Kozhushkov, Sergei I.

[["dc.bibliographiccitation.firstpage","1409"],["dc.bibliographiccitation.issue","7"],["dc.bibliographiccitation.journal","European Journal of Organic Chemistry"],["dc.bibliographiccitation.lastpage","1415"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Yufit, Dmitry S."],["dc.contributor.author","Boese, R."],["dc.contributor.author","Blaser, D."],["dc.contributor.author","Schreiner, Peter R."],["dc.contributor.author","de Meijere, Armin"],["dc.date.accessioned","2018-11-07T11:15:09Z"],["dc.date.available","2018-11-07T11:15:09Z"],["dc.date.issued","2005"],["dc.description.abstract","1,3-Diisopropyl- (4), 1-tert-butyl-3-isopropyl- (5), 1,3,5-triisopropyl- (6) and 1-tert-butyl-3,5-diisopropyladamantane (7) were prepared from the same synthetic precursor - methyl 3-isopropyladamantane-1-carboxylate (10) - applying a standard set of repetitive procedures in 65, 77, 24, and 34 % overall yield, respectively. 1,3,5,7-Tetraethenyladamantane (17) was obtained in two steps - Swern oxidation and Wittig olefination - from 1,3,5,7-tetrakis(hydroxymethyl)adamantane (15) in 45 % overall yield and converted into 1,3,5,7-tetracy-clopropyladamantane (8) by fourfold cyclopropanation with diazomethane catalyzed by palladium(II) acetate (91 % yield). Hydrogenolysis of 8 over a platinum catalyst furnished 1,3,5,7-tetraisopropyladamantane (9) in quantitative yield. 1-Isopropyladamantane (3) as well as the hydrocarbons 4-7 did not give any crystals suitable for X-ray crystal structure analysis, even when using the Optical Heating and Crystallization Device (OHCD). This method was rather successful when applied to the tetravinyl derivative 17, X-ray crystal structure analysis of which revealed an approximately C-2- symmetric conformation in the solid state at 150 K However, no well-defined orientation was detected for the cyclopropyl groups in 8, and the molecules were severely disordered even at 30(1) K. In contrast to this, X-ray crystal structure analysis of the tetraisopropyl derivative 9 revealed an S-4-symmetric conformation for this hydrocarbon at 203 K. ((c) Wiley-VCH Verlag GmbH 1 Co. KGaA, 69451 Weinheim, Germany, 2005)."],["dc.identifier.doi","10.1002/ejoc.200400731"],["dc.identifier.isi","000228260600022"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/54303"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1434-193X"],["dc.title","Conformational studies on oligosubstituted adamantane derivatives - Structural features of tetravinyl-, tetracyclopropyl-, and tetraisopropyladamantane"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","no"],["dc.bibliographiccitation.issue","16"],["dc.bibliographiccitation.journal","ChemInform"],["dc.bibliographiccitation.lastpage","no"],["dc.bibliographiccitation.volume","32"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Kostikov, Rafael R."],["dc.contributor.author","Molchanov, Alexander P."],["dc.contributor.author","Boese, Roland"],["dc.contributor.author","Benet-Buchholz, Jordi"],["dc.contributor.author","Schreiner, Peter R."],["dc.contributor.author","Rinderspacher, Christopher"],["dc.contributor.author","Ghiviriga, Ion"],["dc.contributor.author","de Meijere, Armin"],["dc.date.accessioned","2021-12-08T12:28:48Z"],["dc.date.available","2021-12-08T12:28:48Z"],["dc.date.issued","2001"],["dc.identifier.doi","10.1002/chin.200116063"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/95841"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-476"],["dc.relation.eissn","1522-2667"],["dc.relation.issn","0931-7597"],["dc.rights.uri","http://doi.wiley.com/10.1002/tdm_license_1.1"],["dc.title","ChemInform Abstract: Tetracyclopropylmethane: A Unique Hydrocarbon with S4 Symmetry."],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","697"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Organic Letters"],["dc.bibliographiccitation.lastpage","700"],["dc.bibliographiccitation.volume","5"],["dc.contributor.author","Fokin, Andrey A."],["dc.contributor.author","Schreiner, Peter R."],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Sattelmeyer, K. W."],["dc.contributor.author","Schaefer, H. F."],["dc.contributor.author","de Meijere, Armin"],["dc.date.accessioned","2018-11-07T10:40:07Z"],["dc.date.available","2018-11-07T10:40:07Z"],["dc.date.issued","2003"],["dc.description.abstract","[GRAPHICS] Highly symmetric aliphatic hydrocarbons such as D(4h)-[4]rotane do not necessarily have degenerate HOMOs. According to our predictions based on high-level computations, its radical cation should display a highly delocalized D(4h)-symmetric structure, in contrast to its Jahn-Teller distorted cousin, the radical cation of [3]rotane, which exists in two distonic localized forms with C(2v) and C(s) symmetry."],["dc.identifier.doi","10.1021/ol027479f"],["dc.identifier.isi","000181233000024"],["dc.identifier.pmid","12605493"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/46221"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","1523-7060"],["dc.title","Delocalizations in sigma-radical cations: The intriguing structures of ionized [n]rotanes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","053208"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Journal of Vacuum Science & Technology A"],["dc.bibliographiccitation.volume","39"],["dc.contributor.author","Willey, Trevor M."],["dc.contributor.author","Lee, Jonathan R. I."],["dc.contributor.author","Brehmer, Daniel"],["dc.contributor.author","Paredes Mellone, Oscar A."],["dc.contributor.author","Landt, Lasse"],["dc.contributor.author","Schreiner, Peter R."],["dc.contributor.author","Fokin, Andrey A."],["dc.contributor.author","Tkachenko, Boryslav A."],["dc.contributor.author","de Meijere, Armin"],["dc.contributor.author","Kozhushkov, Sergei"],["dc.contributor.author","van Buuren, Anthony W."],["dc.date.accessioned","2021-09-01T06:38:33Z"],["dc.date.available","2021-09-01T06:38:33Z"],["dc.date.issued","2021"],["dc.identifier.doi","10.1116/6.0001150"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/88958"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-455"],["dc.relation.eissn","1520-8559"],["dc.relation.issn","0734-2101"],["dc.title","X-ray spectroscopic identification of strain and structure-based resonances in a series of saturated carbon-cage molecules: Adamantane, twistane, octahedrane, and cubane"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.issue","48"],["dc.bibliographiccitation.journal","ChemInform"],["dc.bibliographiccitation.volume","34"],["dc.contributor.author","de Meijere, Armin"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Fokin, Andrey A."],["dc.contributor.author","Emme, Ingo"],["dc.contributor.author","Redlich, Stefan"],["dc.contributor.author","Schreiner, Peter R."],["dc.date.accessioned","2021-12-08T12:29:11Z"],["dc.date.available","2021-12-08T12:29:11Z"],["dc.date.issued","2003"],["dc.identifier.doi","10.1002/chin.200348230"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/95984"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-476"],["dc.relation.eissn","1522-2667"],["dc.relation.issn","0931-7597"],["dc.rights.uri","http://doi.wiley.com/10.1002/tdm_license_1.1"],["dc.title","New Structurally Interesting Cyclopropane Derivatives: A World of Wonders and Surprises"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","549"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Pure and Applied Chemistry"],["dc.bibliographiccitation.lastpage","562"],["dc.bibliographiccitation.volume","75"],["dc.contributor.author","de Meijere, Armin"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Fokin, Andrey A."],["dc.contributor.author","Emme, I."],["dc.contributor.author","Redlich, Sandra"],["dc.contributor.author","Schreiner, Peter R."],["dc.date.accessioned","2018-11-07T10:39:27Z"],["dc.date.available","2018-11-07T10:39:27Z"],["dc.date.issued","2003"],["dc.description.abstract","The structurally intriguing [4]- and [5]triangulanes have been prepared in enantiomerically pure form. Their surprisingly high specific rotations are well reproduced by DFT/SCI computations and stem from the fact that these hydrocarbons essentially are sigma-helicenes (i.e., rigidly held helical arrangements of sigma-bonds). Some light is shed on the properties of radical cations derived from [3]- and [4]rotanes. While the former adopts C-s or C-2v symmetry, the latter retains the D-4h symmetry of the neutral hydrocarbon, according to high-level computations. Experimental and computational evidence is also presented that the anti-aromatic cyclopentadienyl cation is stabilized as a singlet ground state by five cyclopropyl substituents. Yet, the three cyclopropyl groups in tricyclopropylamine do not favor the formation of its radical cation, because they are not in the proper orientation. When this amine radical cation is generated by cobalt gamma-irradiation in a Freon matrix, evidence for a significant conformational change is obtained by EPR spectroscopy. Finally, the conformational dynamics of the newly prepared crowded molecules tetracyclopropyl- and tetraisopropyl-methane are discussed."],["dc.identifier.doi","10.1351/pac200375050549"],["dc.identifier.isi","000183076200003"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/46051"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Int Union Pure Applied Chemistry"],["dc.publisher.place","Res triangle pk"],["dc.relation.conference","16th International Conference on Physical Organic Chemistry (ICPOC-16)"],["dc.relation.eventlocation","SAN DIEGP, CALIFORNIA"],["dc.relation.issn","0033-4545"],["dc.title","New structurally interesting cyclopropane derivatives. A world of wonders and surprises"],["dc.type","conference_paper"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","6175"],["dc.bibliographiccitation.issue","21"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","6184"],["dc.bibliographiccitation.volume","11"],["dc.contributor.author","de Meijere, Armin"],["dc.contributor.author","Lee, C. H."],["dc.contributor.author","Kuznetsov, M. A."],["dc.contributor.author","Gusev, D. V."],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Fokin, Andrey A."],["dc.contributor.author","Schreiner, Peter R."],["dc.date.accessioned","2018-11-07T10:54:57Z"],["dc.date.available","2018-11-07T10:54:57Z"],["dc.date.issued","2005"],["dc.description.abstract","The synthesis of the (CH),, hydrocarbon [D-3d]-octahedrane (heptacyclo[6.4.0.0(2,4). 0(3,7).0(5,12).0(6,10).0(9,11)]dodecane) 1 and its selective functionalization retaining the hydrocarbon cage is described. The B3LYP/6-311+G strain energy of 1 is 83.7 kcal mol(-1) (4.7 kcal mol(-1) per C-C bond) which is significantly higher than that of the structurally related (CH)16 [D-4d]-decahedrane 2 (75.4 kcal mol(-1); 3.1 kcal mol(-1i`) per C-C bond) and (CH)(20) [I-h]-dodecahedrane 3 (51.5 kcal mol(-1); 1.7 kcal mol(-1) per C-C bond); the heats of formation for 1-3 computed according to homodesmotic equations are 52, 35, and 4 kcal mol(-1). Catalytic hydrogenation of 1 leads to consecutive opening of the two cyclopropane rings to give C-2-bisseco-octa-hedrane (pentacyclo[6.4. 0.0(2.6).0(3.11).0(4.9)]- dodecane) 16 as the major product. Although 1 is highly strained, its carbon skeleton is kinetically quite stable: Upon heating, 1 does not decompose until above 180 degrees C. The B3LYP/6-31G barriers for the S,2 attack of the tBuO(.) and Br3C. radicals on a carbon atom of one of the cyclopropane fragments (Delta G(298) , = 27-28 kcal mol-1) are higher 29 than those for hydrogen atom abstraction. The latter barriers are virtually identical for the abstraction from the C-1-H and C-2-H positions with the tBuO(.) radical (Delta G(298)' = 17.4 and 298 17.9 kcal mol(-1), respectively), but significantly different for the reaction at these positions with the Br3C. radical (Delta G(298) = 18.8 and 21.0 kcal mol(-1)). 298 These computational results agree well with experiments, in which the chlorination of 1 with tert-butyl hypochlorite gave a mixture of 1- and 2-chlorooctahedranes (ratio 3:2). The bromination with carbon tetrabromide under phase-transfer catalytic (PTC) conditions (nBu(4)NBr/NaOH) selectively gave 1-bromooctahedrane in 43% isolated yield. For comparison, the PTC bromination was also applied to 2,4-dehydroadamantane yielding 54% 7-bromo2,4-dehydroadamantane."],["dc.identifier.doi","10.1002/chem.200500472"],["dc.identifier.isi","000232960500006"],["dc.identifier.pmid","16075443"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/49679"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","0947-6539"],["dc.title","Preparation and reactivity of [D-3d]-octahedrane: The most stable (CH)(12) hydrocarbon"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","ChemInform"],["dc.bibliographiccitation.volume","35"],["dc.contributor.author","de Meijere, Armin"],["dc.contributor.author","Lee, Chih-Hung"],["dc.contributor.author","Bengtson, Bengt"],["dc.contributor.author","Pohl, Ehmke"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Schreiner, Peter R."],["dc.contributor.author","Boese, Roland"],["dc.contributor.author","Haumann, Thomas"],["dc.date.accessioned","2021-12-08T12:29:12Z"],["dc.date.available","2021-12-08T12:29:12Z"],["dc.date.issued","2004"],["dc.identifier.doi","10.1002/chin.200406061"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/95992"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-476"],["dc.relation.eissn","1522-2667"],["dc.relation.issn","0931-7597"],["dc.rights.uri","http://doi.wiley.com/10.1002/tdm_license_1.1"],["dc.title","Preparation and Properties of Centrally Bridgehead-Substituted Hexacyclo[4.4.0.02,1.03,5.04,8.07,9]decanes (“Diademanes”) and Related (CH)10 Hydrocarbons."],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","5481"],["dc.bibliographiccitation.issue","22"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","5488"],["dc.bibliographiccitation.volume","9"],["dc.contributor.author","Meijere, Armin de"],["dc.contributor.author","Lee, C. H."],["dc.contributor.author","Bengtson, B."],["dc.contributor.author","Pohl, E."],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Schreiner, Peter R."],["dc.contributor.author","Boese, R."],["dc.contributor.author","Haumann, T."],["dc.date.accessioned","2018-11-07T10:34:38Z"],["dc.date.available","2018-11-07T10:34:38Z"],["dc.date.issued","2003"],["dc.description.abstract","6-Trimethylsilyl- (1b), 6-hydroxymethyl- (1e), and 6-methyldiademane (If) have been prepared by irradiation of the corresponding snoutene derivatives, in 23, 2.8, and 17% yields, respectively, together with the isomeric 1-trimethylsilyl- (10b) and 1-methyldiademane (10f) (8 and 2% yields, respectively). The starting 4-trimethylsilyl-(9b) and 4-(trimethylsilyloxymethyl)snoutene (9d) were prepared from the correspondingly substituted cyclooctatetraenes 4b and 4c in several steps in 20 and 8% overall yields, respectively. Upon heating, as well as under the conditions of gas-chromatographic separation, diademanes 1b, 10b, If, and 10f rearranged into the corresponding C10- and C1-substituted triquinacenes 3b, 3f, 11b, and 11f, respectively. Rough kinetic measurements of these rearrangements indicate some acceleration of the reaction caused by the presence of a methyl substituent and retardation by that of a trimethylsilyl substituent, relative to the parent diademane 1a. At this insufficient precision, however, the activation energies (E-a) of 29.0 and 28.1 kcal mol(-1), respectively, are essentially the same as that reported for 1a (28.3 kcal mol(-1)). An X-ray crystal structure analysis of trimethylsilylsnoutene 9b revealed a significant lengthening of the distal (with respect to the substituent) bond (1.534 versus 1.505 Angstrom) in the unsubstituted cyclopropane ring. In the substituted cyclopropane ring, the two proximal bonds are lengthened (1.530 Angstrom) and the distal bond is slightly shortened (1.492 Angstrom). This indicates a small, but significant electron-withdrawing effect of the trimethylsilyl group in 9b. An X-ray crystal structure analysis of 6-hydroxymethyldiademane I e showed pronounced alternation of the bond lengths in the six-membered ring, with 1.494(4) between and 1.539(4) Angstrom within the three cyclopropane moieties, in close agreement with computations at different theoretical levels. This structural feature corroborates a predisposition of the tris-sigma-homobenzene skeleton of this molecule in the ground state to undergo the facile [sigma(s)(2) + sigma(s)(2) + sigma(s)(2)] cycloreversion to the triquinacene skeleton observed for the parent diademane 1a, its derivative 1b and If, as well as for other tris-sigma-homobenzene derivatives."],["dc.identifier.doi","10.1002/chem.200305114"],["dc.identifier.isi","000186886800006"],["dc.identifier.pmid","14639631"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/44918"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.relation.issn","0947-6539"],["dc.title","Preparation and properties of centrally bridgehead-substituted hexacyclo[4.4.0.0(2,1).0(3,5).0(4,8).0(7,9)]decanes (\"diademanes\") and related (CH)(10) hydrocarbons"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2590"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","European Journal of Organic Chemistry"],["dc.bibliographiccitation.lastpage","2600"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Preuss, Thomas"],["dc.contributor.author","Yufit, Dmitry S."],["dc.contributor.author","Howard, Judith A. K."],["dc.contributor.author","Meindl, Kathrin"],["dc.contributor.author","Ruehl, Stephan"],["dc.contributor.author","Yamamoto, Chiyo"],["dc.contributor.author","Okamoto, Yoshio"],["dc.contributor.author","Schreiner, Peter R."],["dc.contributor.author","Rinderspacher, B. Christopher"],["dc.contributor.author","De Meijere, Armin"],["dc.date.accessioned","2018-11-07T09:48:34Z"],["dc.date.available","2018-11-07T09:48:34Z"],["dc.date.issued","2006"],["dc.description.abstract","Epoxidation of barrelene (3) with a neutralized solution of Oxone (R) gave the barrelene trisepoxide 6 in 82% isolated yield, while lead tetraacetate promoted aziridination of 3 with two equiv. of N-aminophthalimide gave a mixture of mono-7 and bis(aziridine) endo,exo-B, which were isolated in 67 and 8% yield, respectively. Fourfold repetition of this aziridination gave the bis(aziridines) exo,exo- and endo,exo8 along with the trisaziridine 9 in 21, 8 and 19% yield, respectively. Epoxidation of 7 and endo,exo-8 with buffered m-chloroperbenzoic acid furnished the dioxaazatrishomobarrelene 10 and oxadiazatrishomobarrelene 11 in 36 and 62% yield, respectively. The structures of triheteratrishomobarrelenes 6 and 9 were established by X-ray crystallography. Upon treatment with (BF3Et2O)-Et-. at -20 degrees C (for 6) or with the strongly acidic ion exchange resin Amberlyst 15 at ambient or elevated temperatures (for 9-11), these triheteratrishomobarrelenes rearrange to give the triheteratrishomocubanes rac-12 to rac-15, as proved by X-ray crystal structure analysis of rac-13, in 75-100% yield. The enantiomeric pairs of trioxa-12 and triazatrishomocubane 13 were separated by preparative HPLC on a chiral column. 12 exhibited specific rotations of [alpha](D)(25) = +196 and [alpha](365)(25) = +652 (c = 0.497, CHCl3) for the firstly eluted and [alpha](D)(25) = -173 and [alpha](365)(25) = -608 (c = 0.503, CHCl3) for the secondly eluted enantiomer; 13 had [alpha](D)(25) = +30 and [alpha](435)(25) CHCl3) for the firstly as well as [alpha](435)(25) =-28 and [alpha](435)(25) = -475 (c = 0.501, CHCW for the secondly eluted enantiomer. The geometry of rac-13 and the absolute configurations of (+12 and (+)-13 were determined by X-ray crystal structure analyses. According to this, (+12 and (+)-13 possess the same (1 R,3R,5R,6R,8R, 10R)-configuration. The absolute configuration of the former was also confirmed by DFT computations at the TD-B3LYP/6-31+G(d,p)//B3LYP/6-31+G(d) level of theory; the computed specific rotation for (+ 12 was -178. Computations for the elusive (all-R)-triazatrishomocubane (all-R)-13-H without phthalimidyl substituents on the nitrogen atoms disclosed that the sign of rotation is the same for the parent (all-R)-13-H and (all-R)-trioxatrishomocubane (all-R)-12 with the same absolute configuration."],["dc.identifier.doi","10.1002/ejoc.200600019"],["dc.identifier.isi","000238086000015"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/35335"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1099-0690"],["dc.relation.issn","1434-193X"],["dc.title","4,7,11-triheterotrishomocubanes - Propeller-shaped highly symmetrical chiral molecules derived"],["dc.type","review"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]