Five naphthalene glycosides from the roots of Rumex patientia

Three novel and two known naphthalene glycosides were isolated from the roots of Rumex patientia L. (Polygonaceae). The structures of the new compounds were established, respectively as 2-acetyl-3-methyl-6-carboxy-1,8-dihydroxynaphthalene-8-O-beta -D-glucopyranosyl 4,4 " -binaphthalene-8,8 " -O,O-di-beta -D-glucopyranoside and 2-acetyl-3-methyl-1,8-dihydroxynaphthalene-8-O-beta -D- glucopyranosyl (1-->3) beta -D-glucopyranoside on the basis of spectral analysis. The other napthalene glycosides were determined as nepodin-8-O-beta -D-glucopyranoside and torachrysone-8-O-beta -D-glucopyranoside by comparison of their spectral data with those previously reported. (C) 2001 Elsevier Science Ltd. All rights reserved.