Now showing 1 - 2 of 2
  • 1993Journal Article
    [["dc.bibliographiccitation.firstpage","3447"],["dc.bibliographiccitation.issue","22"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","3451"],["dc.contributor.author","Hasselbring, Reinhard"],["dc.contributor.author","Pandey, Sushil K."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Steiner, Alexander"],["dc.date.accessioned","2009-07-03T11:02:11Z"],["dc.date.accessioned","2021-10-27T13:12:08Z"],["dc.date.available","2009-07-03T11:02:11Z"],["dc.date.available","2021-10-27T13:12:08Z"],["dc.date.issued","1993"],["dc.description.abstract","The reaction of HN[P(NMe2)2NSiMe3]2 with NaH and KH in 1 : 1 molar ratio yielded a dimer {NaN[P(NMe2)2NSiMe3]2}21 and a polymer {KN[P(NMe2)2NSiMe3]22 with a zigzag chain structure, respectively. The reaction of Ca[N(SiMe3)2]2·2thf (thf = tetrahydrofuran) with the phosphazene in 1 : 2 molar ratio in hexane resulted in the formation of a monomeric spirocyclic phosphazene complex Ca{N[P(NMe2)2NSiMe3]2}23 where the mode of chelation is tridentate. The crystal structures of 1–3 have been determined."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1039/DT9930003447"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3392"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91662"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Metallation of the acyclic phosphazene ligand HN[P(NMe2)2NSiMe3]2. Synthesis and crystal structure of {NaN[P(NMe2)2NSiMe3]2}2, {KN[P(NMe2)2NSiMe3]2} and Ca{N[P(NMe2)2NSiMe3]2}2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]
    Details DOI
  • 1993Journal Article
    [["dc.bibliographiccitation.firstpage","2941"],["dc.bibliographiccitation.issue","24"],["dc.bibliographiccitation.journal","Polyhedron"],["dc.bibliographiccitation.lastpage","2945"],["dc.bibliographiccitation.volume","12"],["dc.contributor.author","Pandey, Sushil K."],["dc.contributor.author","Hasselbring, Reinhard"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2009-07-03T11:10:27Z"],["dc.date.accessioned","2021-10-27T13:11:49Z"],["dc.date.available","2009-07-03T11:10:27Z"],["dc.date.available","2010-05-06T08:15:19Z"],["dc.date.available","2021-10-27T13:11:49Z"],["dc.date.issued","1993"],["dc.description.abstract","The monosilylated acyclic phosphazene ligand Me3SiNP(NMe2)2NP(NMe2)2 NH2 (3) has been synthesized and characterized. The reaction of 3 with antimony triacetate, Sb(OOCMe3), in refluxing toluene forms a cyclic phosphazene derivative, [N{P(NMe2)2NH}2Sb(OOCMe)2 (4), which is characterized by elemental analyses, mass, IR and NMR spectroscopy and single-crystal X-ray structural analysis. Complex 4 crystallizes in the form of a cis and trans isomeric chain in the solid state."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/S0277-5387(00)80043-1"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3393"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91629"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Synthesis and x-ray structure of an isomeric cyclophosphazene complex containing antimony(III)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]
    Details DOI