Demeshko, Serhiy V.

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[["dc.bibliographiccitation.journal","JBIC Journal of Biological Inorganic Chemistry"],["dc.bibliographiccitation.volume","19"],["dc.contributor.author","Klawitter, Iris"],["dc.contributor.author","Meyer, S."],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Meyer, Franc"],["dc.contributor.author","Bill, Eckhard"],["dc.date.accessioned","2018-11-07T09:43:09Z"],["dc.date.available","2018-11-07T09:43:09Z"],["dc.date.issued","2014"],["dc.format.extent","S482"],["dc.identifier.isi","000332835300420"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/34114"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Springer"],["dc.publisher.place","New york"],["dc.relation.conference","16th International Conference on Biological Inorganic Chemistry (ICBIC)"],["dc.relation.eventlocation","Grenoble, FRANCE"],["dc.relation.issn","1432-1327"],["dc.relation.issn","0949-8257"],["dc.title","Bioinorganic meets Organometallics: A Tetracarbene-Oxoiron(IV) Complex"],["dc.type","conference_abstract"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.journal","JBIC Journal of Biological Inorganic Chemistry"],["dc.bibliographiccitation.volume","19"],["dc.contributor.author","Dechert, Sebastian"],["dc.contributor.author","Albers, Antonia"],["dc.contributor.author","Demeshko, Serhiy V."],["dc.contributor.author","Proepper, Kevin"],["dc.contributor.author","Meyer, Franc"],["dc.contributor.author","Bill, Eckhard"],["dc.date.accessioned","2018-11-07T09:43:09Z"],["dc.date.available","2018-11-07T09:43:09Z"],["dc.date.issued","2014"],["dc.identifier.isi","000332835300373"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/34112"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Springer"],["dc.publisher.place","New York"],["dc.relation.conference","16th International Conference on Biological Inorganic Chemistry (ICBIC)"],["dc.relation.eventlocation","Grenoble, FRANCE"],["dc.title","Biomimetic [2Fe-2S] Clusters in Different Oxidation States"],["dc.type","conference_abstract"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1704"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","1707"],["dc.bibliographiccitation.volume","135"],["dc.contributor.author","Albers, Antonia"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Proepper, Kevin"],["dc.contributor.author","Dechert, Sebastian"],["dc.contributor.author","Bill, Eckhard"],["dc.contributor.author","Meyer, Franc"],["dc.date.accessioned","2018-11-07T09:28:15Z"],["dc.date.available","2018-11-07T09:28:15Z"],["dc.date.issued","2013"],["dc.description.abstract","A biomimetic [2Fe-2S] cluster has been isolated in the fully reduced diferrous form and characterized by X-ray diffraction. This completes a consistent series of synthetic analogues of protein-bound [2Fe-2S](z) redox centers (z = 2+, 1+, 0) with identical capping ligands. Fe-57 Mossbauer data of the extremely oxidation-sensitive complex compare well with those of the very few reports of all-ferrous ferredoxins and Rieske centers; they confirm the S-T = 0 ground state and establish a lower limit for the exchange coupling, -J >= 30 cm(-1)."],["dc.identifier.doi","10.1021/ja311563y"],["dc.identifier.isi","000314794400018"],["dc.identifier.pmid","23320988"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/30730"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0002-7863"],["dc.title","A Super-Reduced Diferrous [2Fe-2S] Cluster"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Nature Communications"],["dc.bibliographiccitation.volume","9"],["dc.contributor.author","Böhnke, Julian"],["dc.contributor.author","Dellermann, Theresa"],["dc.contributor.author","Celik, Mehmet Ali"],["dc.contributor.author","Krummenacher, Ivo"],["dc.contributor.author","Dewhurst, Rian D."],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Ewing, William C."],["dc.contributor.author","Hammond, Kai"],["dc.contributor.author","Heß, Merlin"],["dc.contributor.author","Bill, Eckhard"],["dc.contributor.author","Welz, Eileen"],["dc.contributor.author","Röhr, Merle I. S."],["dc.contributor.author","Mitrić, Roland"],["dc.contributor.author","Engels, Bernd"],["dc.contributor.author","Meyer, Franc"],["dc.contributor.author","Braunschweig, Holger"],["dc.date.accessioned","2020-12-10T18:09:45Z"],["dc.date.available","2020-12-10T18:09:45Z"],["dc.date.issued","2018"],["dc.identifier.doi","10.1038/s41467-018-02998-3"],["dc.identifier.eissn","2041-1723"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/15589"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/73748"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.title","Isolation of diborenes and their 90°-twisted diradical congeners"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

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[["dc.bibliographiccitation.firstpage","9770"],["dc.bibliographiccitation.issue","20"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","9776"],["dc.bibliographiccitation.volume","54"],["dc.contributor.author","Meyer, Steffen"],["dc.contributor.author","Krahe, Oliver"],["dc.contributor.author","Kupper, Claudia"],["dc.contributor.author","Klawitter, Iris"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Bill, Eckhard"],["dc.contributor.author","Neese, Frank"],["dc.contributor.author","Meyer, Franc"],["dc.date.accessioned","2018-11-07T09:50:06Z"],["dc.date.available","2018-11-07T09:50:06Z"],["dc.date.issued","2015"],["dc.description.abstract","A disulfide-bridged diiron complex with [Fe-S-S-Fe] core, which represents an isomer of the common biological [2Fe-2S] ferredoxin-type clusters, was synthesized using strongly sigma-donating macrocyclic tetracarbene capping ligands. Though the complex is quite labile in solution, single crystals were obtained, and the structure was elucidated by X-ray diffraction. The electron-rich iron-sulfur core is found to show rather unusual magnetic and electronic properties. Experimental data and density functional theory studies indicate extremely strong antiferromagnetic coupling (-J > 800 cm(-1)) between two low-spin iron(III) ions via the S-2(2-) bridge, and the intense near-IR absorption characteristic for the [Fe-S-S-Fe] core was assigned to a S -> Fe ligand-to-metal charge transfer transition."],["dc.identifier.doi","10.1021/acs.inorgchem.5b01446"],["dc.identifier.isi","000363224000015"],["dc.identifier.pmid","26445295"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/35644"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","A trans-1,2 End-On Disulfide-Bridged Iron-Tetracarbene Dimer and Its Electronic Structure"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]