Clever, Guido Heinrich

[["dc.bibliographiccitation.firstpage","10102"],["dc.bibliographiccitation.issue","38"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","10106"],["dc.bibliographiccitation.volume","52"],["dc.contributor.author","Frank, Marina"],["dc.contributor.author","Hey, Jakob"],["dc.contributor.author","Balcioglu, Ilker"],["dc.contributor.author","Chen, Yu-Sheng"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Suenobu, Tomoyoshi"],["dc.contributor.author","Fukuzumi, Shunichi"],["dc.contributor.author","Frauendorf, Holm"],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T09:19:53Z"],["dc.date.available","2018-11-07T09:19:53Z"],["dc.date.issued","2013"],["dc.identifier.doi","10.1002/anie.201302536"],["dc.identifier.isi","000324309900050"],["dc.identifier.pmid","23881819"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/28748"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1521-3773"],["dc.relation.issn","1433-7851"],["dc.title","Assembly and Stepwise Oxidation of Interpenetrated Coordination Cages Based on Phenothiazine"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2191"],["dc.bibliographiccitation.issue","9"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","2194"],["dc.bibliographiccitation.volume","51"],["dc.contributor.author","Freye, Sabrina"],["dc.contributor.author","Hey, Jakob"],["dc.contributor.author","Torras-Galan, Anna"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","John, Michael"],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T09:15:28Z"],["dc.date.available","2018-11-07T09:15:28Z"],["dc.date.issued","2012"],["dc.description.sponsorship","CaSuS program of the state of Lower Saxony"],["dc.identifier.doi","10.1002/anie.201107184"],["dc.identifier.isi","000300691900035"],["dc.identifier.pmid","22253128"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/27700"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1433-7851"],["dc.title","Allosteric Binding of Halide Anions by a New Dimeric Interpenetrated Coordination Cage"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","6863"],["dc.bibliographiccitation.issue","20"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","6866"],["dc.bibliographiccitation.volume","139"],["dc.contributor.author","Schulte, Thorben R."],["dc.contributor.author","Holstein, Julian Jacob"],["dc.contributor.author","Krause, Lennard"],["dc.contributor.author","Michel, Reent"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Sakuda, Eri"],["dc.contributor.author","Umakoshi, Keisuke"],["dc.contributor.author","Longhi, Giovanna"],["dc.contributor.author","Abbate, Sergio"],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T10:23:40Z"],["dc.date.available","2018-11-07T10:23:40Z"],["dc.date.issued","2017"],["dc.description.abstract","The synthesis and characterization of a new kind of cis- and trans-cyclometalated square-planar platinum(II) complexes is reported. Uncharged organometallic compounds carrying one or two of the CAN-donor ligand L-CN were prepared. Due to the heterobidentate coordination of the achiral chelate ligand, the formed [ptL(CN)Cl(SEt2)], cis- and trans-[PtL2CN] complexes are chiral with the metal serving as the stereo center. The enantiomers of complex trans-[PtL2CN] could be separated and their absolute configuration was determined by anomalous X-ray diffraction, in accordance with CD spectroscopic results and TD-DFT calculations. All compounds were fully characterized by NMR spectroscopy, mass spectrometry and X-ray structure determination. The photophysical properties of trans-[PtL2CN]] have been investigated showing phosphorescence in solution and in the solid state with a moderate quantum yield. For the enantiomers, strong circular dichroism (CD) and circularly polarized luminescence (CPL) effects were observed, rendering this new structural motif suitable for application in chiroptical and luminescent materials."],["dc.description.sponsorship","DFG; FCI"],["dc.identifier.doi","10.1021/jacs.7b03963"],["dc.identifier.isi","000402498500021"],["dc.identifier.pmid","28481510"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/42507"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","PUB_WoS_Import"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0002-7863"],["dc.title","Chiral-at-Metal Phosphorescent Square-Planar Pt(II)-Complexes from an Achiral Organometallic Ligand"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1060"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","1063"],["dc.bibliographiccitation.volume","137"],["dc.contributor.author","Loeffler, Susanne"],["dc.contributor.author","Luebben, Jens"],["dc.contributor.author","Krause, Lennard"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Dittrich, Birger"],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T10:01:54Z"],["dc.date.available","2018-11-07T10:01:54Z"],["dc.date.issued","2015"],["dc.description.abstract","Molecular encapsulation processes under the control of an external trigger play a major role in biological signal transduction processes and enzyme catalysis. Here, we present an artificial mimic of a controllable host system that forms via self-assembly from a simple bis-monodentate ligand and Pd(II) cations. The resulting interpenetrated double cage features three consecutive pockets which initially contain one tetrafluoroborate anion, each. Activation of this host system with two halide anions triggers a conformational change that renders the central pocket susceptible to the uptake of small neutral guest molecules. Thereby, the pentacationic cage expels the central anion and replaces it with a neutral molecule to give a hexacationic species. The cage structures prior and after the halide triggered binding of benzene were examined by X-ray crystallography, ESI MS, and NMR techniques. The kinetics and thermodynamics of the encapsulation of benzene, cyclohexane, and norbornadiene are compared."],["dc.description.sponsorship","DFG [CL 489/2-1]; Fonds der Chemischen Industrie"],["dc.identifier.doi","10.1021/ja5130379"],["dc.identifier.isi","000348690100014"],["dc.identifier.pmid","25569812"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/38126"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0002-7863"],["dc.title","Triggered Exchange of Anionic for Neutral Guests inside a Cationic Coordination Cage"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1319"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","1323"],["dc.bibliographiccitation.volume","52"],["dc.contributor.author","Han, Muxin"],["dc.contributor.author","Michel, Reent"],["dc.contributor.author","He, Bice"],["dc.contributor.author","Chen, Yu-Sheng"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","John, Michael"],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T09:30:32Z"],["dc.date.available","2018-11-07T09:30:32Z"],["dc.date.issued","2013"],["dc.identifier.doi","10.1002/anie.201207373"],["dc.identifier.isi","000313719300047"],["dc.identifier.pmid","23208865"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/31329"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1433-7851"],["dc.title","Light-Triggered Guest Uptake and Release by a Photochromic Coordination Cage"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","9574"],["dc.bibliographiccitation.issue","18"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","9576"],["dc.bibliographiccitation.volume","51"],["dc.contributor.author","Han, Muxin"],["dc.contributor.author","Hey, Jakob"],["dc.contributor.author","Kawamura, Wataru"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Shionoya, Mitsuhiko"],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T09:05:50Z"],["dc.date.available","2018-11-07T09:05:50Z"],["dc.date.issued","2012"],["dc.description.abstract","A self-assembled cage compound consisting of four concave ligands and two square-planar-coordinated Pd-II ions was found to quantitatively encapsulate a hexamolybdate dianion [Mo6O19](2-) in solution. The addition of 1 equiv more of [Mo6O19](2-) to the inclusion complex resulted in the formation of a precipitate from which single crystals were grown. X-ray analysis showed that a structural conversion had taken place upon crystallization: one hexamolybdate anion was found to be wrapped in a chiral, cyclic arrangement of three ligands in the absence of any Pd-II ions to give a compound of the formula {[Mo6O19](2-)@(ligand)(3)+2H(+)}. We postulate the stabilization of this arrangement by attractive C-H center dot center dot center dot O and CF3-pyridine interactions."],["dc.identifier.doi","10.1021/ic301359n"],["dc.identifier.isi","000308778000002"],["dc.identifier.pmid","22931252"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/25416"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.title","An Inclusion Complex of Hexamolybdate inside a Supramolecular Cage and Its Structural Conversion"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4587"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","4592"],["dc.bibliographiccitation.volume","43"],["dc.contributor.author","Frank, Marina"],["dc.contributor.author","Krause, Lennard"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T09:46:30Z"],["dc.date.available","2018-11-07T09:46:30Z"],["dc.date.issued","2014"],["dc.description.abstract","Previously, we introduced a series of anion-binding interpenetrated double-cages based on phenothiazine and its mono- and di-S-oxygenated derivatives. Here, we complete the structural comparison of the three related assemblies by an X-ray single crystal analysis of the sulfone derivative. We further show that the three palladium cages coexist in solution upon post-assembly mixing due to the very slow ligand exchange whereas treatment of binary mixtures of the corresponding ligands with Pd(II) leads to the formation of mixed cages comprising a statistical ligand distribution. In contrast, mixtures of one of these ligands with a shorter ligand derivative lead to narcissistic self-assembly into a double-cage and a coexisting small monomeric cage, regardless of the order of mixing and Pd(II) addition."],["dc.identifier.doi","10.1039/c3dt53243g"],["dc.identifier.fs","605010"],["dc.identifier.isi","000332389700045"],["dc.identifier.pmid","24519242"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/10557"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/34883"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9234"],["dc.relation.issn","1477-9226"],["dc.rights.access","openAccess"],["dc.title","Narcissistic self-sorting vs. statistic ligand shuffling within a series of phenothiazine-based coordination cages"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","8476"],["dc.bibliographiccitation.issue","23"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","8479"],["dc.bibliographiccitation.volume","135"],["dc.contributor.author","Freye, Sabrina"],["dc.contributor.author","Michel, Reent"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Pawliczek, Martin"],["dc.contributor.author","Frauendorf, Holm"],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T09:23:41Z"],["dc.date.available","2018-11-07T09:23:41Z"],["dc.date.issued","2013"],["dc.description.abstract","We have previously shown that the self-assembly of dibenzosuberone-based bis-monodentate pyridyl ligands L-1 with Pd-11 cations leads to the quantitative formation of interpenetrated coordination cages [BF4@Pd4L81]. The BF4- anion inside the central cavity serves as a template, causing the outer two pockets to show a tremendous affinity for allosteric binding of two small chloride anions. Here we show that derivatization of the ligand backbone with a bulky aryl substituent allows us to control the dimerization and hence the guest binding ability of the cage by the choice of the templating anion. Steric constraints imposed by L-2 prevent the large BF4- anion from serving as a template for the formation of interpenetrated double cages. Instead, a single isomer of the monomeric cage [Pd2L42] is formed. Addition of the small anionic template Cl- permits dimerization, yielding the interpenetrated double cage [Cl@Pd4L82], whose enlarged outer pockets show a preference for the binding of large anions such as ReO4-."],["dc.description.sponsorship","DFG [CL 489/2-1]; Fonds der Chemischen Industrie"],["dc.identifier.doi","10.1021/ja403184a"],["dc.identifier.isi","000320483900012"],["dc.identifier.pmid","23697828"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/29638"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0002-7863"],["dc.title","Template Control over Dimerization and Guest Selectivity of Interpenetrated Coordination Cages"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]