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Ghadwal, Rajendra Singh
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Ghadwal, Rajendra Singh
Official Name
Ghadwal, Rajendra Singh
Alternative Name
Ghadwal, Rajendra S.
Ghadwal, R. S.
Ghadwal, Rajendra
Ghadwal, R.
Now showing 1 - 10 of 12
2017Journal Article [["dc.bibliographiccitation.firstpage","262"],["dc.bibliographiccitation.issue","9"],["dc.bibliographiccitation.journal","Catalysts"],["dc.bibliographiccitation.volume","7"],["dc.contributor.author","Ho, Nga Kim T."],["dc.contributor.author","Reichmann, Sven O."],["dc.contributor.author","Rottschäfer, Dennis"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.date.accessioned","2020-12-10T18:46:58Z"],["dc.date.available","2020-12-10T18:46:58Z"],["dc.date.issued","2017"],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft"],["dc.identifier.doi","10.3390/catal7090262"],["dc.identifier.eissn","2073-4344"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/17014"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/78599"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.notes.intern","Merged from goescholar"],["dc.publisher","MDPI"],["dc.relation.eissn","2073-4344"],["dc.rights","CC BY 4.0"],["dc.rights.uri","https://creativecommons.org/licenses/by/4.0"],["dc.title","Expanding the Scope of Cu(I) Catalyzed “Click Chemistry” with Abnormal NHCs: Three-Fold Click to Tris-Triazoles"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]Details DOI2015Journal Article [["dc.bibliographiccitation.firstpage","14359"],["dc.bibliographiccitation.issue","32"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","14367"],["dc.bibliographiccitation.volume","44"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Schuermann, Christian J."],["dc.contributor.author","Andrada, Diego M."],["dc.contributor.author","Frenking, Gernot"],["dc.date.accessioned","2018-11-07T10:03:05Z"],["dc.date.available","2018-11-07T10:03:05Z"],["dc.date.issued","2015"],["dc.description.abstract","Bronsted acid HNTf2 (Tf = SO2CF3) mediated dehydrogenative hydride abstraction from (L-1)BH3 (3) and (L-2)BH3 (4) (L-1 = IPrCH2 = 1,3-(2,6-di-isopropylphenyl) imidazol-2-methylidene (1); L-2 = SIPrCH2 = 1,3-(2,6-di-isopropylphenyl)imidazolidin-2-methylidiene (2)) affords thermally stable hydride bridged monocationic hydrido boron compounds [{(L-1)BH2}(2)(mu-H)](NTf2) (5) and [{(L-2)BH2}(2)(mu-H)](NTf2) (6). Furthermore, hydride abstraction yields di-cationic hydrido boron compounds [{(L-1) BH}(2)(mu-H)(2)](NTf2)(2) (7) and [{(L-2)-BH} 2(mu-H)(2)](NTf2)(2) (8). Unique cationic boron compounds with CH2BH2(mu-H)BH2CH2 (5 and 6) and CH2BH(mu-H)(2)BHCH2 (7 and 8) moieties feature a 3c-2e bond and have been fully characterized. Interesting electronic and structural features of compounds 5-8 are analysed using spectroscopic, crystallographic, and computational methods."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft (DFG) [GH 129/4-1]"],["dc.identifier.doi","10.1039/c5dt02237a"],["dc.identifier.isi","000359088200024"],["dc.identifier.pmid","26200103"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/12606"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/38371"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9234"],["dc.relation.issn","1477-9226"],["dc.rights.access","openAccess"],["dc.title","Mono- and di-cationic hydrido boron compounds"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]Details DOI PMID PMC WOS2011Journal Article [["dc.bibliographiccitation.firstpage","3853"],["dc.bibliographiccitation.issue","14"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","3858"],["dc.bibliographiccitation.volume","30"],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Hey, Jakob"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T08:54:12Z"],["dc.date.available","2018-11-07T08:54:12Z"],["dc.date.issued","2011"],["dc.description.abstract","The reactions of L [PhC(NtBu)(2)SiCl] and L' [CH{(C=CH2)(CMe)(2,6-iPr(2)C(6)H(3)N)(2)}Si] with monoketones and quinone have been examined. The reaction of L with 2-adamantanone furnishes a [1 + 2]-cycloaddition product 1, whereas with 3,5-di-tert-butyl-o-benzoquinone leads to the [1 + 4]-ycloaddition product 2. The treatment of L' with 3,5-di-tert-butyl-o-benzoquinone gives [1 + 4]-cycloaddition product 3, and the reaction with acylferrocene yields compound 4. Compounds 1-4 were characterized by single crystal X-ray structural analysis, NMR spectroscopy, EI-MS spectrometry, and elemental analysis."],["dc.identifier.doi","10.1021/om200388a"],["dc.identifier.isi","000292847900020"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/8950"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/22618"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0276-7333"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Reactions of Stable N-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]Details DOI WOS2011Journal Article [["dc.bibliographiccitation.firstpage","8502"],["dc.bibliographiccitation.issue","17"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","8508"],["dc.bibliographiccitation.volume","50"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Proepper, Kevin"],["dc.contributor.author","Holstein, Julian Jacob"],["dc.contributor.author","Dittrich, Birger"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2018-11-07T08:51:49Z"],["dc.date.available","2018-11-07T08:51:49Z"],["dc.date.issued","2011"],["dc.description.abstract","Reactions of N-heterocyclic carbene stabilized dichlorosilylene IPr center dot SiCl2 (1) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with (eta(5)-C5H5)V(CO)(4), (eta(5)-C5H5)Co(CO)(2), and Fe-2(CO)(9) afford dichlorosilylene complexes IPr center dot SiCl2 center dot V(CO)(3)(eta(5)-C5H5) (2), IPr center dot SiCl2 center dot Co(CO)-(eta(5)-C5H5) (3), and IPr center dot SiCl2 center dot Fe(CO)(4) (4), respectively. Complexes 2-4 are stable under an inert atmosphere, are soluble in common organic solvents, and have been characterized by elemental analysis and multinudear (H-1, C-13, and Si-29) NMR spectroscopy. Molecular structures of 2-4 have been determined by single crystal X-ray crystallographic studies and refined with nonspherical scattering factors."],["dc.identifier.doi","10.1021/ic201096c"],["dc.identifier.isi","000294242700074"],["dc.identifier.pmid","21780764"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/9434"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/22025"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","N-Heterocyclic Carbene Stabilized Dichlorosilylene Transition-Metal Complexes of V(I), Co(I), and Fe(0)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]Details DOI PMID PMC WOS2011Journal Article [["dc.bibliographiccitation.firstpage","1030"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","1033"],["dc.bibliographiccitation.volume","30"],["dc.contributor.author","Sen, Sakya S."],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Kratzert, Daniel"],["dc.contributor.author","Stern, Daniel"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T08:58:09Z"],["dc.date.available","2018-11-07T08:58:09Z"],["dc.date.issued","2011"],["dc.description.abstract","LGeCl (L = PhC(NtBu)(2)) was treated with elemental sulfur in THF to afford [{PhC(NtBu)(2)}(2)Ge-2(mu-S)(2)Cl-2] (2) in 44% yield instead of yielding a compound containing a Ge=S double bond. It was revealed by the X-ray single-crystal structure that there is no Ge=S unit in 2. Instead, 2 features a four-membered ring containing two germanium and two sulfur atoms. The four-membered Ge2S2 ring is planar and is formed by a weak [2 + 2] cycloaddition interaction. Within the ring skeleton the two germanium atoms are arranged opposite to each other. Furthermore, 2 was reduced with 2 equiv of potassium graphite in THF to yield a potassium salt of a germathiocarboxylate analogue of composition [{PhC(NtBu)(2)}Ge(S)SK(THF)](2) (3). Compounds 2 and 3 were characterized by single-crystal X-ray diffraction studies, NMR spectroscopy, EI-MS spectrometry, and elemental analysis."],["dc.identifier.doi","10.1021/om101074j"],["dc.identifier.isi","000287955800014"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/8946"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/23577"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0276-7333"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Synthesis and Structure of [{PhC(NtBu)(2)}(2)Ge-2(mu-S)(2)Cl-2] and a Germanium Dithiocarboxylate Analogue"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]Details DOI WOS2013Journal Article [["dc.bibliographiccitation.firstpage","9440"],["dc.bibliographiccitation.issue","82"],["dc.bibliographiccitation.journal","Chemical Communications"],["dc.bibliographiccitation.lastpage","9442"],["dc.bibliographiccitation.volume","49"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Reichmann, Sven O."],["dc.contributor.author","Engelhardt, Felix"],["dc.contributor.author","Andrada, Diego M."],["dc.contributor.author","Frenking, Gernot"],["dc.date.accessioned","2018-11-07T09:29:33Z"],["dc.date.available","2018-11-07T09:29:33Z"],["dc.date.issued","2013"],["dc.description.abstract","N-heterocyclic olefins (NHOs), IPrCH2(1) and SIPrCH2 (2) (IPrCH2 = {N(2,6-iPr(2)C(6)H(3))CH}(2)CCH2 and SIPrCH2 = {N(2,6-iPr(2)C(6)H(3))CH2}(2)CCH2), react with HSiCl3 and afford IPrCH(SiHCl2)(3) and SIPrCH(SiHCl2) (4), respectively. Compounds 3 and 4 have been isolated in almost quantitative yield. Interestingly, treatment of the silylene IPr center dot SiCl2 with 1 also affords 3, where silylene insertion into a C-H bond is observed. Computational analysis shows a high energy barrier for silylene insertion, therefore a protonation-deprotonation mechanism is more likely."],["dc.identifier.doi","10.1039/c3cc45652h"],["dc.identifier.isi","000324758000021"],["dc.identifier.pmid","24005446"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/10195"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/31063"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1364-548X"],["dc.relation.issn","1359-7345"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Facile access to silyl-functionalized N-heterocyclic olefins with HSiCl3"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]Details DOI PMID PMC WOS2012Journal Article [["dc.bibliographiccitation.firstpage","9601"],["dc.bibliographiccitation.issue","32"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","9603"],["dc.bibliographiccitation.volume","41"],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Holstein, Julian Jacob"],["dc.contributor.author","Dittrich, Birger"],["dc.date.accessioned","2018-11-07T09:15:07Z"],["dc.date.available","2018-11-07T09:15:07Z"],["dc.date.issued","2012"],["dc.description.abstract","The three-membered silacyclic ring compounds LSi[N-2(Ph)(2)]-tBu (1), LSi[HCN(Ph)(2)]tBu (2) and LSi[C-2(Ph)(2)]tBu (3) were obtained by the treatment of base stabilized monoalkylsilylenes LSitBu (L = PhC(NtBu)(2)) with PhN=NPh, PhN=CHPh and PhC CPh. The reaction of PhN=NPh and PhC CPh with LSitBu shows a different reactivity pattern with base stabilized monochlorosilylene LSiCl. The arrangement of the three-membered ring (SiNN) in 1 is the first structurally isolated example of a siladiaziridine compound."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft; Alexander von Humboldt Stiftung"],["dc.identifier.doi","10.1039/c2dt31326j"],["dc.identifier.isi","000306749100006"],["dc.identifier.pmid","22785327"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/10214"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/27598"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9226"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","An access to base-stabilized three-membered silicon heterocycles"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]Details DOI PMID PMC WOS2013Journal Article [["dc.bibliographiccitation.firstpage","5987"],["dc.bibliographiccitation.issue","53"],["dc.bibliographiccitation.journal","Chemical Communications"],["dc.bibliographiccitation.lastpage","5989"],["dc.bibliographiccitation.volume","49"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Proepper, Kevin"],["dc.contributor.author","Dittrich, Birger"],["dc.contributor.author","John, Michael"],["dc.date.accessioned","2018-11-07T09:29:55Z"],["dc.date.available","2018-11-07T09:29:55Z"],["dc.date.issued","2013"],["dc.description.abstract","Functionalization of N-heterocyclic carbenes (NHCs) has an important influence on their stability, Lewis donor, and acceptor properties. In this study, we report on the selective functionalization of a four-membered N-heterocyclic bis-silylene (2,6-Ar2C6H3NSi:)(2) (1) (Ar = 2,4,6-iPr(3)C(6)H(2)) with mono-oxygen sources N2O and Me3NO. Treatment of 1 with N2O results in the selective formation of mono-silylene (2,6-Ar2C6H3NSi(OH)(2))(2,6-Ar2C6H3NSi:) (2) as a major product, along with a small amount of further oxidized product (2,6-Ar2C6H3NSi(OH)(2))(2) (3). Compound 2 is the first four-membered mono-silylene with a di-coordinate silicon atom."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft"],["dc.identifier.doi","10.1039/c3cc43199a"],["dc.identifier.isi","000319987600025"],["dc.identifier.pmid","23715462"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/10198"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/31171"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1359-7345"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Selective functionalization of a bis-silylene"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]Details DOI PMID PMC WOS2011Journal Article [["dc.bibliographiccitation.firstpage","358"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","364"],["dc.bibliographiccitation.volume","50"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Proepper, Kevin"],["dc.contributor.author","Dittrich, Birger"],["dc.contributor.author","Jones, Peter G."],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2018-11-07T09:00:09Z"],["dc.date.available","2018-11-07T09:00:09Z"],["dc.date.issued","2011"],["dc.description.abstract","Pentacoordinate silicon fluorides (LSiF3)-Si-1 (2a), (LSiF3)-Si-2 (2b), and ((LSiF2)-Si-3)(2) (2c)(2) based on amidinate (L-1 = PhC((NBu)-Bu-t)(2)), guanidinate (L-2 = 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidinate), and triazapentadienate = (L-3 = NC(NMe2)NC-(NMe2)NAr, Ar = 2,6-(Pr2C6H3)-Pr-i) ligands were prepared by fluorination of the corresponding chlorosilanes (LSiCl3)-Si-1 (1a), (LSiCl3)-Si-2 (1b), and (LSiCl2)-Si-3 (1c) with Me3SnF at ambient temperature. Compounds 1b. 1c, 2a, 2b, and (2c)(2) were characterized by H-1, C-13, F-19, and Si-29 NMR spectroscopic studies. Molecular structures of 1b, 1c, 2a, and (2c)(2) were determined by single crystal X-ray structural analysis. Invariom refinement involving non-spherical scattering factors of the Hansen-Coppens multipole model was performed for 1b. Compound (LSiF2)-Si-3 (2c) is dimeric both in the solid state and in solution, whereas its chloro-analogue lc is monomeric. The attempted synthesis of diamidinatotetrachlorodisilane by reaction of lithium amidinate with Si2Cl6 led to the formation of the silane (1a) and the silylene (LSiCl)-Si-1 (3). Reaction of Si2Cl6 with N-heterocyclic carbenes (NHC) afforded NHC adducts of dichlorosilylene and SiCl4. A one pot method for the preparation of base-stabilized silylenes from Si2Cl6 is discussed."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft"],["dc.identifier.doi","10.1021/ic1020548"],["dc.identifier.isi","000285559800040"],["dc.identifier.pmid","21126009"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/9427"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/24081"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Neutral Pentacoordinate Silicon Fluorides Derived from Amidinate, Guanidinate, and Triazapentadienate Ligands and Base-Induced Disproportionation of Si2Cl6 to Stable Silylenes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]Details DOI PMID PMC WOS2012Journal Article [["dc.bibliographiccitation.firstpage","1529"],["dc.bibliographiccitation.issue","5"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","1533"],["dc.bibliographiccitation.volume","41"],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Ghadwal, Rajendra S."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Hey, Jakob"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T09:15:53Z"],["dc.date.available","2018-11-07T09:15:53Z"],["dc.date.issued","2012"],["dc.description.abstract","The reaction of N-heterocyclic silylene (NHSi) L [L = CH{(C=wCH(2))(CMe)(2,6-iPr(2)C(6)H(3)N)(2)}Si] with benzoylhydrazine, 1,2-dicarbethoxyhydrazine, 1,2-diacetylhydrazine and 1,2-bis(tert-butoxycarbonyl)-hydrazine in 1 : 1 molar ratio resulted in compounds 1-4 with an almost quantitative yield and five coordinate silicon atoms. Compounds 1-4 were formed by double N-H bond activation by deliberate selection of N,N'-bis-substituted hydrazine compounds bearing the -C(O)NHNH- unit. Compounds 1-4 were characterized by NMR spectroscopy, EI-MS and elemental analysis. The molecular structures of compounds 1-3 were unambiguously established by single crystal X-ray structural analysis."],["dc.identifier.doi","10.1039/c1dt11708d"],["dc.identifier.isi","000299054500017"],["dc.identifier.pmid","22159089"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/10271"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/27808"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9226"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.title","Double N-H bond activation of N,N '-bis-substituted hydrazines with stable N-heterocyclic silylene"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]Details DOI PMID PMC WOS