Lanthanide alkoxides—III. Four-coordinate anionic neodymium(III) alkoxides and amides 1

Edelmann, Frank T.; Steiner, Alexander; Stalke, Dietmar; Gilje, John W.; Jagner, Susan; Håkanssons, Mikael

doi:10.1016/S0277-5387(00)84729-4

Lanthanide alkoxides—III. Four-coordinate anionic neodymium(III) alkoxides and amides 1

Date Issued

1994

Author(s)

Edelmann, Frank T.

Steiner, Alexander

Stalke, Dietmar

Gilje, John W.

Jagner, Susan

Håkanssons, Mikael

DOI

10.1016/S0277-5387(00)84729-4

Abstract

Tetracoordinate anionic neodymium(III) alkoxides and amides are obtained by adduct formation of Nd[OC(tBu)3]3 (1) and Nd[N(SiMe3)2]3 (2) with either LiCl or LiOSiMe3. The compounds (THF)3Li(μ-Cl)Nd[OC(tBu)3]3 (3), (THF)3Li(μ-Cl)Nd [N(SiMe3)2]3 (4) and [Li(THF)4][(Me3Si)2N3Nd(OSiMe3)] (5) have been characterized by single-crystal X-ray analyses.