Now showing 1 - 3 of 3
  • 2013Journal Article
    [["dc.bibliographiccitation.firstpage","15906"],["dc.bibliographiccitation.issue","45"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","15910"],["dc.bibliographiccitation.volume","42"],["dc.contributor.author","Frank, Marina"],["dc.contributor.author","Dieterich, Johannes M."],["dc.contributor.author","Freye, Sabrina"],["dc.contributor.author","Mata, Ricardo A."],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T09:29:31Z"],["dc.date.accessioned","2020-05-12T12:28:31Z"],["dc.date.available","2018-11-07T09:29:31Z"],["dc.date.available","2020-05-12T12:28:31Z"],["dc.date.issued","2013"],["dc.description.abstract","Previously, we have reported on the quantitative self-assembly of a series of interpenetrated double-cages [Pd(4)Ligand(8)] with ligands based on various organic backbones. For dibenzosuber-one-based cages it was shown that anion binding in the outer two pockets follows an allosteric mechanism. Herein we wish to report the anion binding capabilities of three related phenothiazine cages. We present a systematic comparison of the relative halide (Cl- and Br-) binding affinities and the structural rearrangements of four double-cages based on NMR titrations, NOESY experiments and electronic structure calculations."],["dc.description.sponsorship","Evonik Foundation; DFG [CL 489/2-1]; FCI"],["dc.identifier.doi","10.1039/c3dt51709h"],["dc.identifier.isi","000326782600016"],["dc.identifier.pmid","23942941"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/10791"],["dc.identifier.scopus","2-s2.0-84886819111"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/65219"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/31053"],["dc.identifier.url","http://www.scopus.com/inward/record.url?eid=2-s2.0-84886819111&partnerID=MN8TOARS"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.relation.eissn","1477-9234"],["dc.relation.issn","1477-9226"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Relative anion binding affinity in a series of interpenetrated coordination cages"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]
    Details DOI PMID PMC WOS
  • 2014Journal Article
    [["dc.bibliographiccitation.firstpage","21930"],["dc.bibliographiccitation.issue","40"],["dc.bibliographiccitation.journal","Physical Chemistry Chemical Physics"],["dc.bibliographiccitation.lastpage","21935"],["dc.bibliographiccitation.volume","16"],["dc.contributor.author","Frank, Marina"],["dc.contributor.author","Funke, Sebastian"],["dc.contributor.author","Wackerbarth, Hainer"],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T09:33:23Z"],["dc.date.available","2018-11-07T09:33:23Z"],["dc.date.issued","2014"],["dc.description.abstract","A series of self-assembled coordination cages [pd(4)L(8)(n)] based on a phenothiazine backbone has been investigated by means of Raman spectroscopy in solution and by Surface Enhanced Raman Scattering (SERS) on a nanostructured Au surface. The experiments demonstrate that the cages can be clearly distinguished from their constituting ligands by their Raman spectroscopic signatures. Furthermore, the structural integrity of the interpenetrated coordination cages upon deposition on the Au surface was demonstrated for the first time. The signal assignment of the experimental vibrational spectra was supported by Density Functional Theory (DFT) calculations on suitable molecular models."],["dc.description.sponsorship","Evonik Foundation; DFG [CL 489/2-1]; Fonds der Chemischen Industrie"],["dc.identifier.doi","10.1039/c4cp02188f"],["dc.identifier.isi","000343072800002"],["dc.identifier.pmid","25204834"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/11430"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/31953"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1463-9084"],["dc.relation.issn","1463-9076"],["dc.rights.access","openAccess"],["dc.title","SERS spectroscopic evidence for the integrity of surface-deposited self-assembled coordination cages"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]
    Details DOI PMID PMC WOS
  • 2014Journal Article
    [["dc.bibliographiccitation.firstpage","4587"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","4592"],["dc.bibliographiccitation.volume","43"],["dc.contributor.author","Frank, Marina"],["dc.contributor.author","Krause, Lennard"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Clever, Guido H."],["dc.date.accessioned","2018-11-07T09:46:30Z"],["dc.date.available","2018-11-07T09:46:30Z"],["dc.date.issued","2014"],["dc.description.abstract","Previously, we introduced a series of anion-binding interpenetrated double-cages based on phenothiazine and its mono- and di-S-oxygenated derivatives. Here, we complete the structural comparison of the three related assemblies by an X-ray single crystal analysis of the sulfone derivative. We further show that the three palladium cages coexist in solution upon post-assembly mixing due to the very slow ligand exchange whereas treatment of binary mixtures of the corresponding ligands with Pd(II) leads to the formation of mixed cages comprising a statistical ligand distribution. In contrast, mixtures of one of these ligands with a shorter ligand derivative lead to narcissistic self-assembly into a double-cage and a coexisting small monomeric cage, regardless of the order of mixing and Pd(II) addition."],["dc.identifier.doi","10.1039/c3dt53243g"],["dc.identifier.fs","605010"],["dc.identifier.isi","000332389700045"],["dc.identifier.pmid","24519242"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/10557"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/34883"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9234"],["dc.relation.issn","1477-9226"],["dc.rights.access","openAccess"],["dc.title","Narcissistic self-sorting vs. statistic ligand shuffling within a series of phenothiazine-based coordination cages"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]
    Details DOI PMID PMC WOS