Ghadwal, Rajendra Singh

[["dc.bibliographiccitation.firstpage","4561"],["dc.bibliographiccitation.issue","38"],["dc.bibliographiccitation.journal","Chemical Communications"],["dc.bibliographiccitation.lastpage","4563"],["dc.bibliographiccitation.volume","48"],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Wolf, Hilke"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:15:25Z"],["dc.date.available","2018-11-07T09:15:25Z"],["dc.date.issued","2012"],["dc.description.abstract","The first base stabilized monoalkylsilylenes LSitBu (2) and LSi[C(SiMe3)(3)] (3) (L = PhC(NtBu)(2)) were synthesized by the facile metathesis reactions of LitBu and KC(SiMe3)(3) with LSiCl (1). The reaction of LSitBu (2) with N2O afforded the dimer [LSitBu(mu-O)](2) (4) which contains a four-membered Si2O2 ring."],["dc.identifier.doi","10.1039/c2cc31041d"],["dc.identifier.isi","000302743000010"],["dc.identifier.pmid","22460291"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/27682"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1359-7345"],["dc.title","A debut for base stabilized monoalkylsilylenes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","528"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Chemistry - An Asian Journal"],["dc.bibliographiccitation.lastpage","533"],["dc.bibliographiccitation.volume","7"],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Hey, Jakob"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:12:24Z"],["dc.date.available","2018-11-07T09:12:24Z"],["dc.date.issued","2012"],["dc.description.abstract","Three transition-metalcarbonyl complexes [V(L)(CO)3(Cp)] (1), [Co(L)(CO)(Cp)] (2), and [Co(L2)(CO)3]+[CoCO)4]- (3), each containing stable N-heterocyclic-chlorosilylene ligands (L; L=PhC(NtBu)2SiCl) were synthesized from [V(CO)4(Cp)], [Co(CO)2(Cp)], and Co2(CO)8, respectively. Complexes 13 were characterized by NMR and IR spectroscopy, EI-MS spectrometry, and elemental analysis. The molecular structures of compounds 13 were determined by single-crystal X-ray diffraction."],["dc.identifier.doi","10.1002/asia.201100722"],["dc.identifier.isi","000300871500011"],["dc.identifier.pmid","22246607"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/26940"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1861-4728"],["dc.title","Facile Access to Transition-Metal-Carbonyl Complexes with an Amidinate-Stabilized Chlorosilylene Ligand"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","444"],["dc.bibliographiccitation.issue","2"],["dc.bibliographiccitation.journal","Accounts of Chemical Research"],["dc.bibliographiccitation.lastpage","456"],["dc.bibliographiccitation.volume","46"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2018-11-07T09:28:05Z"],["dc.date.available","2018-11-07T09:28:05Z"],["dc.date.issued","2013"],["dc.description.abstract","Isolating stable compounds with low-valent main group elements have long been an attractive research topic, because several of these compounds can mimic transition metals in activating small molecules. In addition, compounds with heavier low-valent main group elements have fundamentally different electronic properties when compared with their lighter congeners. Among group 14 elements, the heavier analogues of carbenes (R2C:) such as silylenes (R2Si:), germylenes (R2Ge:), stannylenes (R2Sn:), and plumbylenes (R2Pb:) are the most studied species with low-valent elements. The first stable carbene and silylene species were isolated as N-heterocycles. Among the dichlorides of group 14 elements, CCl2 and SiCl2 are highly reactive intermediates and play an important role in many chemical transformations. GeCl2 can be stabilized as a dioxane adduct, whereas SnCl2/ and PbCl2 are available as stable compounds. In the Siemens process, which produces electronic grade silicon by thermal decomposition of HSiCl3 at 1150 degrees C, chemists proposed dichlorosilylene (SiCl2) as an intermediate, which further dissociates to Si and SiCl4. Similarly, base induced disproportionation of HSiCl3 or Si2Cl6 to SiCl2 is a known reaction. Trapping these products in situ with organic substrates suggested the mechanism for this reaction. In addition, West and co-workers reported a polymeric trans-chain like perchloropolysilane (SiCl2)(n). However, the isolation of a stable free monomeric dichlorosilylene remained a challenge. The first successful attempt of taming SiCl2 was the isolation of monochlorosilylene PhC(NtBu)(2)SiCl supported by an amidinate ligand in 2006. In 2009, we succeeded in isolating N-heterocyclic carbene (NHC) stabilized dichlorosilylene (NHC)SiCl2 with a three coordinate silicon atom. (The NHC is 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene (IPr) or 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (IMes).) Notably, this method allows for the almost quantitative synthesis of (NHC)SiCl2 without using any hazardous reducing agents. Dehydrochlorination of HSiCl(3) with NHC under mild reaction conditions produces (NHC)SiCl2. We can separate the insoluble side product (NHC)HCl readily and recycle it to form NHC. The high yield and facile access to dichlorosilylene allow us to explore its chemistry to a greater extent. In this Account, we describe the results using (NHC)SiCl2 primarily from our laboratory, including findings by other researchers. We emphasize the novel silicon compounds, which supposedly existed only as short-lived species. We also discuss silaoxirane, silaimine with tricoordinate silicon atom, silaisonitrile, and silaformyl chloride. In analogy with N-heterocyclic silylenes (NHSis), oxidative addition reactions of organic substrates with (NHC)SiCl2 produce Si(IV) compounds. The presence of the chloro-substituents both on (NHC)SiCl2 and its products allows metathesis reactions to produce novel silicon compounds with new functionality. These substituents also offer the possibility to synthesize interesting compounds with low-valent silicon by further reduction. Coordination of NHC to the silicon increases the acidity of the backbone protons on the imidazole ring, and therefore (NHC)SiCl2 can functionalize NHC at the C-4 or C-5 position."],["dc.description.sponsorship","DFG; Alexander von Humboldt Foundation, Germany"],["dc.identifier.doi","10.1021/ar300196u"],["dc.identifier.isi","000315478700024"],["dc.identifier.pmid","23181482"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/30689"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","1520-4898"],["dc.relation.issn","0001-4842"],["dc.title","Dichlorosilylene: A High Temperature Transient Species to an Indispensable Building Block"],["dc.type","review"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","17552"],["dc.bibliographiccitation.issue","44"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","17555"],["dc.bibliographiccitation.volume","133"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Proepper, Kevin"],["dc.contributor.author","Dittrich, Birger"],["dc.contributor.author","Klein, Susanne"],["dc.contributor.author","Frenking, Gernot"],["dc.date.accessioned","2018-11-07T08:49:55Z"],["dc.date.available","2018-11-07T08:49:55Z"],["dc.date.issued","2011"],["dc.description.abstract","A stable silicon analogue of an acid anhydride {PhC((BuN)-N-t)(2)}Si{=O center dot B(C6F5)(3)}O-Si(H){=O center dot B(C6F5)(3)}{(NBut)(HNBut)CPh} (4) with a O=Si-O-Si=O core has been prepared by treating monochlorosilylene PhC((BuN)-N-t)(2)SiCl (1) with H2O center dot B(C6F5)(3) in the presence of NHC (NHC = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene). Compound 4 has been characterized by elemental analysis and multinuclear NMR spectroscopic investigations. The molecular structure of 4 has been established by single-crystal X-ray diffraction studies, and DFT calculations support the experimental results."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft; AvHS"],["dc.identifier.doi","10.1021/ja206702e"],["dc.identifier.isi","000296312200009"],["dc.identifier.pmid","21999232"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/21570"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0002-7863"],["dc.title","Donor-Acceptor-Stabilized Silicon Analogue of an Acid Anhydride"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","11049"],["dc.bibliographiccitation.issue","20"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","11054"],["dc.bibliographiccitation.volume","51"],["dc.contributor.author","Samuel, Prinson P."],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Sen, Sakya S."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Granitzka, Markus"],["dc.contributor.author","Matussek, Julia"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:04:36Z"],["dc.date.available","2018-11-07T09:04:36Z"],["dc.date.issued","2012"],["dc.description.abstract","The reactions of silylenes with organic azides are quite diverse, depending on the substituents of the silylene center and on the nature of the azide employed. Elusive silaimine with three-coordinate silicon atom (LSiN)-Si-1(2,6-Triip(2)-C6H3) (5) {L-1 = CH[(C=CH2)(CMe)(2,6-iPr(2)C(6)H(3)N)(2)] and Triip = 2,4,6-triisopropylphenyl) was synthesized by treatment of the silylene (LSi)-Si-1 (1) with a sterically demanding 2,6-bis(2,4,6-triisopropylphenyl)phenyl azide (2,6-Triip(2)C(6)H(3)N(3)). The reaction of Lewis base-stabilized dichlorosilylene (LSiCl2)-Si-2 (2) {L-2 = 1,3-bis(2,6-iPr(2)C(6)H(3))imidazol-2-ylidene} with Ph3SiN3 afforded four-coordinate silaimine L-2(Cl-2)SiNSiPh3 (6). Treatment of 2,6-Triip(2)C(6)H(3)N(3) with (LSiCl)-Si-3 (3) (L-3 = PhC(NtBu)(2)) yielded silaimine L-3(Cl)SiN(2,6-Triip(2)-C6H3) (7) possessing a four-coordinate silicon atom, The reactions of (LSiN)-Si-3(SiMe3)(2) (4) with adamantyl and trimethylsilyl azide furnished silaimine compounds with a four-coordinate silicon atom L-3(N(Ad)SiMe3)SiN(SiMe3) (8) (Ad = adamantyl) and L-3(N(SiMe3)(2))SiN(SiMe3) (9). Compound 8 was formed by migration of one of the SiMe3 groups. Compounds 5-9 are stable under inert atmosphere and were characterized by elemental analysis, NMR spectroscopy, and single-crystal X-ray studies."],["dc.identifier.doi","10.1021/ic301543y"],["dc.identifier.isi","000309739100060"],["dc.identifier.pmid","23036040"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/25142"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.title","Stable Silaimines with Three- and Four-Coordinate Silicon Atoms"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","3715"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","Chemistry: a European Journal"],["dc.bibliographiccitation.lastpage","3720"],["dc.bibliographiccitation.volume","19"],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Ghadwal, Rajendra Singh"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Mata, Ricardo A."],["dc.contributor.author","Wolf, Hilke"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:27:35Z"],["dc.date.accessioned","2020-05-12T12:35:20Z"],["dc.date.available","2018-11-07T09:27:35Z"],["dc.date.available","2020-05-12T12:35:20Z"],["dc.date.issued","2013"],["dc.description.abstract","Three- and five-membered rings that bear the (Si-C-S) and (Si-C-C-C-S) unit have been synthesized by the reactions of LSiCl (1; L=PhC(NtBu)2) and LSi (2; L=CH{(CCH2)(CMe)(2,6-iPr2C6H3N)2}) with the thioketone 4,4-bis(dimethylamino)thiobenzophenone. Treatment of 4,4-bis(dimethylamino)thiobenzophenone with LSiCl at room temperature furnished the [1+2]-cycloaddition product silathiacyclopropane 3. However, reaction of 4,4-bis(dimethylamino)thiobenzophenone with LSi at low temperature afforded a [1+4]-cycloaddition to yield the five-membered ring product 4. Compounds 3 and 4 were characterized by NMR spectroscopy, EIMS, and elemental analysis. The molecular structures of 3 and 4 were unambiguously established by single-crystal X-ray structural analysis. The room-temperature reaction of 4,4-bis(dimethylamino)thiobenzophenone with LSi resulted in products 4 and 5, in which 4 is the dearomatized product and 5 is formed under the 1,3-migration of a hydrogen atom from the aromatic phenyl ring to the carbon atom of the CS unit. Furthermore, the optimized structures of probable products were investigated by using DFT calculations."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft; DNRF; Alexander von Humboldt Stiftung"],["dc.identifier.doi","10.1002/chem.201203242"],["dc.identifier.isi","000315596400026"],["dc.identifier.pmid","23361862"],["dc.identifier.scopus","2-s2.0-84874605392"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/30573"],["dc.identifier.url","http://www.scopus.com/inward/record.url?eid=2-s2.0-84874605392&partnerID=MN8TOARS"],["dc.language.iso","en"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.relation.issn","0947-6539"],["dc.title","Reaction of N-Heterocyclic Silylenes with Thioketone: Formation of SiliconSulfur Three (Si-C-S)- and Five (Si-C-C-C-S)-Membered Ring Systems"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","5506"],["dc.bibliographiccitation.issue","15"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","5510"],["dc.bibliographiccitation.volume","31"],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Granitzka, Markus"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:07:13Z"],["dc.date.available","2018-11-07T09:07:13Z"],["dc.date.issued","2012"],["dc.description.abstract","The reaction of the stable N-heterocyclic silylene [CH{(C= CH2)(CMe)(2,6-iPr(2)C(6)H(3)N)(2)}Si] (1) with triphenylsilanol and pentafluorphenol in a 1:2 molar ratio resulted in quantitative yields of the pentacoordinate silicon-containing compounds [CH{(CMe)(2)(2,6-iPr(2)C(6)H(3)N)(2)}Si(H){OSiPh3}(2)] (2) and [CH{(CMe)(2)(2,6-iPr(2)C(6)H(3)N)(2)}Si-(H){OC6F5}(2)] (3), respectively. Compounds 2 and 3 were formed by O H bond activation of triphenylsilanol and pentafluorophenol. They were characterized by elemental analysis, NMR spectroscopy, and E1-MS spectrometry. In their solid-state structures the silicon atom is tetracoordinate in 2, whereas it is pentacoordinate in 3."],["dc.identifier.doi","10.1021/om300476q"],["dc.identifier.isi","000307422200032"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/25743"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0276-7333"],["dc.title","Reactivity Studies of a Stable N-Heterocyclic Silylene with Triphenylsilanol and Pentafluorophenol"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4588"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","4592"],["dc.bibliographiccitation.volume","31"],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Wolf, Hilke"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:09:11Z"],["dc.date.available","2018-11-07T09:09:11Z"],["dc.date.issued","2012"],["dc.description.abstract","Reactions of silylenes with organic substrates generally lead to silicon(IV) compounds. Ligand substitution at the silicon(II) atom of silylene, without changing the formal +2 oxidation state, is very rare. We report herein a straightforward route to functionalized silylenes LSiX (L = PhC(NtBu)(2) and X = PPh2 (1), NPh2 (2), NCy2(3), NiPr2 (4), NMe2 (5), N(SiMe3)(2) (6), OtBu (7)). Silylenes 1-7 have been prepared in quantitative yield by a modified ligand exchange reaction of PhC(NtBu)(2)SiCl (LSiCl) with the corresponding lithium or potassium salts. Compounds 1-7 were characterized by spectroscopic and spectrometric techniques. Single-crystal X-ray structures of 1, 3, and 4 were determined."],["dc.identifier.doi","10.1021/om3003762"],["dc.identifier.isi","000305588000026"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/26198"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0276-7333"],["dc.title","Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)(2)SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)(2), OtBu)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","11970"],["dc.bibliographiccitation.issue","43"],["dc.bibliographiccitation.journal","Chemistry - A European Journal"],["dc.bibliographiccitation.lastpage","11973"],["dc.bibliographiccitation.volume","17"],["dc.contributor.author","Percival, Paul W."],["dc.contributor.author","Brodovitch, Jean-Claude"],["dc.contributor.author","Mozafari, M. R."],["dc.contributor.author","Mitra, Amitabha"],["dc.contributor.author","West, Robert"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2018-11-07T08:50:52Z"],["dc.date.available","2018-11-07T08:50:52Z"],["dc.date.issued","2011"],["dc.identifier.doi","10.1002/chem.201102405"],["dc.identifier.isi","000297316100002"],["dc.identifier.pmid","21905145"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/21794"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-blackwell"],["dc.relation.issn","0947-6539"],["dc.title","Free Radical Reactivity of Mono- and Dichlorosilylene with Muonium"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","8186"],["dc.bibliographiccitation.issue","66"],["dc.bibliographiccitation.journal","Chemical Communications"],["dc.bibliographiccitation.lastpage","8188"],["dc.bibliographiccitation.volume","48"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Proepper, Kevin"],["dc.contributor.author","Dittrich, Birger"],["dc.contributor.author","Goedecke, Catharina"],["dc.contributor.author","Frenking, Gernot"],["dc.date.accessioned","2018-11-07T09:15:10Z"],["dc.date.available","2018-11-07T09:15:10Z"],["dc.date.issued","2012"],["dc.description.abstract","Formyl chloride (H(Cl)C=O) is unstable at room temperature and decomposes to HCl and CO. Silicon analogue of formyl chloride, silaformyl chloride IPr center dot SiH(Cl)=O center dot B(C6F5)(3) (3) (IPr = 1,3-bis(2,6-diisopropyl-phenyl)imidazol-2-ylidene), was stabilized by Lewis donor-acceptor ligands. Compound 3 is not only the first stable acyclic silacarbonyl compound but also the first silacarbonyl halide reported so far."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft; AvH foundation"],["dc.identifier.doi","10.1039/c2cc32887a"],["dc.identifier.isi","000306656800005"],["dc.identifier.pmid","22786582"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/27611"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1359-7345"],["dc.title","Donor-acceptor stabilized silaformyl chloride"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]