Samuel, Prinson Poikayil

[["dc.bibliographiccitation.firstpage","354"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","357"],["dc.bibliographiccitation.volume","32"],["dc.contributor.author","Singh, Amit Pratap"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Sidhu, Navdeep S."],["dc.contributor.author","Dittrich, Birger"],["dc.date.accessioned","2018-11-07T09:29:12Z"],["dc.date.available","2018-11-07T09:29:12Z"],["dc.date.issued","2013"],["dc.description.abstract","The chemistry of stable metalylenes (the heavier group 14 element analogues of carbenes) is an intriguing target of main group chemistry due to their synthetic potential and industrial application. In the present study, we report on the utilization of an abnormal N-heterocyclic carbene (aNHC) and a cyclic alkylamino carbene (cAAC) as a Lewis base for the syntheses of compounds aNHC-SiCl2 (3), aNHC-SnCl2 (4), and cAAC.SnCl2 (5). The synthesis of silylene 3 involved the ligand-substitution reaction between NHC-SiCl2 and an aNHC. However, compounds 4 and 5 were synthesized by the reactions of aNHC and cAAC with SnCl2 in the molar ratio of 1:1. Compounds 3-5 are well-characterized with various spectroscopic methods and single-crystal X-ray structural analysis."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft"],["dc.identifier.doi","10.1021/om301062d"],["dc.identifier.isi","000313606200041"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/30964"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0276-7333"],["dc.title","Lewis Base Stabilized Group 14 Metalylenes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","12572"],["dc.bibliographiccitation.issue","36"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","+"],["dc.bibliographiccitation.volume","21"],["dc.contributor.author","Mohapatra, Chandrajeet"],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Keil, Helena"],["dc.contributor.author","Niepoetter, Benedikt"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Dutta, Sayan"],["dc.contributor.author","Koley, Debasis"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2018-11-07T09:52:44Z"],["dc.date.available","2018-11-07T09:52:44Z"],["dc.date.issued","2015"],["dc.description.abstract","The Me-cAAC:-stabilized dimer of silicon disulfide (SiS2) has been isolated in the molecular form as (Me-cAAC:)(2)Si2S4 (2) at room temperature [Me-cAAC:=cyclic alkyl(amino) carbene]. Compound 2 has been synthesized from the reaction of (Me-cAAC:)(2)Si-2 with elemental sulfur in a 1:4 molar ratio under oxidative addition. This is the smallest molecular unit of silicon disulfide characterized by X-ray crystallography, electron ionization mass spectrometry, and NMR spectroscopy. Structures with three sulfur atoms arranged around a silicon atom are known; however, 2 is the first structurally characterized silicon-sulfur compound containing one terminal and two bridging sulfur atoms at each silicon atom. Compound 2 shows no decomposition after storing for three months in an inert atmosphere at ambient temperature. The bonding of 2 has been further studied by theoretical calculations."],["dc.identifier.doi","10.1002/chem.201502092"],["dc.identifier.isi","000360312100001"],["dc.identifier.pmid","26179976"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/36187"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3765"],["dc.relation.issn","0947-6539"],["dc.title","A Stable Dimer of SiS2 Arranged between Two Carbene Molecules"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","11817"],["dc.bibliographiccitation.issue","45"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","11821"],["dc.bibliographiccitation.volume","52"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Hermann, Markus"],["dc.contributor.author","Frenking, Gernot"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Meyer, Franc"],["dc.contributor.author","Stueckl, A. Claudia"],["dc.contributor.author","Christian, Jonathan H."],["dc.contributor.author","Dalal, Naresh S."],["dc.contributor.author","Ungur, Liviu"],["dc.contributor.author","Chibotaru, Liviu F."],["dc.contributor.author","Proepper, Kevin"],["dc.contributor.author","Meents, Alke"],["dc.contributor.author","Dittrich, Birger"],["dc.date.accessioned","2018-11-07T09:17:42Z"],["dc.date.available","2018-11-07T09:17:42Z"],["dc.date.issued","2013"],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft [RO 224/60-1]"],["dc.identifier.doi","10.1002/anie.201304642"],["dc.identifier.isi","000326138500029"],["dc.identifier.pmid","24038991"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/28227"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.title","Synthesis and Characterization of a Two-Coordinate Manganese Complex and its Reaction with Molecular Hydrogen at Room Temperature"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","9240"],["dc.bibliographiccitation.issue","30"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","9245"],["dc.bibliographiccitation.volume","20"],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Niepoetter, Benedikt"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Ehret, Fabian"],["dc.contributor.author","Kaim, Wolfgang"],["dc.contributor.author","Maity, Bholanath"],["dc.contributor.author","Koley, Debasis"],["dc.date.accessioned","2018-11-07T09:37:35Z"],["dc.date.available","2018-11-07T09:37:35Z"],["dc.date.issued","2014"],["dc.description.abstract","The trichlorosilylcarbene monoradical (Cy-cAACC center dot)SiCl3 (1) was directly converted to (Cy-cAACC center dot)SiPh3 (2) by substitution of the three chlorine atoms with phenyl groups without affecting the radical center adjacent to the silicon atom. In addition to the structure determination, compound 2 was studied by EPR spectroscopy and DFT calculations. The three hyperfine lines in the EPR spectrum of 2 are due to the coupling with N-14 nucleus. Functionalized 1,4-quinodimethane Me-2-cAAC=C6H4=CPh2 (7) was isolated, whereas carbon analogue of radical 2 was targeted. Cyclic voltammogram of 7 indicated that a stable radical-anion 7 center dot(+), as well as a radical-cation 7 center dot(+), can be prepared. Theoretical calculations showed that one-electron ionization energy and electron affinity of 7 are 5.1 and 0.7 eVmol(-1), respectively."],["dc.identifier.doi","10.1002/chem.201400393"],["dc.identifier.isi","000339568800013"],["dc.identifier.pmid","24664879"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/32874"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3765"],["dc.relation.issn","0947-6539"],["dc.title","Synthesis and Characterization of a Triphenyl-Substituted Radical and an Unprecedented Formation of a Carbene-Functionalized Quinodimethane"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","412"],["dc.bibliographiccitation.issue","2"],["dc.bibliographiccitation.journal","ChemPhysChem"],["dc.bibliographiccitation.lastpage","419"],["dc.bibliographiccitation.volume","16"],["dc.contributor.author","Dittrich, Birger"],["dc.contributor.author","Wandtke, Claudia M."],["dc.contributor.author","Meents, Alke"],["dc.contributor.author","Proepper, Kevin"],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Sk, Nurul Amin"],["dc.contributor.author","Singh, Amit Pratap"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Sidhu, Navdeep S."],["dc.date.accessioned","2018-11-07T10:01:06Z"],["dc.date.available","2018-11-07T10:01:06Z"],["dc.date.issued","2015"],["dc.description.abstract","Single-crystal X-ray diffraction (XRD) is often considered the gold standard in analytical chemistry, as it allows element identification as well as determination of atom connectivity and the solid-state structure of completely unknown samples. Element assignment is based on the number of electrons of an atom, so that a distinction of neighboring heavier elements in the periodic table by XRD is often difficult. A computationally efficient procedure for aspherical-atom least-squares refinement of conventional diffraction data of organometallic compounds is proposed. The iterative procedure is conceptually similar to Hirshfeld-atom refinement (Acta Crystallogr. Sect. A 2008, 64, 383-393; IUCrJ. 2014, 1,61-79), but it relies on tabulated invariom scattering factors (Acta Crystallogr. Sect. B 2013, 69, 91-104) and the Hansen/Coppens multipole model; disordered structures can be handled as well. Five linear-coordinate 3d metal complexes, for which the wrong element is found if standard independent-atom model scattering factors are relied upon, are studied, and it is shown that only aspherical-atom scattering factors allow a reliable assignment. The influence of anomalous dispersion in identifying the correct element is investigated and discussed."],["dc.identifier.doi","10.1002/cphc.201402600"],["dc.identifier.isi","000348510700018"],["dc.identifier.pmid","25393218"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/37945"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1439-7641"],["dc.relation.issn","1439-4235"],["dc.title","Aspherical-Atom Modeling of Coordination Compounds by Single-Crystal X-ray Diffraction Allows the Correct Metal Atom To Be Identified"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2766"],["dc.bibliographiccitation.issue","10"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","2770"],["dc.bibliographiccitation.volume","53"],["dc.contributor.author","Niepoetter, Benedikt"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Kratzert, Daniel"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Jerabek, Paul"],["dc.contributor.author","Frenking, Gernot"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:42:43Z"],["dc.date.available","2018-11-07T09:42:43Z"],["dc.date.issued","2014"],["dc.description.abstract","An experimental and theoretical charge density study confirms the interpretation of (cAAC)(2)Si as a silylone to be valid. Two separated VSCCs present in the non-bonding region of the central silicon are indicative for two lone pairs. In the experiment, both the two crystallographically independent SiC bond lengths and ellipticities vary notably. It is only the cyclohexyl derivative that shows significant differences in these values, both in the silylones and the germylones. Only by calculating increasing spheres of surrounding point charges we were able to recover the changes in the properties of the charge density distribution caused by weak intermolecular interactions. The nitrogen-carbene-carbon bond seems to have a significant double-bond character, indicating a singlet state for the carbene carbon, which is needed for donor acceptor bonding. Thus the sum of bond angles at the nitrogen atoms seems to be a reasonable estimate for singlet versus triplet state of cAACs."],["dc.identifier.doi","10.1002/anie.201308609"],["dc.identifier.isi","000331774700044"],["dc.identifier.pmid","24481811"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/34018"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.title","Experimental Charge Density Study of a Silylone"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","8919"],["dc.bibliographiccitation.issue","25"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","8922"],["dc.bibliographiccitation.volume","136"],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Samuel, Prinson Poikayil"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Aysin, Rinat R."],["dc.contributor.author","Leites, Larissa A."],["dc.contributor.author","Neudeck, Sven"],["dc.contributor.author","Luebben, Jens"],["dc.contributor.author","Dittrich, Birger"],["dc.contributor.author","Holzmann, Nicole"],["dc.contributor.author","Hermann, Markus"],["dc.contributor.author","Frenking, Gernot"],["dc.date.accessioned","2018-11-07T09:38:49Z"],["dc.date.available","2018-11-07T09:38:49Z"],["dc.date.issued","2014"],["dc.description.abstract","A disiladicarbene, (Cy-cAAC)(2)Si-2 (2), was synthesized by reduction of Cy-cAAC:SiCl4 adduct with KC8. The dark-colored compound 2 is stable at room temperature for a year under an inert atmosphere. Moreover, it is stable up to 190 degrees C and also can be characterized by electron ionization mass spectrometry. Theoretical and Raman studies reveal the existence of a Si=Si double bond with a partial double bond between each carbene carbon atom and silicon atom. Cyclic voltammetry suggests that 2 can quasi-reversibly accept an electron to produce a very reactive radical anion, 2(circle-), as an intermediate species. Thus, reduction of 2 with potassium metal at room temperature led to the isolation of an isomeric neutral rearranged product and an anionic dimer of a potassium salt via the formation of 2(circle-)."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft [DFG RO 224/60-I]"],["dc.identifier.doi","10.1021/ja504821u"],["dc.identifier.isi","000338184200021"],["dc.identifier.pmid","24911357"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/33141"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.relation.issn","0002-7863"],["dc.title","One-Electron-Mediated Rearrangements of 2,3-Disiladicarbene"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","11964"],["dc.bibliographiccitation.issue","34"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","11971"],["dc.bibliographiccitation.volume","136"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Sk, Nurul Amin"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Carl, Elena"],["dc.contributor.author","Neufeld, Roman"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Meyer, Franc"],["dc.contributor.author","Ungur, Liviu"],["dc.contributor.author","Chibotaru, Liviu F."],["dc.contributor.author","Christian, Jonathan H."],["dc.contributor.author","Ramachandran, Vasanth"],["dc.contributor.author","van Tol, Johan"],["dc.contributor.author","Dalal, Naresh S."],["dc.date.accessioned","2018-11-07T09:36:25Z"],["dc.date.available","2018-11-07T09:36:25Z"],["dc.date.issued","2014"],["dc.description.abstract","Cyclic alkyl(amino) carbene stabilized two- and three-coordinate Fe(I) complexes, (cAAC)(2)FeCl (2) and [(cAAC)(2)Fe][B(C6F5)(4)] (3), respectively, were prepared and thoroughly studied by a bouquet of analytical techniques as well as theoretical calculations. Magnetic susceptibility and Mossbauer spectroscopy reveal the +1 oxidation state and S = 3/2 spin ground state of iron in both compounds. 2 and 3 show slow magnetic relaxation typical for single molecule magnets under an applied direct current magnetic field. The high-frequency EPR measurements confirm the S = 3/2 ground state with a large, positive zero-field splitting (similar to 20.4 cm(-1)) and reveal easy plane anisotropy for compound 2. CASSCF/CASPT2/RASSI-SO ab initio calculations using the MOLCAS program package support the experimental results."],["dc.identifier.doi","10.1021/ja5043116"],["dc.identifier.isi","000340993400025"],["dc.identifier.pmid","25072104"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/32615"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0002-7863"],["dc.title","Electronic Structure and Slow Magnetic Relaxation of Low-Coordinate Cyclic Alkyl(amino) Carbene Stabilized Iron(I) Complexes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","818"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","European Journal of Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","823"],["dc.bibliographiccitation.volume","2014"],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Li, Yan"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Roy, Sudipta"],["dc.contributor.author","Ackermann, Lutz"],["dc.contributor.author","Sidhu, Navdeep S."],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Carl, Elena"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","De, Susmita"],["dc.contributor.author","Parameswaran, Pattiyil"],["dc.contributor.author","Ungur, Liviu"],["dc.contributor.author","Chibotaru, Liviu F."],["dc.contributor.author","Andrada, Diego M."],["dc.date.accessioned","2018-11-07T09:44:12Z"],["dc.date.available","2018-11-07T09:44:12Z"],["dc.date.issued","2014"],["dc.identifier.isi","000331004200004"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/34341"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1099-0682"],["dc.relation.issn","1434-1948"],["dc.title","A Catalyst with Two-Coordinate Nickel: Theoretical and Catalytic Studies"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4736"],["dc.bibliographiccitation.issue","8"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","4743"],["dc.bibliographiccitation.volume","52"],["dc.contributor.author","Mondal, Kartik Chandra"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Tretiakov, Mykyta"],["dc.contributor.author","Singh, Amit Pratap"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Stueckl, A. Claudia"],["dc.contributor.author","Niepoetter, Benedikt"],["dc.contributor.author","Carl, Elena"],["dc.contributor.author","Wolf, Hilke"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:25:59Z"],["dc.date.available","2018-11-07T09:25:59Z"],["dc.date.issued","2013"],["dc.description.abstract","Two different synthetic methodologies of silicon dihalide bridged biradicals of the general formula (L-n center dot)(2)SiX2 (n = 1, 2) have been developed. First, the metathesis reaction between NHC:SiX2 and L-n: (L-n: = cyclic akyl(amino) carbene in a 1:3 molar ratio leads to the products 2 (n = 1, X = Cl), 4 (n = 2, X = CO, 6 (n = 1, X = Br), and 7 (n = 2, X = Br). These reactions also produce coupled NHCs (3, 5) under C-C bond formation. The formation of the coupled NHCs (L-m = cyclic alkyl(amino) carbene substituted N-heterocyclic carbene; m = 3, n = 1 (3) and m = 4, n = 2 (5)) is faster during the metathesis reaction between NHC:SiBr2 and L-n: when compared with that of NHC:SiCl2. Second, the reaction of L-l:SiCl4 (8) (L-l: =:C(CH2)(CMe2)(2)N-2,6-iPr(2)C(6)H(3)) with a non-nucleophilic base LiN(iPr)(2) in a 1:1 molar ratio shows an unprecedented methodology for the synthesis of the biradical (L-l center dot)2SiCl(2) (2). The blue blocks of silicon dichloride bridged biradicals (2, 4) are stable for more than six months under an inert atmosphere and in air for one week. Compounds 2 and 4 melt in the temperature range of 185 to 195 C. The dibromide (6, 7) analogue is more prone to decomposition in the solution but comparatively more stable in the solid state than in the solution. Decomposition of the products has been observed in the UV-vis spectra. Moreover, compounds 2 and 4 were further converted to stable singlet biradicaloid dicarbene-coordinated (L-n:)(2)Si(0) (n = 1 (9), 2 (10)) under KC8 reduction. Compounds 2 and 4 were also reduced to dehalogenated products 9 and 10, respectively when treated with RLi (R = Ph, Me, tBu). Cyclic voltametry measurements show that 10 can irreversibly undergo both one electron oxidation and reduction."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft [RO 224/60-1]"],["dc.identifier.doi","10.1021/ic400357p"],["dc.identifier.isi","000317712000074"],["dc.identifier.pmid","23527879"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/30192"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.title","Easy Access to Silicon(0) and Silicon(II) Compounds"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]