Stalke, Dietmar

[["dc.bibliographiccitation.firstpage","2339"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","2341"],["dc.contributor.author","Bhaduri, Sumit"],["dc.contributor.author","Gopalkrishnan, Kalpathi S."],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Clegg, William"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2009-06-10T11:46:14Z"],["dc.date.accessioned","2021-10-27T13:11:50Z"],["dc.date.available","2009-06-10T11:46:14Z"],["dc.date.available","2021-10-27T13:11:50Z"],["dc.date.issued","1983"],["dc.description.abstract","Triruthenium dodecacarbonyl [Ru3(CO)12] reacts with nitrobenzene to give [Ru3(CO)10(NPh)](3) and [Ru3(CO)9(NPh)2](4) in low yields, accompanied by formation of CO2. The solution i.r. spectrum of (3) suggests the presence of triply bridging NPh and CO groups, confirmed by a single-crystal X-ray structure determination; space group P21/n, a= 12.457(1), b= 11.428(1), c= 29.234(2)Å, = 92.38(1)°, Z= 8, and R= 0.036 for 4 817 unique observed reflections. The two independent molecules differ slightly in the relative orientations of the phenyl groups. Mean bond lengths include Ru–Ru 2.746(5), Ru–µ-C 2.172(8), and Ru–µ-N 2.055(5)Å. The i.r. Spectra of complexes (3) and (4) are discussed in terms of a molecular-orbital description of M3(CO)9 moieties."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1039/DT9830002339"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3262"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91631"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.publisher","Chemical Society"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","Anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Reaction of triruthenium dodecacarbonyl with nitrobenzene and structure of µ3-phenylnitrene-triruthenium decacarbonyl, [Ru3(CO)10(µ3-NPh)] : Notes. Reaction of triruthenium dodecacarbonyl with nitrobenzene and structure of µ3-phenylnitrene-triruthenium decacarbonyl, [Ru3(CO)10(µ3-NPh) : Notes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]