Sheldrick, George M.

[["dc.bibliographiccitation.firstpage","2339"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","2341"],["dc.contributor.author","Bhaduri, Sumit"],["dc.contributor.author","Gopalkrishnan, Kalpathi S."],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Clegg, William"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2009-06-10T11:46:14Z"],["dc.date.accessioned","2021-10-27T13:11:50Z"],["dc.date.available","2009-06-10T11:46:14Z"],["dc.date.available","2021-10-27T13:11:50Z"],["dc.date.issued","1983"],["dc.description.abstract","Triruthenium dodecacarbonyl [Ru3(CO)12] reacts with nitrobenzene to give [Ru3(CO)10(NPh)](3) and [Ru3(CO)9(NPh)2](4) in low yields, accompanied by formation of CO2. The solution i.r. spectrum of (3) suggests the presence of triply bridging NPh and CO groups, confirmed by a single-crystal X-ray structure determination; space group P21/n, a= 12.457(1), b= 11.428(1), c= 29.234(2)Å, = 92.38(1)°, Z= 8, and R= 0.036 for 4 817 unique observed reflections. The two independent molecules differ slightly in the relative orientations of the phenyl groups. Mean bond lengths include Ru–Ru 2.746(5), Ru–µ-C 2.172(8), and Ru–µ-N 2.055(5)Å. The i.r. Spectra of complexes (3) and (4) are discussed in terms of a molecular-orbital description of M3(CO)9 moieties."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1039/DT9830002339"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3262"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91631"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.publisher","Chemical Society"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","Anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Reaction of triruthenium dodecacarbonyl with nitrobenzene and structure of µ3-phenylnitrene-triruthenium decacarbonyl, [Ru3(CO)10(µ3-NPh)] : Notes. Reaction of triruthenium dodecacarbonyl with nitrobenzene and structure of µ3-phenylnitrene-triruthenium decacarbonyl, [Ru3(CO)10(µ3-NPh) : Notes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1765"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","1767"],["dc.contributor.author","Bhaduri, Sumit"],["dc.contributor.author","Gopalkrishnan, Kalpathi S."],["dc.contributor.author","Clegg, William"],["dc.contributor.author","Jones, Peter G."],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2009-06-11T10:04:12Z"],["dc.date.accessioned","2021-10-27T13:12:12Z"],["dc.date.available","2009-06-11T10:04:12Z"],["dc.date.available","2021-10-27T13:12:12Z"],["dc.date.issued","1984"],["dc.description.abstract","Ru3(CO)10(NPh)](1) reacts with molecular hydrogen to give [Ru3H2(CO)9(NPh)](2), which can be carbonylated to produce [Ru3(CO)12]. A single-crystal X-ray structure determination of (2) confirms the presence of a triply-bridging NPh group and two doubly-bridging hydrogen atoms: space group P21/c, a= 11.697(2), b= 9.265(2), c= 18.589(4)Å, = 100.18(2)°, Z= 4, R= 0.039 for 3 019 unique observed reflections. Mean bond lengths include Ru–Ru 2.805(1)(H-bridged), 2.680(1)(unbridged), Ru–N 2.068(6), Ru–H 1.76(5)Å."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1039/DT9840001765"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3264"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91669"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Preparation and crystal structure of nonacarbonyl-di-µ-hydrido-µ3-phenylimido-triangulo-triruthenium, [Ru3(µ-H)2(CO)9(µ3-NPh)]"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]