Linser, Rasmus

[["dc.bibliographiccitation.firstpage","5230"],["dc.bibliographiccitation.issue","9"],["dc.bibliographiccitation.journal","Chemical Science"],["dc.bibliographiccitation.lastpage","5234"],["dc.bibliographiccitation.volume","6"],["dc.contributor.author","Chandra Mondal, Kartik"],["dc.contributor.author","Roy, Sudipta"],["dc.contributor.author","Dittrich, Birger"],["dc.contributor.author","Maity, Bholanath"],["dc.contributor.author","Dutta, Sayan"],["dc.contributor.author","Koley, Debasis"],["dc.contributor.author","Vasa, Suresh Kumar"],["dc.contributor.author","Linser, Rasmus"],["dc.contributor.author","Dechert, Sebastian"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2015-07-17T07:46:46Z"],["dc.date.accessioned","2021-10-27T13:12:19Z"],["dc.date.available","2015-07-17T07:46:46Z"],["dc.date.available","2021-10-27T13:12:19Z"],["dc.date.issued","2015"],["dc.description.abstract","Silicondiselenide is a semiconductor and exists as an insoluble polymer (SiSe2)n which is prepared by reacting elemental silicon with selenium powder in the temperature range of 400–850 °C. Herein, we report on the synthesis, isolation, and characterization of carbene stabilized molecular silicondiselenide in the form of (cAAC)2Si2Se4 (3) [cAAC = cyclic alkyl(amino)carbene]. 3 is synthesized via reaction of diatomic silicon(0) compound (cAAC)2Si2 (2) with black selenium powder at −78 °C to room temperature. The intensely orange colored compound 3 is soluble in polar organic solvents and stable at room temperature for a month under an inert atmosphere. 3 decomposes above 245 °C. The molecular structure of 3 has been confirmed by X-ray single crystal diffraction. It is also characterized by UV-vis, IR, Raman spectroscopy and mass spectrometry. The stability, bonding, and electron density distributions of 3 have been studied by theoretical calculations."],["dc.identifier.doi","10.1039/C5SC01516B"],["dc.identifier.isi","000359214100017"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/11973"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91681"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","2041-6539"],["dc.relation.issn","2041-6520"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","silicondiselenide; semiconducting; soluble molecular variant"],["dc.title","A soluble molecular variant of the semiconducting silicondiselenide"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]