Roesky, Herbert W.

[["dc.bibliographiccitation.firstpage","231"],["dc.bibliographiccitation.journal","Phosphorus, Sulfur, and Silicion"],["dc.bibliographiccitation.lastpage","237"],["dc.bibliographiccitation.volume","84"],["dc.contributor.author","Pandey, Sushil K."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Schmidt, Hans Georg"],["dc.contributor.author","Noltemeyer, Mathias"],["dc.date.accessioned","2019-07-09T11:52:17Z"],["dc.date.available","2019-07-09T11:52:17Z"],["dc.date.issued","1994"],["dc.description.abstract","The reaction of the acyclic phosphazene ligand, HNP(NMe2)2NSiMe32 (1) with NH4VO3 in 1:1 molar ratio resulted in the formation of an ionic species NP(NMe2)2NH2+2 VO4(SiMe3)2- (2) in quantitative yield. The reaction shows the migration of silyl group from the terminal nitrogen atoms of the phosphazene ligand 1 to the oxygen of the vanadyl group. Compound 2 crystallizes as monomer in the solid state. The X-ray structure of the phosphazenium salt, NP(NMe2)2NH2+2Cl- (3) has also been described which crystallizes as a polymeric zig-zag chain in the solid state."],["dc.identifier.doi","10.1080/10426509308034336"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60145"],["dc.language.iso","en"],["dc.subject.ddc","540"],["dc.title","Functionalization of the Classical Oxoanion VO43- by Bissilylated Phosphazene Ligand: Syntheses and X-ray Structure"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]