Demeshko, Serhiy V.

[["dc.bibliographiccitation.firstpage","806"],["dc.bibliographiccitation.issue","2"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","816"],["dc.bibliographiccitation.volume","43"],["dc.contributor.author","Falkenhagen, Jan P."],["dc.contributor.author","Limberg, Christian"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Horn, Sebastian"],["dc.contributor.author","Haumann, Michael"],["dc.contributor.author","Braun, Beatrice"],["dc.contributor.author","Mebs, Stefan"],["dc.date.accessioned","2018-11-07T09:47:16Z"],["dc.date.available","2018-11-07T09:47:16Z"],["dc.date.issued","2014"],["dc.description.abstract","The reaction between [(TPA) Fe(MeCN)(2)](OTf)(2) and [nBu(4)N](Cp MoO3) yields the novel tetranuclear complex [(TPA) Fe(mu-Cp MoO3)](2)(OTf)(2), 1, with a rectangular [Mo-O-Fe-O-](2) core containing high-spin iron(II) centres. 1 proved to be an efficient initiator/(pre)catalyst for the autoxidation of cis-cyclooctene with O-2 to give cyclooctene epoxide. To test, which features of 1 are essential in this regard, analogues with zinc(II) and cobalt(II) central atoms, namely [(TPA)Zn(Cp MoO3)](OTf), 3, and [(TPA) Co(Cp MoO3)](OTf), 4, were prepared, which proved to be inactive. The precursor compounds of 1, [(TPA) Fe(MeCN)(2)](OTf)(2) and [nBu(4)N](Cp MoO3) as well as Cp-2 Mo2O5, were found to be inactive, too. Reactivity studies in the absence of cyclooctene revealed that 1 reacts both with O-2 and PhIO via loss of the Cp ligands to give the triflate salt 2 of the known cation [((TPA)Fe)(2)(mu-O)(mu-MoO4)](2+). The cobalt analogue 4 reacts with O-2 in a different way yielding [((TPA)Co)(2)(mu-Mo2O8)](OTf)(2), 5, featuring a Mo2O84- structural unit which is novel in coordination chemistry. The compound [(TPA) Fe(mu-MoO4)](2), 6, being related to 1, but lacking Cp ligands failed to trigger autoxidation of cyclooctene. However, initiation of autoxidation by Cp radicals was excluded via experiments including thermal dissociation of Cp-2 ."],["dc.identifier.doi","10.1039/c3dt52349g"],["dc.identifier.isi","000327894400052"],["dc.identifier.pmid","24154868"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/35073"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9234"],["dc.relation.issn","1477-9226"],["dc.title","Iron-molybdenum-oxo complexes as initiators for olefin autoxidation with O-2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2315"],["dc.bibliographiccitation.issue","13-14"],["dc.bibliographiccitation.journal","Zeitschrift für anorganische und allgemeine Chemie"],["dc.bibliographiccitation.lastpage","2322"],["dc.bibliographiccitation.volume","636"],["dc.contributor.author","Ohde, Christian"],["dc.contributor.author","Limberg, Christian"],["dc.contributor.author","Schmidt, Dennis"],["dc.contributor.author","Enders, Markus"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Knispel, Christina"],["dc.date.accessioned","2018-11-07T08:37:52Z"],["dc.date.available","2018-11-07T08:37:52Z"],["dc.date.issued","2010"],["dc.description.abstract","Employing various incompletely condensed silsesquioxanes as ligand precursors in reactions with simple oxovanadates a variety of oxovanadium silsequioxanes could be synthesised, that might be regarded as models for oxovanadium units on silica surfaces. These include a tetranuclear vanadium(IV) compound as well as two complexes where O2V+ units are coordinated to two siloxide functions as part of a silsesquioxane framework. Moreover, compounds containing Cp V(O)(2+) moieties were prepared, whose activities as polymerisation procatalysts were examined: They turned out to be moderately active for the polymerisation of ethylene. All compounds were fully characterised, in case of the tetranuclear vanadium(IV) complex this also includes the investigation of the magnetic behaviour. Moreover, for two complexes also the molecular structures could be determined with sufficient quality by X-ray diffraction."],["dc.identifier.doi","10.1002/zaac.201000287"],["dc.identifier.isi","000284209900004"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/18642"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3749"],["dc.relation.issn","0044-2313"],["dc.title","Progress in the Compilation of an Oxovanada-Silsesquioxane Portfolio and Catalytic Activity of Organometallic Representatives in Ethylene Polymerisation"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","10202"],["dc.bibliographiccitation.issue","33"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","10213"],["dc.bibliographiccitation.volume","16"],["dc.contributor.author","Ostermeier, Marc"],["dc.contributor.author","Berlin, Marie-Anne"],["dc.contributor.author","Meudtner, Robert M."],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Meyer, Franc"],["dc.contributor.author","Limberg, Christian"],["dc.contributor.author","Hecht, Stefan"],["dc.date.accessioned","2018-11-07T08:39:18Z"],["dc.date.available","2018-11-07T08:39:18Z"],["dc.date.issued","2010"],["dc.description.abstract","2,6-Bis(1,2,3-triazol-4-yl) pyridine (btp) ligands with substitution patterns ranging from strongly electron-donating to strongly electron-accepting groups, readily prepared by means of Cu-catalyzed 1,3-dipolar cycloaddition (the \"click\" reaction), were investigated with regard to their complexation behavior, and the properties of the resulting transition-metal compounds were compared. Metal-btp complexes of 1: 1 stoichiometry, that is, [Ru(btp) Cl(2)(dmso)] and [Zn(btp)Br(2)], could be isolated and were crystallo-graphically characterized: they display octahedral and trigonal-bipyramidal coordination geometries, respectively, and exhibit high aggregation tendencies due to efficient p-p stacking leading to low solubilities. Metal-btp complexes of 1: 2 stoichiometry, that is, [Fe(btp)(2)](2+) and [Ru(btp)(2)](2+), could also be synthesized and their metal centers show the expected octahedral coordination spheres. The iron compounds exhibit quite a complex magnetic behavior in the solid state including spin crossover near room temperature, and hysteresis and locking into high-spin states on tempering at 400 K, depending on the substituents on the btp ligands. Cyclic voltammetry studies of [Ru(btp)(2)](2+) reveal strong modulation of the oxidation potentials by more than 0.6 V and a clear linear correlation to the Hammett constant (sigma(para)) of the substituent at the pyridine core. Isothermal titration calorimetry was used to measure the thermodynamics of the Fe(II)-btp complexation process and enabled accurate determination of the complexation enthalpies, which display a linear relationship with the spara values for the terminal phenyl substituents. Detailed NMR spectroscopic studies finally revealed that in the case of FeII complexation, dynamics are rapid for all investigated btp derivatives in acetonitrile, while replacing Fe(II) by Ru(II) or changing the solvent to dichloromethane effectively slows down ligand exchange. The results nicely demonstrate the utility of substituent parameters, originally developed for linear free-energy relationships to explain reactivity in organic reactions, in coordination chemistry, and to illustrate the potential to custom-design btp ligands and complexes thereof with predictable properties. The fast equilibration of the [Fe(btp)(2)](2+) complexes together with their tunable stability and interesting magnetic properties should enable the design of dynamic metallosupramolecular materials with advantageous properties."],["dc.identifier.doi","10.1002/chem.201000721"],["dc.identifier.isi","000282156700032"],["dc.identifier.pmid","20658498"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/18960"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-blackwell"],["dc.relation.issn","0947-6539"],["dc.title","Complexes of Click-Derived Bistriazolylpyridines: Remarkable Electronic Influence of Remote Substituents on Thermodynamic Stability as well as Electronic and Magnetic Properties"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","5155"],["dc.bibliographiccitation.issue","19"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","5158"],["dc.bibliographiccitation.volume","52"],["dc.contributor.author","Pinkert, Denise"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Schax, Fabian"],["dc.contributor.author","Braun, Beatrice"],["dc.contributor.author","Meyer, Franc"],["dc.contributor.author","Limberg, Christian"],["dc.date.accessioned","2018-11-07T09:29:59Z"],["dc.date.available","2018-11-07T09:29:59Z"],["dc.date.issued","2013"],["dc.identifier.doi","10.1002/anie.201209650"],["dc.identifier.isi","000318799800030"],["dc.identifier.pmid","23512618"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/31190"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1433-7851"],["dc.title","A Dinuclear Molecular Iron(II) Silicate with Two High-Spin Square-Planar FeO4 Units"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","10275"],["dc.bibliographiccitation.issue","44"],["dc.bibliographiccitation.journal","Chemical Science"],["dc.bibliographiccitation.lastpage","10282"],["dc.bibliographiccitation.volume","10"],["dc.contributor.author","Schluschaß, Bastian"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Franke, Alicja"],["dc.contributor.author","Herwig, Christian"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Ivanovic-Burmazovic, Ivana"],["dc.contributor.author","Limberg, Christian"],["dc.contributor.author","Schneider, Sven"],["dc.contributor.author","Telser, Joshua"],["dc.date.accessioned","2021-06-01T10:50:53Z"],["dc.date.available","2021-06-01T10:50:53Z"],["dc.date.issued","2019"],["dc.description.abstract","An N 2 -bridged ditungsten complex is presented that undergoes N 2 -splitting or hydrogen evolution upon protonation depending on the acid and reaction conditions. Spectroscopic, kinetic and computational results emphasize the impact of hydrogen bonding on the reaction selectivity."],["dc.description.abstract","Mo complexes are currently the most active catalysts for nitrogen fixation under ambient conditions. In comparison, tungsten platforms are scarcely examined. For active catalysts, the control of N 2 vs. proton reduction selectivities remains a difficult task. We here present N 2 splitting using a tungsten pincer platform, which has been proposed as the key reaction for catalytic nitrogen fixation. Starting from [WCl 3 (PNP)] (PNP = N(CH 2 CH 2 P t Bu 2 ) 2 ), the activation of N 2 enabled the isolation of the dinitrogen bridged redox series [(N 2 ){WCl(PNP)} 2 ] 0/+/2+ . Protonation of the neutral complex results either in the formation of a nitride [W(N)Cl( H PNP)] + or H 2 evolution and oxidation of the W 2 N 2 core, respectively, depending on the acid and reaction conditions. Examination of the nitrogen splitting vs. proton reduction selectivity emphasizes the role of hydrogen bonding of the conjugate base with the protonated intermediates and provides guidelines for nitrogen fixation."],["dc.identifier.doi","10.1039/C9SC03779A"],["dc.identifier.eissn","2041-6539"],["dc.identifier.issn","2041-6520"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16963"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/86812"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.notes.intern","Merged from goescholar"],["dc.relation.eissn","2041-6539"],["dc.relation.issn","2041-6520"],["dc.rights","CC BY 3.0"],["dc.rights.uri","https://creativecommons.org/licenses/by/3.0"],["dc.title","Selectivity of tungsten mediated dinitrogen splitting vs. proton reduction"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","875"],["dc.bibliographiccitation.issue","7"],["dc.bibliographiccitation.journal","Chemical Communications"],["dc.bibliographiccitation.lastpage","878"],["dc.bibliographiccitation.volume","57"],["dc.contributor.author","Zimmermann, Philipp"],["dc.contributor.author","Kilpatrick, Alexander F. R."],["dc.contributor.author","Ar, Deniz"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Cula, Beatrice"],["dc.contributor.author","Limberg, Christian"],["dc.date.accessioned","2021-04-14T08:30:16Z"],["dc.date.available","2021-04-14T08:30:16Z"],["dc.date.issued","2021"],["dc.identifier.doi","10.1039/d0cc06983c"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/83171"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1364-548X"],["dc.relation.issn","1359-7345"],["dc.title","Electron transfer within β-diketiminato nickel bromide and cobaltocene redox couples activating CO 2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4721"],["dc.bibliographiccitation.issue","16"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","4735"],["dc.bibliographiccitation.volume","20"],["dc.contributor.author","Metzinger, Ramona"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Limberg, Christian"],["dc.date.accessioned","2018-11-07T09:41:16Z"],["dc.date.available","2018-11-07T09:41:16Z"],["dc.date.issued","2014"],["dc.description.abstract","A novel redox-active ligand, (H4LAP)-L-Ph2S (1) which was designed to be potentially pentadentate with an O,N,S,N,O donor set is described. Treatment of 1 with two equivalents of potassium hydride gave access to octametallic precursor complex [(H2LK2)-L-Ph2S-K-AP(thf)](4) (2), which reacted with FeCl3 to yield iron(III) complex [(H2LFeCl)-L-Ph2S-Fe-AP] (3). Employing Fe[N(SiMe3)(2)](3) for a direct reaction with 1 led to ligand rearrangement through CS bond cleavage and thiolate formation, finally yielding [(HLFe)-Fe-AP] (5). Upon exposure to O-2, 3 and 5 are oxidized through formal hydrogen-atom abstraction from the ligand NH units to form [(LFeCl)-L-Ph2S-Fe-SQ] (4) and [(LFe)-Fe-SQ] (6) featuring two or one coordinated iminosemiquinone moieties, respectively. Mossbauer measurements demonstrated that the iron centers remain in their +III oxidation states. Compounds 3 and 5 were tested with respect to their potential as models for the catechol dioxygenase. Thus, they were treated with 3,5-di-tert-butyl-catechol, triethylamine and O-2. It turned out that the iron-catecholate complexes react with O-2 in dichloromethane at ambient conditions through CC bond cleavage mainly forming extradiol cleavage products. Intradiol products are only side products and quinone formation becomes negligible. This observation has been rationalized by a dissociation of two donor functions upon coordination of the catecholate."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft (DFG); Humboldt-Universitat zu Berlin"],["dc.identifier.doi","10.1002/chem.201304535"],["dc.identifier.isi","000334080800027"],["dc.identifier.pmid","24623641"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/33693"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3765"],["dc.relation.issn","0947-6539"],["dc.title","A Novel Pentadentate Redox-Active Ligand and Its Iron(III) Complexes: Electronic Structures and O-2 Reactivity"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","14367"],["dc.bibliographiccitation.issue","19"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","14375"],["dc.bibliographiccitation.volume","59"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Oudsen, Jean-Pierre H."],["dc.contributor.author","Venderbosch, Bas"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Herwig, Christian"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Limberg, Christian"],["dc.contributor.author","Tromp, Moniek"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-04-14T08:31:55Z"],["dc.date.available","2021-04-14T08:31:55Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1021/acs.inorgchem.0c02134"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17871"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/83751"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","Examination of Protonation-Induced Dinitrogen Splitting by in Situ EXAFS Spectroscopy"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","9377"],["dc.bibliographiccitation.issue","30"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","9388"],["dc.bibliographiccitation.volume","14"],["dc.contributor.author","Siewert, Inke"],["dc.contributor.author","Limberg, Christian"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Hoppe, Elke"],["dc.date.accessioned","2018-11-07T11:19:41Z"],["dc.date.available","2018-11-07T11:19:41Z"],["dc.date.issued","2008"],["dc.description.abstract","A ligand that offers two parallel malonate binding sites linked by a xanthene backbone, namely, Xanthmal(2-), has been utilised to synthesise dinuclear Fe(II) complex [Fe(2)-(Xanthmal)(2)] (1). The reactivity of 1 in contact with O(2) was investigated at -40 degrees C and room temperature. After activation of O(2) through interaction with both iron centres the ligand is oxidised: at the C(alpha) position monooxygenation and peroxide formation occur, partially accompanied by C-C bond cleavage to yield alpha-keto ester groups. To reveal mechanistic details investigations concerning 1) peroxide decomposition, 2) the reactivity of a corresponding mononuclear complex, 3) the influence of monooxygenation of the ligand on the reactivity and 4) product formation in dependence on time were carried out. The results can be explained by postulating formation of high-valent Fe intermediates and ligand-to-metal electron transfer, and the mechanistic scheme derived includes several steps that mimic the (suggested) functioning of non-heme iron enzymes. In agreement with this proposal, ligand oxidation can also be performed catalytically. Furthermore, we show that via a competitive route [(Xanthmal)(2)Fe(2)O] (2) is formed, which is unreactive towards O(2) and thus is a dead end with respect to ligand oxidation. Both compounds 1 and 2 were fully characterised, and their properties are discussed."],["dc.identifier.doi","10.1002/chem.200800955"],["dc.identifier.isi","000260703900033"],["dc.identifier.pmid","18792042"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/55344"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","0947-6539"],["dc.title","A Dinuclear Iron Complex Based on Parallel Malonate Binding Sites: Cooperative Activation of Dioxygen and Biomimetic Ligand Oxidation"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1917"],["dc.bibliographiccitation.issue","14"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","1923"],["dc.contributor.author","Pilz, Maurice Frederic"],["dc.contributor.author","Limberg, Christian"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Meyer, Franc"],["dc.contributor.author","Ziemer, Burkhard"],["dc.date.accessioned","2018-11-07T11:19:47Z"],["dc.date.available","2018-11-07T11:19:47Z"],["dc.date.issued","2008"],["dc.description.abstract","With the background that certain natural systems utilize two FeII centres in their prosthetic groups for the activation of O-2, a ligand system containing two parallel beta-diiminato binding sites linked by a xanthene backbone ([(R)Xanthdim](2-) with residues R = 2,3-dimethylphenyl and 2,4-difluorophenyl at the iminato units, respectively) was investigated with respect to its FeII coordination chemistry in order to study O2 activation reactions. Hence, the corresponding lithium salts were treated with FeCl2 to yield the complexes [(Me2C6H3)Xanthdim]Fe2Cl3(Li(thf)(3)), 1 and [(F2C6H3)Xanthdim] Fe2Cl3(Li(thf)(3)), 2, respectively, each of which comprises Cl-Fe(mu-Cl)Fe-Cl(Li(thf)(3)) units. 1 and 2 indeed readily react with O-2 to give the oxides [(R)Xanthdim]Fe2Cl2O containing Fe-III-O-Fe-III moieties. Due to the electron withdrawing F atoms 2 reacts more slowly than 1. The molecular structures of 1, 2 and [(Me2C6H3)Xanthdim] Fe2Cl2O, 3, as determined by single crystal X-ray diffraction are discussed, and an investigation concerning their magnetic properties revealed an antiferromagnetic coupling of the two iron centres in all complexes; naturally, the strongest coupling is observed for 3."],["dc.identifier.doi","10.1039/b715376g"],["dc.identifier.isi","000254424200016"],["dc.identifier.pmid","18369499"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/55371"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9226"],["dc.title","Dinuclear iron complexes based on parallel beta-diiminato binding sites: syntheses, structures and reaction with O-2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]