],["dc.identifier.issn","0020-1669"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/73474"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.title","Introducing NacNac-Like Bis(4,6-isopropylbenzoxazol-2-yl)methanide in s-Block Metal Coordination"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","3508"],["dc.bibliographiccitation.issue","17"],["dc.bibliographiccitation.journal","European Journal of Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","3512"],["dc.contributor.author","Jancik, Vojtech"],["dc.contributor.author","Moya Cabrera, Monica M."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Neculai, Dante"],["dc.contributor.author","Neculai, Ana M."],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Schmidt, Hans-Georg"],["dc.date.accessioned","2018-11-07T10:45:39Z"],["dc.date.available","2018-11-07T10:45:39Z"],["dc.date.issued","2004"],["dc.description.abstract","Addition of catalytic amounts of a phosphane to a reaction mixture containing LAlH2 [2; L = HC{C(Me)N(Ar)}(2), Ar = 2,6-iPr(2)C(6)H(3)] and elemental Se or Te resulted in the formation of poorly soluble [LAl(mu-Se)(2)AiL] (3) and [LAl(mu-Te)(2)AlL] (4), respectively. The sulfur analogue [LAl(mu-S)(2)AlL] (5) could not be obtained from the direct reaction of 2 with elemental sulfur; consequently, its synthesis was successfully achieved from the reaction of [LAlH2] and [LAl(SH)(2)]. A possible mechanism for the formation of [LAl(mu-Se)(2)AlL] and [LAl(mu-Te)(2)AlL] is discussed. The molecular structures of compounds 3-5 were determined by X-ray structure analyses. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)."],["dc.identifier.doi","10.1002/ejic.200400062"],["dc.identifier.isi","000223940100013"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/47552"],["dc.language.iso","en"],["dc.notes.status","final"],["dc.notes.submitter","Najko"],["dc.relation.issn","1434-1948"],["dc.title","Phosphane-catalyzed reactions of LAlH2 with elemental chalcogens; preparation of [LAl(mu-E)(2)AlL] [E = S, Se, Te, L = HC{C(Me)N(Ar)}(2), Ar=2,6-iPr(2)C(6)H(3)]"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","675"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","679"],["dc.contributor.author","Colis, JCF"],["dc.contributor.author","Larochelle, Catherine"],["dc.contributor.author","Staples, Richard J."],["dc.contributor.author","Herbst-Irmer, R."],["dc.contributor.author","Patterson, H."],["dc.date.accessioned","2018-11-07T08:37:13Z"],["dc.date.available","2018-11-07T08:37:13Z"],["dc.date.issued","2005"],["dc.description.abstract","Crystal structures of four lanthanide complexes of La [Au(CN)(2)](3) . 3H(2)O, La [Ag(CN)(2)](3) . 3H(2)O, La [Ag0.83Au0.17(CN)(2)](3) . 3H(2)O, and La [Ag0.39Au0.61(CN)(2)](3) . 3H(2)O are reported. Studies reveal that all the structures reported are isostructural. All systems were found to be in the hexagonal crystal system, space group P6(3)/mcm. The metal metal distance for the pure gold system is 3.332 ( 1) Angstrom versus 3.359( 1) Angstrom for the pure silver system. The mixed-metal systems have shown no distinct differences in the location of the metal atoms, with the La [Ag0.83Au0.17(CN)(2)](3) . 3H(2)O complex having a metal metal Ag-Au separation of 3.346( 1) Angstrom, and 3.344( 1) Angstrom for the La [Ag0.39Au0.61(CN)(2)](3) . 3H(2)O complex. The crystal structures of the pure and mixed La complexes have been solved to provide evidence of Ag-Au heterometallic interactions and as a basis for understanding the interesting optical properties of the systems."],["dc.description.sponsorship","NCRR NIH HHS [1S10RR11937-01]"],["dc.identifier.doi","10.1039/b413967d"],["dc.identifier.isi","000226844900007"],["dc.identifier.pmid","15702177"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/18480"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9226"],["dc.title","Structural studies of lanthanide ion complexes of pure gold, pure silver and mixed metal (gold silver) dicyanides"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1417"],["dc.bibliographiccitation.issue","7"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","1423"],["dc.bibliographiccitation.volume","7"],["dc.contributor.author","Walfort, B."],["dc.contributor.author","Lameyer, L."],["dc.contributor.author","Weiss, W."],["dc.contributor.author","Herbst-Irmer, R."],["dc.contributor.author","Bertermann, R."],["dc.contributor.author","Rocha, J."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:11:46Z"],["dc.date.available","2018-11-07T09:11:46Z"],["dc.date.issued","2001"],["dc.description.abstract","Organolithium compounds play the leading role among the organometallic reagents in synthesis and in industrial processes. Up to date industrial application of methyllithium is limited because it is only soluble in diethyl ether, which amplifies various hazards in large-scale processes. However, most reactions require polar solvents like diethyl ether or TI-IF to disassemble parent organolithium oligomers. If classical bidentate donor solvents like TMEDA (TMEDA = N,N,N,N'tetramethyl- 1,2-ethanediamine) or DME (DME=1,2-dimethoxyethane) are added to methyllithium, tetrameric units are linked to form polymeric arrays that suffer from reduced reactivity and/or solubility. In this paper we present two different approaches to tune methyllithium aggregation. In [((MeLi)(4)(dem)(1.5)}(infinity)] (1; DEM - EtOCH2OEt, diethoxymethane) a polymeric architecture is maintained that forms microporous soluble aggregates as a result of the rigid bite of the methylene-bridged bidentate donor base DEM. Wide channels of 720 pm in diameter in the structure maintain full solubility as they are coated with lipophilic ethyl groups and filled with solvent. In compound 1 the long-range Li3CH3. . . Li interactions found in solid [{(MeLi)(4)}(infinity)] are maintained. A different approach was successful in the disassembly of the tetrameric architecture of [{(MeLi)(4)}(infinity)]. In the reaction of dilithium triazasulfite both the parent [(MeLi)(4)] tetramer and the [(Li-2[(NtBu)(3)S]}(2)] dimer disintegrate and recombine to give an MeLi monomer stabilized in the adduct complex [(thf)(3)Li3Me{(NtBu)(3)S}] (2). One side of the Lit triangle, often found in organolithium chemistry, is shielded by the tripodal triazasulfite, while the other face is mu (3)-capped by the methanide anion. This Li-3 structural motif is also present in organolithium tetramers and hexamers. All single-crystal structures have been confirmed through solid-state NMR experiments to be the same as in the bulk powder material."],["dc.identifier.doi","10.1002/1521-3765(20010401)7:7<1417::AID-CHEM1417>3.0.CO;2-Q"],["dc.identifier.isi","000167983700007"],["dc.identifier.pmid","11330894"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/26794"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","0947-6539"],["dc.title","[{(MeLi)(4)(dem)(1.5)}(infinity)] and [(thf)(3)Li3Me{(NtBu)(3)S}] - How to reduce aggregation of parent methyllithium"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","7517"],["dc.bibliographiccitation.issue","21"],["dc.bibliographiccitation.journal","PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA"],["dc.bibliographiccitation.lastpage","7522"],["dc.bibliographiccitation.volume","102"],["dc.contributor.author","Chiu, T. K."],["dc.contributor.author","Kubelka, J."],["dc.contributor.author","Herbst-Irmer, R."],["dc.contributor.author","Eaton, W. A."],["dc.contributor.author","Hofrichter, J."],["dc.contributor.author","Davies, D. R."],["dc.date.accessioned","2018-11-07T11:00:02Z"],["dc.date.available","2018-11-07T11:00:02Z"],["dc.date.issued","2005"],["dc.description.abstract","The 35-residue subdomain of the villin headpiece (HP35) is a small ultrafast folding protein that is being intensely studied by experiments, theory, and simulations. We have solved the x-ray structures of HP35 and its fastest folding mutant [K24 norleucine (nL)] to atomic resolution and compared their experimentally measured folding kinetics by using laser temperature jump. The structures, which are in different space groups, are almost identical to each other but differ significantly from previously solved NMR structures. Hence, the differences between the x-ray and NMR structures are probably not caused by lattice contacts or crystal/solution differences, but reflect the higher accuracy of the x-ray structures. The x-ray structures reveal important details of packing of the hydrophobic core and some additional features, such as cross-helical H bonds. Comparison of the x-ray structures indicates that the nL substitution produces only local perturbations. Consequently, the finding that the small stabilization by the mutation is completely reflected in an increased folding rate suggests that this region of the protein is as structured in the transition state as in the folded structure. It is therefore a target for engineering to increase the folding rate of the subdomain from approximate to 0.5 mu s(-1) for the nL mutant to the estimated theoretical speed limit of approximate to 3 mu s(-1)."],["dc.identifier.doi","10.1073/pnas.0502495102"],["dc.identifier.isi","000229417500023"],["dc.identifier.pmid","15894611"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/50837"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Natl Acad Sciences"],["dc.relation.issn","0027-8424"],["dc.title","High-resolution x-ray crystal structures of the villin headpiece subdomain, an ultrafast folding protein"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","10860"],["dc.bibliographiccitation.issue","25"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","10863"],["dc.bibliographiccitation.volume","46"],["dc.contributor.author","Yang, Y."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Jones, Peter G."],["dc.contributor.author","So, Cheuk-Wai"],["dc.contributor.author","Zhang, Z."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Ye, Hongqi"],["dc.date.accessioned","2018-11-07T10:45:20Z"],["dc.date.available","2018-11-07T10:45:20Z"],["dc.date.issued","2007"],["dc.description.abstract","The germanium hydroxide complexes LGe(mu-O)M(THF)Cp(2) (M = Yb, 1; Y, 2; L = HC[C(Me)N(Ar)](2); Ar = 2,6-iPr(2)C(6)H(3)) were prepared by the reaction of LGeOH with Cp(3)M (M = Yb, Y) in THF at ambient temperature with the elimination of HCp. 1 and 2 are pale-yellow solids. Both compounds crystallize isotypically as monomers in a triclinic space group P (1) over bar (pseudo- merohedrally twinned, two independent molecules) and were found to be stable in the solid state and in solution at room temperature. The six-membered C(3)N(2)Ge rings in 1 and 2 display a boat conformation with the germanium and the gamma-C out-of-plane. The Ge-O-M skeleton exhibits a bent arrangement (angles 151-154 degrees). The (1)H NMR investigation of 2 confirmed that the solid-state structure is also found in solution."],["dc.identifier.doi","10.1021/ic701262x"],["dc.identifier.isi","000251393900050"],["dc.identifier.pmid","17979270"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/47479"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.title","Synthesis and structural characterization of monomeric heterobimetallic oxides with a Ge(II)-O-M skeleton (M = Yb, Y)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4304"],["dc.bibliographiccitation.issue","19"],["dc.bibliographiccitation.journal","Tetrahedron"],["dc.bibliographiccitation.lastpage","4312"],["dc.bibliographiccitation.volume","64"],["dc.contributor.author","Widjaja, Tien"],["dc.contributor.author","Fitjer, Lutz"],["dc.contributor.author","Meindl, Kathrin"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.date.accessioned","2018-11-07T11:15:10Z"],["dc.date.available","2018-11-07T11:15:10Z"],["dc.date.issued","2008"],["dc.description.abstract","A beta-hydroxy ketone with a helical carbon skeleton of five 1,2-spiroannelated cyclopentane rings is the main product of a Lewis acid catalyzed rearrangement of suitable sized alpha-hydroxy epoxides followed by an in situ equilibration via retro aldol reactions. Various attempts of a conversion to the title hydrocarbon failed. (c) 2008 Elsevier Ltd. All rights reserved."],["dc.identifier.doi","10.1016/j.tet.2008.02.073"],["dc.identifier.isi","000255585600019"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/54307"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Pergamon-elsevier Science Ltd"],["dc.relation.issn","0040-4020"],["dc.title","Helical primary structures of 1,2-spiroannelated five-membered rings: attempted synthesis of (+/-)-tetraspiro[4.0.0.0.4.3.3.3]heneicosane"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1801"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","1805"],["dc.bibliographiccitation.volume","52"],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Schwarzer, Martin C."],["dc.contributor.author","Frenking, Gernot"],["dc.contributor.author","Tkach, Igor"],["dc.contributor.author","Wolf, Hilke"],["dc.contributor.author","Kratzert, Daniel"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Niepoetter, Benedikt"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:30:22Z"],["dc.date.available","2018-11-07T09:30:22Z"],["dc.date.issued","2013"],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft [RO 224/60-1]; DNRF"],["dc.identifier.doi","10.1002/anie.201204487"],["dc.identifier.isi","000314650600037"],["dc.identifier.pmid","23280727"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/31289"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.relation.issn","1433-7851"],["dc.title","Conversion of a Singlet Silylene to a stable Biradical"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","967"],["dc.bibliographiccitation.issue","2"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","972"],["dc.bibliographiccitation.volume","60"],["dc.contributor.author","Jung, Jochen"],["dc.contributor.author","Legendre, Christina M."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2021-06-01T09:41:34Z"],["dc.date.available","2021-06-01T09:41:34Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1021/acs.inorgchem.0c03085"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/84963"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.relation.eissn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","Exchange Coupling in Binuclear Manganese and Cobalt Complexes with the Tetraimido Sulfate Anion [S(N t Bu) 4 ] 2–"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","7000"],["dc.bibliographiccitation.issue","10"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","7009"],["dc.bibliographiccitation.volume","58"],["dc.contributor.author","Paesch, Alexander N."],["dc.contributor.author","Kreyenschmidt, Anne-Kathrin"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2020-12-10T15:22:38Z"],["dc.date.available","2020-12-10T15:22:38Z"],["dc.date.issued","2019"],["dc.identifier.doi","10.1021/acs.inorgchem.9b00629"],["dc.identifier.eissn","1520-510X"],["dc.identifier.issn","0020-1669"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/73480"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.title","Side-Arm Functionalized Silylene Copper(I) Complexes in Catalysis"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]