Roesky, Herbert W.

[["dc.bibliographiccitation.firstpage","2238"],["dc.bibliographiccitation.issue","13"],["dc.bibliographiccitation.journal","European Journal of Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","2243"],["dc.contributor.author","Jimenez-Perez, Victor Manuel"],["dc.contributor.author","Munoz-Flores, Blanca M."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Schulz, Thomas G."],["dc.contributor.author","Pal, Aritra"],["dc.contributor.author","Beck, Tobias"],["dc.contributor.author","Yang, Zhi"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Santillan, Rosa"],["dc.contributor.author","Witt, Michael"],["dc.date.accessioned","2018-11-07T11:15:28Z"],["dc.date.available","2018-11-07T11:15:28Z"],["dc.date.issued","2008"],["dc.description.abstract","The reaction of the diaminonaphthalene dilithium salt (THF)(2)Li(2)[(NSiMe(3))(2)C(10)H(6)] with BX(3) (X = Cl, Br) in hexane provides the monomeric compounds BX[(NSiMe(3))(2)C(10)H(6)] [3 (X = Cl), 4 (X = Br)] with a tricoordinate boron atom. Attempts to reduce 3 and 4 with lithium, sodium, potassium or sodium/potassium alloy with the intention to isolate a boranide resembling a carbene were unsuccessful. However, the diaminonaphthalene dilithium salt (THF)(2)Li(2)[(NSi-iPr(3))(2)C(10)H(6)] (2) reacts with SnCl(2) in THF to provide the carbene analog 5. Compounds 2, 3 and 5 were characterized by single-crystal X-ray structure analysis. The structures of 3 and 5 show the naphthalene backbone to be nearly planar, while the heterocycles in 3 and 5 containing boron and tin atoms, respectively, have torsion angles (3: 30.06 degrees; 5: 37.27 degrees) with respect to the naphthalene plane. The boron atom has a trigonal-planar environment, and the stannylene tin-nitrogen bonds form a very acute N-Sn-N angle of 92.2 degrees. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)."],["dc.identifier.doi","10.1002/ejic.200800073"],["dc.identifier.isi","000255854400015"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/54373"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-blackwell"],["dc.relation.issn","1434-1948"],["dc.title","Monomeric boron and tin(II) heterocyclic derivatives of 1,8-diaminonaphthalenes: Synthesis, characterization and X-ray structures"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]