Schneider, Sven

[["dc.bibliographiccitation.firstpage","5511"],["dc.bibliographiccitation.issue","40"],["dc.bibliographiccitation.journal","Chemical Communications"],["dc.bibliographiccitation.lastpage","5514"],["dc.bibliographiccitation.volume","53"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Bete, Sarah C."],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Volkmann, Christian"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2018-08-17T09:33:43Z"],["dc.date.accessioned","2021-10-27T13:12:42Z"],["dc.date.available","2018-08-17T09:33:43Z"],["dc.date.available","2021-10-27T13:12:42Z"],["dc.date.issued","2017"],["dc.description.abstract","Reduction of the pincer complex [OsIIICl2(PNP)] (PNP = N(CHCHPtBu2)2) affords the isolation and full characterization of an osmium(II) complex with square-planar coordination geometry, i.e. [OsIICl(PNP)]. Spectroscopic, structural and magnetic data in combination with multireference computations indicate strong temperature independent paramagnetism, which arises from an energetically well separated ground state that mixes with excited states through spin-orbit coupling."],["dc.identifier.doi","10.1039/C7CC01569K"],["dc.identifier.isi","000401602900006"],["dc.identifier.pmid","28405639"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/15307"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91714"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.notes.intern","In goescholar not merged with http://resolver.sub.uni-goettingen.de/purl?gs-1/15078 but duplicate"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.relation.eissn","1364-548X"],["dc.relation.issn","1359-7345"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","Complex; Square-Planar; Osmium(II)"],["dc.subject.ddc","540"],["dc.title","A Square-Planar Osmium(II) Complex"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","11581"],["dc.bibliographiccitation.issue","30"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","11591"],["dc.bibliographiccitation.volume","61"],["dc.contributor.author","van Alten, Richt S."],["dc.contributor.author","Wieser, Philipp A."],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Siewert, Inke"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2022-09-01T09:49:54Z"],["dc.date.available","2022-09-01T09:49:54Z"],["dc.date.issued","2022"],["dc.identifier.doi","10.1021/acs.inorgchem.2c00973"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/113570"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-597"],["dc.relation.eissn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","Halide Effects in Reductive Splitting of Dinitrogen with Rhenium Pincer Complexes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","469"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Inorganic Chemistry Frontiers"],["dc.bibliographiccitation.lastpage","477"],["dc.bibliographiccitation.volume","3"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Kasanmascheff, Müge"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2016-02-15T11:46:27Z"],["dc.date.accessioned","2021-10-27T13:12:29Z"],["dc.date.available","2016-02-15T11:46:27Z"],["dc.date.available","2021-10-27T13:12:29Z"],["dc.date.issued","2016"],["dc.description.abstract","The oxidative coupling of nitride ligands (N3−) to dinitrogen and its microscopic reverse, N2-splitting to nitrides, are important elementary steps in chemical transformations, such as selective ammonia oxidation or nitrogen fixation. Here an experimental and computational evaluation is provided for the homo- and heterocoupling of our previously reported iridium(IV) and iridium(V) nitrides [IrN(PNP)]n (n = 0, +1; PNP = N(CHCHPtBu2)2). All three formal coupling products [(PNP)IrN2Ir(PNP)]n (n = 0–+2) were structurally characterized. While the three coupling reactions are all thermodynamically feasible, homocoupling of [IrN(PNP)]+ is kinetically hindered. The contributing parameters to relative coupling rates are discussed providing qualitative guidelines for the stability of electron rich transition metal nitrides."],["dc.description.sponsorship","European Research Council [646747]"],["dc.identifier.doi","10.1039/c5qi00267b"],["dc.identifier.isi","000374011600004"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/12839"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91696"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU/N2 as Chemical Feedstock – Synthetic Nitrogen Fixation beyond Haber-Bosch/N2FEED"],["dc.relation.issn","2052-1553"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","iridium nitrido complexes; Coupling"],["dc.title","Coupling of terminal iridium nitrido complexes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","802"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","811"],["dc.bibliographiccitation.volume","37"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Bete, Sarah C."],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Volkmann, Christian"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2019-07-09T11:51:20Z"],["dc.date.available","2019-07-09T11:51:20Z"],["dc.date.issued","2017"],["dc.identifier.doi","10.1021/acs.organomet.7b00707"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16106"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/59928"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Four- and Five-Coordinate Osmium(IV) Nitrides and Imides: Circumventing the “Nitrido Wall”"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1054"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","Nature Chemistry"],["dc.bibliographiccitation.lastpage","1059"],["dc.bibliographiccitation.volume","12"],["dc.contributor.author","Sun, Jian"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Verplancke, Hendrik"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Hunger, David"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","van Slageren, Joris"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-04-14T08:24:29Z"],["dc.date.available","2021-04-14T08:24:29Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1038/s41557-020-0522-4"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17872"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/81300"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1755-4349"],["dc.relation.issn","1755-4330"],["dc.rights.access","openAccess"],["dc.subject.ddc","540"],["dc.title","A platinum(ii) metallonitrene with a triplet ground state"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4506"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","4513"],["dc.bibliographiccitation.volume","43"],["dc.contributor.author","Kinauer, Markus"],["dc.contributor.author","Scheibel, Markus G."],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Heinemann, Frank W."],["dc.contributor.author","Stollberg, Peter"],["dc.contributor.author","Wuertele, Christian"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2018-11-07T09:46:30Z"],["dc.date.available","2018-11-07T09:46:30Z"],["dc.date.issued","2014"],["dc.description.abstract","The iridium(II) complex [IrCl{N(CHCHPtBu2)(2)}] is reduced by KC8 to give the anionic iridium(I) pincer complex [IrCl{N(CHCHPtBu2)(2)}](-) which was isolated and fully characterized upon stabilization of the counter cation with crown ether as [K(15-cr-5)(2)][IrCl{N(CHCHPtBu2)(2)}]. This unprecedented anionic iridium(I) pincer complex completes the unusual, structurally characterized Ir-I/Ir-II/Ir-III redox series [IrCl{N(CHCHPtBu2)(2)}](-/0/+), all in a square-planar coordination geometry, emphasizing the versatility of this PNP pincer ligand in stabilizing a broad range of oxidation states. The anionic chloro complex is a versatile source of the Ir(PNP) platform. Its reactivity was examined towards chloride ligand substitution against CO and N-2, and oxidative addition of C-electrophiles, C-H bonds and dioxygen, allowing for the isolation of iridium(I) and iridium(III) (PNP) carbonyl, hydrocarbyl and peroxo complexes which were spectroscopically and crystallographically characterized."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft [SCHN950/2]"],["dc.identifier.doi","10.1039/c3dt53304b"],["dc.identifier.isi","000332389700037"],["dc.identifier.pmid","24399308"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/34882"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9234"],["dc.relation.issn","1477-9226"],["dc.title","[IrCl{N(CHCHPtBu2)(2)}](-): a versatile source of the Ir-I(PNP) pincer platform"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","9290"],["dc.bibliographiccitation.issue","19"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","9302"],["dc.bibliographiccitation.volume","54"],["dc.contributor.author","Scheibel, Markus G."],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Kinauer, Markus"],["dc.contributor.author","Heinemann, Frank W."],["dc.contributor.author","Wuertele, Christian"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2018-11-07T09:50:22Z"],["dc.date.available","2018-11-07T09:50:22Z"],["dc.date.issued","2015"],["dc.description.abstract","The redox series [Ir-n(NHx)(PNP)] (n = II-IV, x = 3-0; PNP = N(CHCHPtBu2)(2)) was examined with respect to electron, proton, and hydrogen atom transfer steps. The experimental and computational results suggest that the Ir-III imido species [Ir(NH) (PNP)] is not stable but undergoes to the respective Ir-II amido and Ir-III nitrido species. N-H bond strengths are estimated upon reaction with hydrogen atom transfer reagents to rationalize this observation and are used to discuss the reactivity of these compounds toward E-H bond activation."],["dc.identifier.doi","10.1021/acs.inorgchem.5b00829"],["dc.identifier.isi","000362460800008"],["dc.identifier.pmid","26192601"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/12282"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/35691"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Homolytic N-H Activation of Ammonia: Hydrogen Transfer of Parent Iridium Ammine, Amide, lmide, and Nitride Species"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","6338"],["dc.bibliographiccitation.issue","19"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","6341"],["dc.bibliographiccitation.volume","58"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Delony, Daniel"],["dc.contributor.author","Neben, Marc C."],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2019-07-09T11:51:54Z"],["dc.date.available","2019-07-09T11:51:54Z"],["dc.date.issued","2019"],["dc.description.abstract","The isolable complex [Os(PHMes )H(PNP)] (Mes =2,4,6-t Bu3 C6 H3 ; PNP=N{CHCHPt Bu2 }2 ) exhibits high phosphinyl radical character. This compound offers access to the phosphinidene complex [Os(PMes )H(PNP)] by P-H proton coupled electron transfer (PCET). The P-H bond dissociation energy (BDE) was determined by isothermal titration calorimetry and supporting DFT computations. The phosphinidene product exhibits electrophilic reactivity as demonstrated by intramolecular C-H activation."],["dc.identifier.doi","10.1002/anie.201901470"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/16225"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60037"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.relation.issn","1433-7851"],["dc.rights","CC BY-NC-ND 4.0"],["dc.rights.uri","https://creativecommons.org/licenses/by-nc-nd/4.0"],["dc.subject.ddc","540"],["dc.title","Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","830"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","834"],["dc.bibliographiccitation.volume","58"],["dc.contributor.author","Schendzielorz, Florian"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Krewald, Vera"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2020-01-14T13:35:36Z"],["dc.date.accessioned","2021-10-27T13:12:51Z"],["dc.date.available","2020-01-14T13:35:36Z"],["dc.date.available","2021-10-27T13:12:51Z"],["dc.date.issued","2018"],["dc.identifier.doi","10.1002/anie.201812125"],["dc.identifier.doi","10.1002/ange.201812125"],["dc.identifier.eissn","1521-3773"],["dc.identifier.issn","1433-7851"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17095"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91728"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation","info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED"],["dc.relation.issn","1433-7851"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","N2FEED"],["dc.subject.ddc","540"],["dc.title","Metal-Ligand Cooperative Synthesis of Benzonitrile by Electrochemical Reduction and Photolytic Splitting of Dinitrogen"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","submitted_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","614"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","Nature Chemistry"],["dc.bibliographiccitation.lastpage","614"],["dc.bibliographiccitation.volume","13"],["dc.contributor.author","Sun, Jian"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Verplancke, Hendrik"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Hunger, David"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","van Slageren, Joris"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-06-01T10:50:39Z"],["dc.date.available","2021-06-01T10:50:39Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1038/s41557-020-00613-x"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/86740"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.relation.eissn","1755-4349"],["dc.relation.issn","1755-4330"],["dc.title","Publisher Correction: A platinum(ii) metallonitrene with a triplet ground state"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]