Schneider, Sven

[["dc.bibliographiccitation.artnumber","jacs.2c10743"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.contributor.author","Lv, Ze-Jie"],["dc.contributor.author","Engel, Philipp D."],["dc.contributor.author","Alig, Lukas"],["dc.contributor.author","Maji, Sandipan"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2022-12-01T08:30:47Z"],["dc.date.available","2022-12-01T08:30:47Z"],["dc.date.issued","2022"],["dc.identifier.doi","10.1021/jacs.2c10743"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/117982"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-621"],["dc.relation.eissn","1520-5126"],["dc.relation.issn","0002-7863"],["dc.title","Stabilizing Doubly Deprotonated Diazomethane: Isolable Complexes with CN\n 2\n 2–\n and CN\n 2\n –\n Radical Ligands"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","3994"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","ACS Catalysis"],["dc.bibliographiccitation.lastpage","4003"],["dc.bibliographiccitation.volume","4"],["dc.contributor.author","Chakraborty, Sumit"],["dc.contributor.author","Lagaditis, Paraskevi O."],["dc.contributor.author","Foerster, Moritz"],["dc.contributor.author","Bielinski, Elizabeth A."],["dc.contributor.author","Hazari, Nilay"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Jones, William D."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2018-11-07T09:32:57Z"],["dc.date.available","2018-11-07T09:32:57Z"],["dc.date.issued","2014"],["dc.description.abstract","Acceptorless dehydrogenation of alcohols, an important organic transformation, was accomplished with well-defined and inexpensive iron-based catalysts supported by a cooperating PNP pincer ligand. Benzylic and aliphatic secondary alcohols were dehydrogenated to the corresponding ketones in good isolated yields upon release of dihydrogen. Primary alcohols were dehydrogenated to esters and lactones, respectively. Mixed primary/secondary diols were oxidized at the secondary alcohol moiety with good chemoselectivity. The mechanism of the reaction was investigated using both experiment and DFT calculations, and the crucial role of metalligand cooperativity in the reaction was elucidated. The iron complexes are also excellent catalysts for the hydrogenation of challenging ketone substrates at ambient temperature under mild H-2 pressure, the reverse of secondary alcohol dehydrogenation."],["dc.identifier.doi","10.1021/cs5009656"],["dc.identifier.isi","000344639300022"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/31854"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","2155-5435"],["dc.title","Well-Defined Iron Catalysts for the Acceptor less Reversible Dehydrogenation-Hydrogenation of Alcohols and Ketones"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","15271"],["dc.bibliographiccitation.issue","50"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","15275"],["dc.bibliographiccitation.volume","54"],["dc.contributor.author","Schiwek, Christoph"],["dc.contributor.author","Meiners, Jenni"],["dc.contributor.author","Foerster, Moritz"],["dc.contributor.author","Wuertele, Christian"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2018-11-07T09:47:37Z"],["dc.date.available","2018-11-07T09:47:37Z"],["dc.date.issued","2015"],["dc.description.abstract","The iridium dihydride [Ir(H)(2)(HPNP)](+) (PNP=N(CH2CH2PtBu2)(2)) reacts with O-2 to give the unusual, square-planar iridium(III) hydroxide [Ir(OH)(PNP)](+) and water. Regeneration of the dihydride with H-2 closes a quasi-catalytic synthetic oxygen-reduction reaction (ORR) cycle that can be run several times. Experimental and computational examinations are in agreement with an oxygenation mechanism via rate-limiting O-2 coordination followed by H-transfer at a single metal site, facilitated by the cooperating pincer ligand. Hence, the four electrons required for the ORR are stored within the two covalent M-H bonds of a mononuclear metal complex."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft [SCHN950/2]; COST action [CM1205]"],["dc.identifier.doi","10.1002/anie.201504369"],["dc.identifier.isi","000368057400052"],["dc.identifier.pmid","26511744"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/35152"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.title","Oxygen Reduction with a Bifunctional Iridium Dihydride Complex"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1782"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","1786"],["dc.bibliographiccitation.volume","55"],["dc.contributor.author","Schweizer, Julia I."],["dc.contributor.author","Scheibel, Markus G."],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Neumeyer, Felix"],["dc.contributor.author","Wuertele, Christian"],["dc.contributor.author","Kulminskaya, Natalia"],["dc.contributor.author","Linser, Rasmus"],["dc.contributor.author","Auner, Norbert"],["dc.contributor.author","Schneider, Sven"],["dc.contributor.author","Holthausen, Max C."],["dc.date.accessioned","2018-11-07T10:19:10Z"],["dc.date.available","2018-11-07T10:19:10Z"],["dc.date.issued","2016"],["dc.description.abstract","An experimental and theoretical study of the base-stabilized disilene 1 is reported, which forms at low temperatures in the disproportionation reaction of Si2Cl6 or neo-Si5Cl12 with equimolar amounts of NMe2Et. Single-crystal X-ray diffraction and quantum-chemical bonding analysis disclose an unprecedented structure in silicon chemistry featuring a dative Si -> Si single bond between two silylene moieties, Me2EtN -> SiCl2 -> Si(SiCl3)(2). The central ambiphilic SiCl2 group is linked by dative bonds to the amine donor and the bis(trichlorosilyl) silylene acceptor, which leads to push-pull stabilization. Based on experimental and theoretical examinations a formation mechanism is presented that involves an autocatalytic reaction of the intermediately formed anion Si(SiCl3)(3)(-) with neo-Si5Cl12 to yield 1."],["dc.identifier.doi","10.1002/anie.201510477"],["dc.identifier.isi","000369854000033"],["dc.identifier.pmid","26696311"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/41609"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.title","A Disilene Base Adduct with a Dative Si-Si Single Bond"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1054"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","Nature Chemistry"],["dc.bibliographiccitation.lastpage","1059"],["dc.bibliographiccitation.volume","12"],["dc.contributor.author","Sun, Jian"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Verplancke, Hendrik"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Hunger, David"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","van Slageren, Joris"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-04-14T08:24:29Z"],["dc.date.available","2021-04-14T08:24:29Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1038/s41557-020-0522-4"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17872"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/81300"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1755-4349"],["dc.relation.issn","1755-4330"],["dc.rights.access","openAccess"],["dc.subject.ddc","540"],["dc.title","A platinum(ii) metallonitrene with a triplet ground state"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","614"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","Nature Chemistry"],["dc.bibliographiccitation.lastpage","614"],["dc.bibliographiccitation.volume","13"],["dc.contributor.author","Sun, Jian"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Verplancke, Hendrik"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Hunger, David"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","van Slageren, Joris"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-06-01T10:50:39Z"],["dc.date.available","2021-06-01T10:50:39Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1038/s41557-020-00613-x"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/86740"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.relation.eissn","1755-4349"],["dc.relation.issn","1755-4330"],["dc.title","Publisher Correction: A platinum(ii) metallonitrene with a triplet ground state"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.contributor.author","Schmidt-Räntsch, Till"],["dc.contributor.author","Verplancke, Hendrik"],["dc.contributor.author","Lienert, Jonas N."],["dc.contributor.author","Demeschko, Serhiy"],["dc.contributor.author","Otte, Matthias"],["dc.contributor.author","Van Trieste, Gerard P."],["dc.contributor.author","Reid, Kaleb A."],["dc.contributor.author","Reibenspies, Joseph H."],["dc.contributor.author","Powers, David C."],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2022-01-11T14:08:09Z"],["dc.date.available","2022-01-11T14:08:09Z"],["dc.date.issued","2021"],["dc.identifier.doi","10.1002/anie.202115626"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/97945"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-507"],["dc.relation.eissn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.title","Nitrogen Atom Transfer Catalysis by Metallonitrene C–H Insertion: Photocatalytic Amidation of Aldehydes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","10971"],["dc.bibliographiccitation.issue","32"],["dc.bibliographiccitation.journal","Angewandte Chemie. International Edition"],["dc.bibliographiccitation.lastpage","10974"],["dc.bibliographiccitation.volume","58"],["dc.contributor.author","Delony, Daniel"],["dc.contributor.author","Kinauer, Markus"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2020-12-10T14:05:38Z"],["dc.date.available","2020-12-10T14:05:38Z"],["dc.date.issued","2019"],["dc.identifier.doi","10.1002/anie.201905325"],["dc.identifier.eissn","1521-3773"],["dc.identifier.issn","1433-7851"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17097"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/69603"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.title","A Terminal Iridium Oxo Complex with a Triplet Ground State"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4325"],["dc.bibliographiccitation.issue","18"],["dc.bibliographiccitation.journal","Chemical Science"],["dc.bibliographiccitation.lastpage","4332"],["dc.bibliographiccitation.volume","9"],["dc.contributor.author","Kinauer, Markus"],["dc.contributor.author","Diefenbach, Martin"],["dc.contributor.author","Bamberger, Heiko"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Reijerse, Edward J."],["dc.contributor.author","Volkmann, Christian"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","van Slageren, Joris"],["dc.contributor.author","de Bruin, Bas"],["dc.contributor.author","Schneider, Sven"],["dc.contributor.author","Holthausen, Max C."],["dc.date.accessioned","2021-06-01T10:50:50Z"],["dc.date.available","2021-06-01T10:50:50Z"],["dc.date.issued","2018"],["dc.description.abstract","An iridium( iii – v ) imido series has been isolated that features an iridium complex with an unprecedented triplet ground state."],["dc.description.abstract","The iridium( iii / iv / v ) imido redox series [Ir(N t Bu){N(CHCHP t Bu 2 ) 2 }] 0/+/2+ was synthesized and examined spectroscopically, magnetically, crystallographically and computationally. The monocationic iridium( iv ) imide exhibits an electronic doublet ground state with considerable ‘imidyl’ character as a result of covalent Ir–N t Bu bonding. Reduction gives the neutral imide [Ir(N t Bu){N(CHCHP t Bu 2 ) 2 }] as the first example of an iridium complex with a triplet ground state. Its reactivity with respect to nitrene transfer to selected electrophiles (CO 2 ) and nucleophiles (PMe 3 ), respectively, is reported."],["dc.identifier.doi","10.1039/C8SC01113C"],["dc.identifier.eissn","2041-6539"],["dc.identifier.issn","2041-6520"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/86803"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-425"],["dc.relation.eissn","2041-6539"],["dc.relation.issn","2041-6520"],["dc.title","An iridium( iii / iv / v ) redox series featuring a terminal imido complex with triplet ground state"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","14367"],["dc.bibliographiccitation.issue","19"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","14375"],["dc.bibliographiccitation.volume","59"],["dc.contributor.author","Abbenseth, Josh"],["dc.contributor.author","Oudsen, Jean-Pierre H."],["dc.contributor.author","Venderbosch, Bas"],["dc.contributor.author","Demeshko, Serhiy"],["dc.contributor.author","Finger, Markus"],["dc.contributor.author","Herwig, Christian"],["dc.contributor.author","Würtele, Christian"],["dc.contributor.author","Holthausen, Max C."],["dc.contributor.author","Limberg, Christian"],["dc.contributor.author","Tromp, Moniek"],["dc.contributor.author","Schneider, Sven"],["dc.date.accessioned","2021-04-14T08:31:55Z"],["dc.date.available","2021-04-14T08:31:55Z"],["dc.date.issued","2020"],["dc.identifier.doi","10.1021/acs.inorgchem.0c02134"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17871"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/83751"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","Examination of Protonation-Induced Dinitrogen Splitting by in Situ EXAFS Spectroscopy"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]