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Schill, Heiko
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Schill, Heiko
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Schill, Heiko
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Schill, H.
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2007Journal Article [["dc.bibliographiccitation.issue","18"],["dc.bibliographiccitation.journal","ChemInform"],["dc.bibliographiccitation.volume","38"],["dc.contributor.author","de Meijere, Armin"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Schill, Heiko"],["dc.date.accessioned","2021-12-08T12:29:34Z"],["dc.date.available","2021-12-08T12:29:34Z"],["dc.date.issued","2007"],["dc.identifier.doi","10.1002/chin.200718249"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/96125"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-476"],["dc.relation.eissn","1522-2667"],["dc.relation.issn","0931-7597"],["dc.rights.uri","http://doi.wiley.com/10.1002/tdm_license_1.1"],["dc.title","Three-Membered-Ring-Based Molecular Architectures"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]Details DOI2012Journal Article [["dc.bibliographiccitation.firstpage","6953"],["dc.bibliographiccitation.issue","35"],["dc.bibliographiccitation.journal","European Journal of Organic Chemistry"],["dc.bibliographiccitation.lastpage","6958"],["dc.contributor.author","de Meijere, Armin"],["dc.contributor.author","Redlich, Stefan"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Yufit, Dmitry S."],["dc.contributor.author","Magull, Joerg"],["dc.contributor.author","Vidovic, Denis"],["dc.contributor.author","Schill, Heiko"],["dc.contributor.author","Menzel, Henning"],["dc.date.accessioned","2018-11-07T09:02:47Z"],["dc.date.available","2018-11-07T09:02:47Z"],["dc.date.issued","2012"],["dc.description.abstract","(E,E)-1,2,3,4-Tetracyclopropylbuta-1,3-diene (3) and (Z,Z)-1,4-diodo-1,2,3,4-tetracyclopropylbuta-1,3-diene (4) were prepared from dicyclopropylacetylene via an intermediate 2,3,4,5-tetracyclopropyltitanacyclopentadiene (2) in 91 and 77% yield, respectively. In the crystal, 3 adopts a conformation with an almost coplanar (phi = 163 degrees) 1,3-diene core, with the inner vinylcyclopropane units in an orthogonal and the outer vinylcyclopropane moieties in an s-trans orientation. This diene, like 2,3-cyclopropylbuta-1,3-diene (5), undergoes facile concerted [4+2] cycloadditions at 130 degrees C with dimethyl acetylenedicarboxylate as well as N-phenylmaleimide and at 0 degrees C with N-phenyltriazolinedione. An X-ray crystal structure analysis of 2,3-dicyclopropylbuta-1,3-diene (5) also reveals a coplanar inner core with the vinylcyclopropane units in essentially orthogonal (phi(av)=89.3 degrees) orientation. Differential scanning calorimetry (DSC) measurements indicate that 3 undergoes significant internal reorganization on going from the liquid to the crystalline phase, and a gauche conformer of 3 may well be favored over the s-trans conformer in the liquid."],["dc.identifier.doi","10.1002/ejoc.201201054"],["dc.identifier.isi","000312035900015"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/24762"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1434-193X"],["dc.title","(E,E)-1,2,3,4-Tetracyclopropylbuta-1,3-diene: Synthesis and Some of Its Properties"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]Details DOI WOS2004Journal Article [["dc.bibliographiccitation.firstpage","289"],["dc.bibliographiccitation.issue","2"],["dc.bibliographiccitation.journal","European Journal of Organic Chemistry"],["dc.bibliographiccitation.lastpage","303"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Langer, R."],["dc.contributor.author","Yufit, Dmitry S."],["dc.contributor.author","Howard, JAK"],["dc.contributor.author","Schill, H."],["dc.contributor.author","Demus, D."],["dc.contributor.author","Miyazawa, K."],["dc.contributor.author","de Meijere, Armin"],["dc.date.accessioned","2018-11-07T10:51:46Z"],["dc.date.available","2018-11-07T10:51:46Z"],["dc.date.issued","2004"],["dc.description.abstract","Additions of ethyl or tert-butyl diazoacetates to 4-substituted cyclopentenes 6 and 17 under dirhodium tetraacetate/tetraoctanoate catalysis led to mixtures of tert-butyl endo,exo and exo,exo-3-carboxyl(aryl)bicyclo[3.1.0]hexane-6-carboxylates 7 and 18 in yields of 54-90% from which exo,exodiastereomers were isolated in yields of 39-63%. Diester exo,exo-7 was saponified and converted into diaryl diesters exo,exo-9a,b in overall yields of 42 and 46%, respectively. The esters exo,exo-18 were reduced to the corresponding hydroxymethyl derivatives, these were transformed to the iodomethyl compounds which in turn were coupled with various alkylmagnesium halides, via Li2CuCl4 catalysis, to give 3-aryl-6-alkylbicyclo[3.1.0]hexyl derivatives exo,exo-21 in overall yields of 72-83%. Fluorinated 3-(2-arylethyl)-6-pentylbicyclo[3.1.0]hexane exo,exo-32 could be prepared in five steps from 4-ethoxy-2,3-difluorobenzaldehyde 26a adopting essentially the same synthetic strategy, but in an overall yield of only 8%, and 6-(4-cyanophenyl)-3-pentylbicyclo[3.1.0]hexane exo,exo-38b was obtained by Pd(OAC)(2) catalyzed cyclopropanation of 4-pentylcyclopentene 34b with (4-cyanophenyl)diazomethane 36b in 29% yield. A comparison of the liquid crystalline properties of these newly prepared compounds containing a bicyclo[3.1.0]hexane core with those of the known analogous compounds with a cyclohexane fragment shows that as a rule, a bicyclo[3.1.0]hexane moiety decreases the transition temperature, while the dielectric (Deltaepsilon) and optical (Deltan) anisotropies are comparable. However, the bicyclo[3.1.0]hexane unit has a poorer mesogenic potential."],["dc.identifier.doi","10.1002/ejoc.200300448"],["dc.identifier.isi","000188531600006"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/48960"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1434-193X"],["dc.title","Novel liquid crystalline compounds containing bicyclo[3.1.0]hexane core units"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]Details DOI WOS2007Journal Article [["dc.bibliographiccitation.firstpage","167"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","177"],["dc.bibliographiccitation.volume","13"],["dc.contributor.author","Seebach, Malte von"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Schill, Heiko"],["dc.contributor.author","Frank, Daniel"],["dc.contributor.author","Boese, Roland"],["dc.contributor.author","Benet-Buchholz, Jordi"],["dc.contributor.author","Yufit, Dmitry S."],["dc.contributor.author","Meijere, Armin de"],["dc.date.accessioned","2018-11-07T11:06:12Z"],["dc.date.available","2018-11-07T11:06:12Z"],["dc.date.issued","2007"],["dc.description.abstract","Diastereomeric meso- and d,l-bis(bicyclopropylidenyl) (5) were obtained upon oxidation with oxygen of a higher-order cuprate generated from lithiobicyclopropylidene (4) in 50 and 31 % yield, respectively. Their perdeuterated analogues meso-[D(14)]- and d,l-[D(14)]-5 were obtained along the same route from perdeuterated bicyclopropylidene [D(8)]-3 (synthesized in six steps in 7.4% overall yield from [D(8)]-THF) in 20.5 % yield each. Dehalogenative coupling of 1,1-dibromo-2-cyclopropylcyclopropane (6) gave a mixture of all possible stereoisomers of 1,5-dicyclopropylbicyclopropylidene 16 in 69% yield, from which (Z)-cis-16 was separated by preparative gas chromatography (26% yield). The crystal structure of meso-5 looks like a superposition of the crystal structures of two outer bicyclopropylidene units (3) and one inner s-trans-bicyclopropyl unit, whereas the two outer cyclopropyl moieties adopt a gauche orientation with respect to the cyclopropane rings at the inner bicyclopropylidene units in (Z)-cis-16. Birch reduction with lithium in liquid ammonia of meso-5 and d,l-5 gave two pairs of diastereomeric quatercyclopropanes trans,trans-(R ,S ,R , S )-17/cis,trans-(R ,S ,R ,R )-18 and trans,trans-(R ,S ,S ,R )-19/cis,trans- (R ,S ,S ,S )-20 in 97 and 76% yield, respectively, in a ratio 9:1 for every pair. The latter diastereomer was also obtained as the sole product by Birch reduction of (Z)-cis-16 in 96% yield. Under the same conditions, tetradecadeuterio analogues trans,trans-[D(14)](R ,S ,R ,S )-171cis,trans-[D(14)]-(R , S ,R ,R )-18 (8:1) and trans,trans[D(14)]-(R ,S ,S ,R )-19/cis,trans-[D(14)]- (R ,S ,S ,S )-20 (12:1) were prepared from meso-[D(14)]-5 and d,l-[D(14)]-5 in 37 and 63% yield, respectively. Reduction of meso-5 with diimine gave the cis,cisquatercyclopropane (S ,S ,R ,R )-21 as the main product (58% yield) along (Z)-cis-16. Birch reduction with lithium in liquid ammonia of meso-5 and d,l-5 gave two pairs of diastereomeric quatercyclopropanes trans,trans-(R ,S ,R , S )-17/cis,trans-(R ,S ,R ,R )-18 and trans,trans-(R ,S ,S ,R )-19/cis,trans-(R ,S ,S ,S )-20 in 97 and 76% yield, respectively, in a ratio 9:1 for every pair. The latter diastereomer was also obtained as the sole product by Birch reduction of (Z)-cis-16 in 96% yield. Under the same conditions, tetradecadeuterio analogues trans,trans-[D(14)](R ,S ,R ,S )-17/cis,trans-[D(14)]-(R , S ,R ,R )-18 (8:1) and trans,trans[D(14)]-(R ,S ,S ,R )-191cis,trans-[D(14)]- (R ,S ,S ,S )-20 (12:1) were prepared from meso-[D(14)]-5 and d,l-[D(14)]-5 in 37 and 63% yield, respectively. Reduction of meso-5 with diimine gave the cis,cis-quatercyclopropane (S ,S ,R ,R )-21 as the main product (58% yield) along with the cis,trans-diastereomer (S ,S ,R ,S )-18 (29 % yield). Thus, five of the six possible diastereomeric quatercyclopropanes were obtained from meso-5, d,l-5, and (Z)-cis-16. ne X-ray crystal structure analyses of trans, trans- (R ,S ,R ,S ) - 17 and cis,cis(S ,S ,R ,R )-21 revealed for the both an unusual conformation in which the central bicyclopropyl unit adopts an strans- (anti periplanar) orientation with phi=180.0 degrees, and the two terminal bicyclopropyl moieties adopt a synclinal conformation with phi=49.8 and 72.0 degrees, respectively. In solution the vicinal coupling constants <(3)J(H,H)> in trans,trans(R ,S ,R ,S )-[D(14)]-17, trans,trans(R ,S ,S ,R )-[D(14)]-19, trns,cis(R ,S ,R ,R )-[D(14)]-18 and trans,cis(R ,S ,S ,S )-[D(14)]-20 were found to be 4.1, 4.7, 5.9 and 5.9 Hz, respectively. This indicates a predominance of the all-gauche conformer in (R ,S ,R ,S )17 and a decreasing fraction of it in this sequence of the other diastereomers."],["dc.identifier.doi","10.1002/chem.200600799"],["dc.identifier.isi","000244231500015"],["dc.identifier.pmid","17024706"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/52252"],["dc.language.iso","en"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.relation.issn","0947-6539"],["dc.title","Stereoselective preparation of six diastereomeric quatercyclopropanes from bicyclopropylidene and some derivatives"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]Details DOI PMID PMC WOS2004Journal Article Research Paper [["dc.bibliographiccitation.firstpage","947"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Russian Chemical Bulletin"],["dc.bibliographiccitation.lastpage","959"],["dc.bibliographiccitation.volume","53"],["dc.contributor.author","Meijere, Armin de"],["dc.contributor.author","Schill, Heiko"],["dc.contributor.author","Kozhushkov, S. I."],["dc.contributor.author","Walsh, R."],["dc.contributor.author","Müller, E. Matthias"],["dc.contributor.author","Grubmüller, Helmut"],["dc.date.accessioned","2017-09-07T11:43:54Z"],["dc.date.available","2017-09-07T11:43:54Z"],["dc.date.issued","2004"],["dc.description.abstract","The routes of transformation of the simplest bicyclopropylidene into the derivatives of the second and third generations and synthesis of perspirocyclopropanated [3]rotane and linear spiral [4]- and [5]triangulanes are discussed."],["dc.identifier.doi","10.1023/B:RUCB.0000041297.57787.d1"],["dc.identifier.gro","3143995"],["dc.identifier.isi","000223947800001"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/1571"],["dc.language.iso","en"],["dc.notes.intern","WoS Import 2017-03-10"],["dc.notes.status","final"],["dc.notes.submitter","PUB_WoS_Import"],["dc.relation.issn","1066-5285"],["dc.title","Cyclopropylidenes, bicyclopropylidenes, and vinylcarbenes - some modes of formation and preparative applications"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.subtype","original"],["dspace.entity.type","Publication"]]Details DOI WOS2003Journal Article [["dc.bibliographiccitation.firstpage","15110"],["dc.bibliographiccitation.issue","49"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","15113"],["dc.bibliographiccitation.volume","125"],["dc.contributor.author","de Meijere, Armin"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Rauch, K."],["dc.contributor.author","Schill, H."],["dc.contributor.author","Verevkin, S. P."],["dc.contributor.author","Kummerlin, M."],["dc.contributor.author","Beckhaus, H. D."],["dc.contributor.author","Ruchardt, C."],["dc.contributor.author","Yufit, Dmitry S."],["dc.date.accessioned","2018-11-07T10:34:07Z"],["dc.date.available","2018-11-07T10:34:07Z"],["dc.date.issued","2003"],["dc.description.abstract","The enthalpies of formation [DeltaH(t)(o)(g)] of tricyclo[8.2.2.2(4.7)]hexadeca-1(13),2,4(16),5,7(15),10-(14),11-heptaene (2, 1,2-dehydro[2.2]paracyclophane or [2.2]paracyclophane-1-ene) and tricyclo[8.2.2.2(4.7)]-hexadeca-1(13),2,4(16),5,7(15),8,10(14),11-octaene (3, 1,2,9,10-dehydro[2.2]paracyclophane or [2.2]-paracyclophane-1,9-diene) have been determined by measuring their heats of combustion in a microcalorimeter and their heats of sublimation by the transpiration method. Values of the strain energies (SE) [SE(2) = 34.7 kcal mol(-1), SE(3) = 42.0 kcal mol-1] have been derived from the gas-phase heats of formation and are compared with those from MM3 and PM3 calculations and with the corresponding value SE(1) = 30.1 kcal mol(-1) for the parent tricyclo[8.2.2.2(4.7)]hexadeca-1(13),4(16),5,7(15),10(14),11-hexaene (1, [2.2]-paracyclophane). The higher strain energies of 2 and 3 (by 4.6 and 11.9 kcal mol(-1)) are in accord with the well-known increased reactivities of their aromatic rings as a consequence of their increased bending. As revealed by an X-ray crystal structure analysis, the bending in the monoene 2 corresponds to that of 1 and 3 at one of two bridging corners."],["dc.identifier.doi","10.1021/ja0374628"],["dc.identifier.isi","000187007400040"],["dc.identifier.pmid","14653746"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/44780"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0002-7863"],["dc.title","Heats of formation of [2.2]paracyclophane-1-ene and [2.2]paracyclophane-1,9-diene - An experimental study"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]Details DOI PMID PMC WOS2006Review [["dc.bibliographiccitation.firstpage","4926"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Chemical Reviews"],["dc.bibliographiccitation.lastpage","4996"],["dc.bibliographiccitation.volume","106"],["dc.contributor.author","de Meijere, Armin"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Schill, Heiko"],["dc.date.accessioned","2018-11-07T08:50:54Z"],["dc.date.available","2018-11-07T08:50:54Z"],["dc.date.issued","2006"],["dc.identifier.doi","10.1021/cr0505369"],["dc.identifier.isi","000242826700008"],["dc.identifier.pmid","17165680"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/21802"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0009-2665"],["dc.title","Three-membered-ring-based molecular architectures"],["dc.type","review"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]Details DOI PMID PMC WOS2012Journal Article [["dc.bibliographiccitation.firstpage","1530"],["dc.bibliographiccitation.issue","8"],["dc.bibliographiccitation.journal","European Journal of Organic Chemistry"],["dc.bibliographiccitation.lastpage","1545"],["dc.contributor.author","Khlebnikov, Alexander F."],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Yufit, Dmitry S."],["dc.contributor.author","Schill, Heiko"],["dc.contributor.author","Reggelin, Michael"],["dc.contributor.author","Spohr, Volker"],["dc.contributor.author","de Meijere, Armin"],["dc.date.accessioned","2018-11-07T09:12:40Z"],["dc.date.available","2018-11-07T09:12:40Z"],["dc.date.issued","2012"],["dc.description.abstract","A new original strategy for the synthesis of axially and helically chiral bidentate diphosphane ligands featuring a rigid triangulanyl backbone has been elaborated and executed for several representative enantiomerically pure ligands. Thus,(1R,3S,4S)-1,4-bis[(diphenylphosphanyl)methyl]spiro[2.2]pentane [(1R,3S,4S)-24.(BH3)2], [(1R,3R,4S)-4-(diphenylphosphanyl)methylspiro[2.2]pentan-1-yl]diphenylphosphane [(1R,3R,4S)-27.(BH3)2], [(1R,3R,4S,5R)-5-(diphenylphosphanyl)methyldispiro[2.0.2.1]heptan-1-yl]diphenylphosphane [(1R,3R,4S,5R)-30.(BH3)2], (1S,3S,4S)-1,4-bis(diphenylphosphanyl)spiropentane [(1R,3S,4S)-35.(BH3)2], (1S,3S,4S)-1,4-bis(diphenylphosphanyl)spiropentane [(1S,3S,4S)-35.(BH3)2], (1S,3S,4S)-1,4-bis(diphenylphosphanyl)spiropentane [(1R,3R,4S)-35.(BH3)2], and (1R,3R,4R,5R)-1,5-bis(diphenylphosphanyl)dispiro[2.0.2.1]heptane [(1R,3R,4R,5R)-36.(BH3)2] with a spiropentyl and a dispiro[2.0.2.1]heptyl moiety, respectively, have been prepared as bishydroborane complexes applying repetitively the same set of standard synthetic operations, starting from [(1S,3R)-4-methylenespiropent-1-yl]methyl acetate [(1S,3R)-7], (4,4-dibromospiropent-1-yl)methanols [(1S,3R)-8 and (1R,3S)-8] and (dibromodispiro[2.0.2.1]heptyl)methanols (1R,3S,4R)-9, (1S,3R,4S)-9 and (1S,3R,4R)-9 in 47 steps. The relative configurations of all important intermediates as well as the absolute configurations of the key intermediates and most final products were established by X-ray crystal structure analyses."],["dc.identifier.doi","10.1002/ejoc.201101715"],["dc.identifier.isi","000300930800010"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/26992"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1434-193X"],["dc.title","A Novel Type of Chiral Triangulane-Based Diphosphane Ligands for Transition Metals"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]Details DOI WOS2007Journal Article [["dc.bibliographiccitation.firstpage","1510"],["dc.bibliographiccitation.issue","9"],["dc.bibliographiccitation.journal","European Journal of Organic Chemistry"],["dc.bibliographiccitation.lastpage","1516"],["dc.contributor.author","Schill, Heiko"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Walsh, Robin"],["dc.contributor.author","de Meijere, Armin"],["dc.date.accessioned","2018-11-07T11:04:19Z"],["dc.date.available","2018-11-07T11:04:19Z"],["dc.date.issued","2007"],["dc.description.abstract","The overall and the individual rate constants of the unimolecular thermal isomerization of methylenespiropentane (4) to 1,2- and 1,3-dimethylenecyclobutanes (7 and 8) have been determined to be lg (k(-4)/s(-1)) = (13.78 +/- 0.06) - (49.7 +/- 0.2) kcal mol(-1)/RT.ln 10, lg(k(7)/s(-1)) = (13.03 +/- 0.19) - (48.0 +/- 0.6) kcal mol(-1)/RT.ln 10 and lg(k(8)/s(-1)) = (14.15 +/- 0.19) - (52.4 +/- 0.5) kcal mol(-1)/RT.ln 10, respectively. The activation energies are significantly lower than that for the rearrangement of the parent spiropentane. ((c) Wiley-VCH Verlag GmbH & Co."],["dc.identifier.doi","10.1002/ejoc.200601100"],["dc.identifier.isi","000245364200012"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/51814"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1434-193X"],["dc.title","The thermal transformations of bicyclopropylidene and methylenespiropentane revisited"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]Details DOI WOS2007Journal Article [["dc.bibliographiccitation.firstpage","6545"],["dc.bibliographiccitation.issue","34"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","6548"],["dc.bibliographiccitation.volume","46"],["dc.contributor.author","Kurahashi, Takuya"],["dc.contributor.author","Kozhushkov, Sergei I."],["dc.contributor.author","Schill, Heiko"],["dc.contributor.author","Meindl, Kathrin"],["dc.contributor.author","Ruehl, Stephan"],["dc.contributor.author","Meijere, Armin de"],["dc.date.accessioned","2018-11-07T11:05:54Z"],["dc.date.available","2018-11-07T11:05:54Z"],["dc.date.issued","2007"],["dc.identifier.doi","10.1002/anie.200702013"],["dc.identifier.isi","000249296900035"],["dc.identifier.pmid","17645288"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/52176"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.relation.issn","1433-7851"],["dc.title","1,1 '-Linked cyclopropane derivatives: The helical conformation of quinquecyclopropanol"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]Details DOI PMID PMC WOS