Rauch, Karsten

[["dc.bibliographiccitation.firstpage","1790"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","1794"],["dc.bibliographiccitation.volume","21"],["dc.contributor.author","Raghuvanshi, Keshav"],["dc.contributor.author","Rauch, Karsten"],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2018-11-07T10:02:06Z"],["dc.date.available","2018-11-07T10:02:06Z"],["dc.date.issued","2015"],["dc.description.abstract","Intermolecular C-H acyloxylations of phenols with removable directing groups were accomplished with a versatile ruthenium catalyst. Specifically, a cationic ruthenium(II) complex, formed in situ, enabled the chemoselective C-H oxygenations of a broad range of substrates. The catalyst proved tolerant of synthetically valuable functional groups, and the substrate scope included both (hetero) aromatic and, the more challenging, aliphatic carboxylic acids. The proposed reaction mechanism involves a reversible C-H ruthenation and an oxidatively induced C-O-bond-forming reductive elimination."],["dc.description.sponsorship","European Research Council under the European Community [307535]; DAAD"],["dc.identifier.doi","10.1002/chem.201405071"],["dc.identifier.isi","000347841500050"],["dc.identifier.pmid","25431040"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/38160"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3765"],["dc.relation.issn","0947-6539"],["dc.title","Ruthenium(II)-Catalyzed C-H Acyloxylation of Phenols with Removable Auxiliary"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","no"],["dc.bibliographiccitation.issue","24"],["dc.bibliographiccitation.journal","ChemInform"],["dc.bibliographiccitation.lastpage","no"],["dc.bibliographiccitation.volume","46"],["dc.contributor.author","Raghuvanshi, Keshav"],["dc.contributor.author","Rauch, Karsten"],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2021-12-08T12:30:17Z"],["dc.date.available","2021-12-08T12:30:17Z"],["dc.date.issued","2015"],["dc.identifier.doi","10.1002/chin.201524170"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/96385"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-476"],["dc.relation.issn","0931-7597"],["dc.rights.uri","http://doi.wiley.com/10.1002/tdm_license_1.1"],["dc.title","ChemInform Abstract: Ruthenium(II)-Catalyzed C-H Acyloxylation of Phenols with Removable Auxiliary."],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","3172"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","ACS Catalysis"],["dc.bibliographiccitation.lastpage","3175"],["dc.bibliographiccitation.volume","6"],["dc.contributor.author","Raghuvanshi, Keshav"],["dc.contributor.author","Zell, Daniel"],["dc.contributor.author","Rauch, Karsten"],["dc.contributor.author","Ackermann, Lutz"],["dc.date.accessioned","2018-11-07T10:14:51Z"],["dc.date.available","2018-11-07T10:14:51Z"],["dc.date.issued","2016"],["dc.description.abstract","The ruthenium(II)-catalyzed intermolecular C-H imidation with weakly coordinating ketones provided step-economical access to synthetically useful primary aminophenones. The azide-free C-H imidation strategy occurred with ample scope and excellent functional group tolerance to efficiently deliver densely substituted aminophenones."],["dc.identifier.doi","10.1021/acscatal.6b00711"],["dc.identifier.isi","000375894500054"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/40701"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","2155-5435"],["dc.title","Ketone-Assisted Ruthenium(II)-Catalyzed C-H Imidation: Access to Primary Aminoketones by Weak Coordination"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]