García, Nuria

[["dc.bibliographiccitation.firstpage","1460"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Journal of Polymer Science Part A Polymer Chemistry"],["dc.bibliographiccitation.lastpage","1469"],["dc.bibliographiccitation.volume","46"],["dc.contributor.author","Woecht, Inga"],["dc.contributor.author","Schmidt-Naake, Gudrun"],["dc.contributor.author","Beuermann, Sabine"],["dc.contributor.author","Buback, Michael"],["dc.contributor.author","Garcia, Nuria"],["dc.date.accessioned","2018-11-07T11:18:18Z"],["dc.date.available","2018-11-07T11:18:18Z"],["dc.date.issued","2008"],["dc.description.abstract","Propagation rate coefficients, k(p), of methyl methacrylate (MMA) and glycidyl methacrylate (GMA) homopolymerizations were measured at ambient pressure in four ionic liquids (ILs): 1-ethyl-3-methylimidazolium ([emim]) ethyl sulfate and [emim] hexyl sulfate as well as butyl-3-methylimidazolium ([bmim]) hexafluorophosphate and [bmim] tetrafluoroborate via the pulsed-laser polymerization size-exclusion chromatography technique. In passing from bulk polymerization at 40 degrees C polymerization in IL solution containing 20 vol % monomer, k(p) is enhanced by up to a factor of 4 with MMA and by a factor of 2 with GMA. This enhancement of kp primarily results from a lowering of activation energy upon partial replacement of monomer by ionic liquid species. (c) 2008 Wiley Periodicals, Inc."],["dc.identifier.doi","10.1002/pola.22485"],["dc.identifier.isi","000253221300028"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/55006"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","John Wiley & Sons Inc"],["dc.relation.issn","0887-624X"],["dc.title","Propagation kinetics of free-radical polymerizations in ionic liquids"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]