Samuel, Prinson Poikayil

[["dc.bibliographiccitation.firstpage","12940"],["dc.bibliographiccitation.issue","36"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","12946"],["dc.bibliographiccitation.volume","42"],["dc.contributor.author","Tretiakov, Mykyta"],["dc.contributor.author","Shermolovich, Yuriy G."],["dc.contributor.author","Singh, Amit Pratap"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Niepoetter, Benedikt"],["dc.contributor.author","Visscher, Arne"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:29:43Z"],["dc.date.available","2018-11-07T09:29:43Z"],["dc.date.issued","2013"],["dc.description.abstract","Oxidation reactions of stable chalcogenamides with iodine are intriguing due to their broad application in various organic syntheses. In the present study we report on the utilization of N-heterocyclic carbene and cyclic-alkyl-amino carbenes L1-3: (L-1: = :C[N(2,6-Pr-i(2)-C6H3)CH](2), L-2: = :C(CH2)(CMe2)(C6H10)N-2,6-Pr-i(2)-C6H3, L-3: = :C(CH2)(CMe2)(2)N-2,6-Pr-i(2)-C6H3) for the syntheses of chalcogenamides L1-3=E (E = S, Se, Te) 1-4 and zwitterionic adducts L1-3=E-I-I 5-8. The synthesis of compounds 1-4 involved the addition reaction of ligand L1-3: and elemental chalcogen. Treatment of 1-4 with iodine resulted in the formation of adducts 5-8. Compounds 5-8 are well characterized with various spectroscopic methods and single-crystal X-ray structural analysis."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft"],["dc.identifier.doi","10.1039/c3dt51309b"],["dc.identifier.isi","000323274800024"],["dc.identifier.pmid","23770833"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/10780"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/31110"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9226"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Lewis-base stabilized diiodine adducts with N-heterocyclic chalcogenamides"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","192"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Chemical Communications"],["dc.bibliographiccitation.lastpage","195"],["dc.bibliographiccitation.volume","53"],["dc.contributor.author","Kundu, Subrata"],["dc.contributor.author","Mohapatra, Chandrajeet"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Kretsch, Johannes"],["dc.contributor.author","Walawalkar, M. G."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","De, Sriman"],["dc.contributor.author","Koley, Debasis"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2021-06-01T10:50:46Z"],["dc.date.available","2021-06-01T10:50:46Z"],["dc.date.issued","2017"],["dc.description.abstract","The synthesis of a 1,4-bisphosphino-2,3-disila butadiene and a 1,3-diphospha-2-silaallyl anion has been reported."],["dc.description.abstract","The first acyclic 4π-electron –PSi–SiP– motif with two four coordinate silicon substituents supported by the amidinate ligand and two coordinate phosphorus has been synthesized from the reaction of heteroleptic chlorosilylene LSiCl (1), TripPCl 2 (Trip = 2,4,6- i Pr 3 C 6 H 2 ) and KC 8 in a 1 : 1 : 3 ratio. The same reaction in a 1 : 2 : 6 ratio in the presence of one equivalent of 18-crown-6 ether affords the 1,3-diphospha-2-silaallyl anion."],["dc.identifier.doi","10.1039/C6CC09171G"],["dc.identifier.eissn","1364-548X"],["dc.identifier.issn","1359-7345"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/13973"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/86779"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.relation.eissn","1364-548X"],["dc.relation.issn","1359-7345"],["dc.rights.access","openAccess"],["dc.title","An unprecedented 1,4-diphospha-2,3-disila butadiene (–PSi–SiP–) derivative and a 1,3-diphospha-2-silaallyl anion, each stabilized by the amidinate ligand"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","12572"],["dc.bibliographiccitation.issue","36"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","+"],["dc.bibliographiccitation.volume","21"],["dc.contributor.author","Mohapatra, Chandrajeet"],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Keil, Helena"],["dc.contributor.author","Niepoetter, Benedikt"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Dutta, Sayan"],["dc.contributor.author","Koley, Debasis"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2018-11-07T09:52:44Z"],["dc.date.available","2018-11-07T09:52:44Z"],["dc.date.issued","2015"],["dc.description.abstract","The Me-cAAC:-stabilized dimer of silicon disulfide (SiS2) has been isolated in the molecular form as (Me-cAAC:)(2)Si2S4 (2) at room temperature [Me-cAAC:=cyclic alkyl(amino) carbene]. Compound 2 has been synthesized from the reaction of (Me-cAAC:)(2)Si-2 with elemental sulfur in a 1:4 molar ratio under oxidative addition. This is the smallest molecular unit of silicon disulfide characterized by X-ray crystallography, electron ionization mass spectrometry, and NMR spectroscopy. Structures with three sulfur atoms arranged around a silicon atom are known; however, 2 is the first structurally characterized silicon-sulfur compound containing one terminal and two bridging sulfur atoms at each silicon atom. Compound 2 shows no decomposition after storing for three months in an inert atmosphere at ambient temperature. The bonding of 2 has been further studied by theoretical calculations."],["dc.identifier.doi","10.1002/chem.201502092"],["dc.identifier.isi","000360312100001"],["dc.identifier.pmid","26179976"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/36187"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3765"],["dc.relation.issn","0947-6539"],["dc.title","A Stable Dimer of SiS2 Arranged between Two Carbene Molecules"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1953"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","1955"],["dc.bibliographiccitation.volume","55"],["dc.contributor.author","Mohapatra, Chandrajeet"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Li, Bin"],["dc.contributor.author","Niepoetter, Benedikt"],["dc.contributor.author","Schuermann, Christian J."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Maity, Bholanath"],["dc.contributor.author","Koley, Debasis"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2018-11-07T10:16:56Z"],["dc.date.available","2018-11-07T10:16:56Z"],["dc.date.issued","2016"],["dc.description.abstract","Carbenes are known for their ability to abstract HCl from hydrochlorosilanes to form carbene hydrochloride adducts. In contrast, the Si-H bond insertion products RSiCl2(cAACH) (2, 4, 6, and 8) have been formed in the reaction of RSiHCl2 [R = Ar(SiMe3)N (1), Cp (3), PhC(NtBu)(2) (5), Cl (7); Ar = 2,6-iPr(2)C(6)H(3)] with a cyclic alkyl(amino) carbene (cAAC:) irrespective of the steric demand of the R group. The new products have been characterized by various analytical tools including X-ray crystallography, electron ionization mass spectrometry, and NMR spectroscopy. Theoretical investigations have also been performed to understand why cAAC prefers insertion into the Si-H bond rather than the dehydrohalogenation pathway."],["dc.identifier.doi","10.1021/acs.inorgchem.6b00024"],["dc.identifier.isi","000371753500001"],["dc.identifier.pmid","26859316"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/41136"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","Insertion of Cyclic Alkyl(amino) Carbene into the Si-H Bonds of Hydrochlorosilanes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1544"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","1549"],["dc.bibliographiccitation.volume","52"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Singh, Amit Pratap"],["dc.contributor.author","Sarish, Sankaranarayana Pillai"],["dc.contributor.author","Matussek, Julia"],["dc.contributor.author","Objartel, Ina"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:28:16Z"],["dc.date.available","2018-11-07T09:28:16Z"],["dc.date.issued","2013"],["dc.description.abstract","Diallcylamino compounds of group 14 elements (Si, Ge, Sn) in the +2 oxidation state supported by benzamidinate ligands were synthesized and treated with pentafluoropyridine. Two different modes of reactivity were observed, depending on the metal atom and the basicity of the substituent at the metal. Pentafluoropyridine undergoes oxidative addition reaction at the Si(II) and Ge(II) atoms whereas at the Sn(II) atom substitution of the NMe2 group by the para fluorine of pentafluoropyridine occurs. The C F bond activation by the lone pair of germanium is the first report of this kind. The Sn(II) fluoride obtained has an elongated Sn F bond length and can be used as a good fluorinating agent. The compounds were characterized by multinuclear NMR spectroscopy, mass spectrometry, elemental analysis, and X-ray structural analysis. Single crystal X-ray structural analysis of the tin fluoride shows an asymmetric dimer with weak Sn(II)(F) (F)Sn(II) interactions."],["dc.description.sponsorship","Center for Materials Crystallography (CMC); Land Niedersachsen"],["dc.identifier.doi","10.1021/ic302344a"],["dc.identifier.isi","000314627700044"],["dc.identifier.pmid","23343458"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/30733"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.title","Oxidative Addition Versus Substitution Reactions of Group 14 Dialkylamino Metalylenes with Pentafluoropyridine"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","9240"],["dc.bibliographiccitation.issue","30"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","9245"],["dc.bibliographiccitation.volume","20"],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Niepoetter, Benedikt"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Ehret, Fabian"],["dc.contributor.author","Kaim, Wolfgang"],["dc.contributor.author","Maity, Bholanath"],["dc.contributor.author","Koley, Debasis"],["dc.date.accessioned","2018-11-07T09:37:35Z"],["dc.date.available","2018-11-07T09:37:35Z"],["dc.date.issued","2014"],["dc.description.abstract","The trichlorosilylcarbene monoradical (Cy-cAACC center dot)SiCl3 (1) was directly converted to (Cy-cAACC center dot)SiPh3 (2) by substitution of the three chlorine atoms with phenyl groups without affecting the radical center adjacent to the silicon atom. In addition to the structure determination, compound 2 was studied by EPR spectroscopy and DFT calculations. The three hyperfine lines in the EPR spectrum of 2 are due to the coupling with N-14 nucleus. Functionalized 1,4-quinodimethane Me-2-cAAC=C6H4=CPh2 (7) was isolated, whereas carbon analogue of radical 2 was targeted. Cyclic voltammogram of 7 indicated that a stable radical-anion 7 center dot(+), as well as a radical-cation 7 center dot(+), can be prepared. Theoretical calculations showed that one-electron ionization energy and electron affinity of 7 are 5.1 and 0.7 eVmol(-1), respectively."],["dc.identifier.doi","10.1002/chem.201400393"],["dc.identifier.isi","000339568800013"],["dc.identifier.pmid","24664879"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/32874"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3765"],["dc.relation.issn","0947-6539"],["dc.title","Synthesis and Characterization of a Triphenyl-Substituted Radical and an Unprecedented Formation of a Carbene-Functionalized Quinodimethane"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","11049"],["dc.bibliographiccitation.issue","20"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","11054"],["dc.bibliographiccitation.volume","51"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Sen, Sakya S."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Granitzka, Markus"],["dc.contributor.author","Matussek, Julia"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:04:36Z"],["dc.date.available","2018-11-07T09:04:36Z"],["dc.date.issued","2012"],["dc.description.abstract","The reactions of silylenes with organic azides are quite diverse, depending on the substituents of the silylene center and on the nature of the azide employed. Elusive silaimine with three-coordinate silicon atom (LSiN)-Si-1(2,6-Triip(2)-C6H3) (5) {L-1 = CH[(C=CH2)(CMe)(2,6-iPr(2)C(6)H(3)N)(2)] and Triip = 2,4,6-triisopropylphenyl) was synthesized by treatment of the silylene (LSi)-Si-1 (1) with a sterically demanding 2,6-bis(2,4,6-triisopropylphenyl)phenyl azide (2,6-Triip(2)C(6)H(3)N(3)). The reaction of Lewis base-stabilized dichlorosilylene (LSiCl2)-Si-2 (2) {L-2 = 1,3-bis(2,6-iPr(2)C(6)H(3))imidazol-2-ylidene} with Ph3SiN3 afforded four-coordinate silaimine L-2(Cl-2)SiNSiPh3 (6). Treatment of 2,6-Triip(2)C(6)H(3)N(3) with (LSiCl)-Si-3 (3) (L-3 = PhC(NtBu)(2)) yielded silaimine L-3(Cl)SiN(2,6-Triip(2)-C6H3) (7) possessing a four-coordinate silicon atom, The reactions of (LSiN)-Si-3(SiMe3)(2) (4) with adamantyl and trimethylsilyl azide furnished silaimine compounds with a four-coordinate silicon atom L-3(N(Ad)SiMe3)SiN(SiMe3) (8) (Ad = adamantyl) and L-3(N(SiMe3)(2))SiN(SiMe3) (9). Compound 8 was formed by migration of one of the SiMe3 groups. Compounds 5-9 are stable under inert atmosphere and were characterized by elemental analysis, NMR spectroscopy, and single-crystal X-ray studies."],["dc.identifier.doi","10.1021/ic301543y"],["dc.identifier.isi","000309739100060"],["dc.identifier.pmid","23036040"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/25142"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.title","Stable Silaimines with Three- and Four-Coordinate Silicon Atoms"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2766"],["dc.bibliographiccitation.issue","10"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","2770"],["dc.bibliographiccitation.volume","53"],["dc.contributor.author","Niepoetter, Benedikt"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Kratzert, Daniel"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Jerabek, Paul"],["dc.contributor.author","Frenking, Gernot"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:42:43Z"],["dc.date.available","2018-11-07T09:42:43Z"],["dc.date.issued","2014"],["dc.description.abstract","An experimental and theoretical charge density study confirms the interpretation of (cAAC)(2)Si as a silylone to be valid. Two separated VSCCs present in the non-bonding region of the central silicon are indicative for two lone pairs. In the experiment, both the two crystallographically independent SiC bond lengths and ellipticities vary notably. It is only the cyclohexyl derivative that shows significant differences in these values, both in the silylones and the germylones. Only by calculating increasing spheres of surrounding point charges we were able to recover the changes in the properties of the charge density distribution caused by weak intermolecular interactions. The nitrogen-carbene-carbon bond seems to have a significant double-bond character, indicating a singlet state for the carbene carbon, which is needed for donor acceptor bonding. Thus the sum of bond angles at the nitrogen atoms seems to be a reasonable estimate for singlet versus triplet state of cAACs."],["dc.identifier.doi","10.1002/anie.201308609"],["dc.identifier.isi","000331774700044"],["dc.identifier.pmid","24481811"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/34018"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.title","Experimental Charge Density Study of a Silylone"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","11964"],["dc.bibliographiccitation.issue","34"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","11971"],["dc.bibliographiccitation.volume","136"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Sk, Nurul Amin"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Carl, Elena"],["dc.contributor.author","Neufeld, Roman"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Meyer, Franc"],["dc.contributor.author","Ungur, Liviu"],["dc.contributor.author","Chibotaru, Liviu F."],["dc.contributor.author","Christian, Jonathan H."],["dc.contributor.author","Ramachandran, Vasanth"],["dc.contributor.author","van Tol, Johan"],["dc.contributor.author","Dalal, Naresh S."],["dc.date.accessioned","2018-11-07T09:36:25Z"],["dc.date.available","2018-11-07T09:36:25Z"],["dc.date.issued","2014"],["dc.description.abstract","Cyclic alkyl(amino) carbene stabilized two- and three-coordinate Fe(I) complexes, (cAAC)(2)FeCl (2) and [(cAAC)(2)Fe][B(C6F5)(4)] (3), respectively, were prepared and thoroughly studied by a bouquet of analytical techniques as well as theoretical calculations. Magnetic susceptibility and Mossbauer spectroscopy reveal the +1 oxidation state and S = 3/2 spin ground state of iron in both compounds. 2 and 3 show slow magnetic relaxation typical for single molecule magnets under an applied direct current magnetic field. The high-frequency EPR measurements confirm the S = 3/2 ground state with a large, positive zero-field splitting (similar to 20.4 cm(-1)) and reveal easy plane anisotropy for compound 2. CASSCF/CASPT2/RASSI-SO ab initio calculations using the MOLCAS program package support the experimental results."],["dc.identifier.doi","10.1021/ja5043116"],["dc.identifier.isi","000340993400025"],["dc.identifier.pmid","25072104"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/32615"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0002-7863"],["dc.title","Electronic Structure and Slow Magnetic Relaxation of Low-Coordinate Cyclic Alkyl(amino) Carbene Stabilized Iron(I) Complexes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","3148"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Chemical Science"],["dc.bibliographiccitation.lastpage","3153"],["dc.bibliographiccitation.volume","6"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Neufeld, Roman"],["dc.contributor.author","Chandra Mondal, Kartik"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Meyer, Franc"],["dc.contributor.author","Rojisha, Vallyanga Chalil"],["dc.contributor.author","De, Susmita"],["dc.contributor.author","Parameswaran, Pattiyil"],["dc.contributor.author","Stückl, A. Claudia"],["dc.contributor.author","Kaim, Wolfgang"],["dc.contributor.author","Christian, Jonathan H."],["dc.contributor.author","Bindra, Jasleen K."],["dc.contributor.author","Dalal, Naresh S."],["dc.date.accessioned","2015-07-17T07:36:40Z"],["dc.date.accessioned","2021-10-27T13:12:19Z"],["dc.date.available","2015-07-17T07:36:40Z"],["dc.date.available","2021-10-27T13:12:19Z"],["dc.date.issued","2015"],["dc.description.abstract","Cr(I)Cl is a very unstable species. The present work describes the stabilisation of Cr(I)Cl in the low coordinate environment of cyclic alkyl(amino) carbene ligands and its synthetic application to yield an unprecedented cationic complex with a two coordinate Cr(I). One electron reduction of (cAAC)2CrCl2 (1) with equivalent amount of KC8 results in the formation of (cAAC)2CrCl (2), with a distorted trigonal planar configuration at the metal centre. SQUID, EPR and theoretical studies reveal a Cr(I) centre with S = 5/2 spin ground state for 2. It represents the first example of a mononuclear Cr complex showing slow relaxation of magnetisation under an applied magnetic field. The chlorine atom in 2 is expected to be prone to further reactions with appropriate reagents. This qualifies 2 as a promising precursor for the preparation of various interesting complexes with Cr(I) in a low coordinate environment. The first example of this metathesis reaction is observed when 2 is treated with Na[B(C6H3(CF3)2)4] resulting in [(cAAC)2Cr]+[B(C6H3(CF3)2)4]−, a linear cationic complex with two coordinate Cr(I) and an S = 5/2 spin ground state."],["dc.identifier.doi","10.1039/c5sc00646e"],["dc.identifier.isi","000353223100059"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/11972"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91680"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","2041-6539"],["dc.relation.issn","2041-6520"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","cyclic; alkyl; amino; carbenes"],["dc.title","Cr(i)Cl as well as Cr+ are stabilised between two cyclic alkyl amino carbenes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]