Visualising the carboxylate shift at a bioinspired diiron(II) site in the solid state

ISSN
1364-548X
1359-7345
Date Issued
2011
Author(s)
Burger, Boris
DOI
10.1039/c1cc13756e
Abstract
A novel pyrazolate-based diiron(II) complex shows five different binding modes of exogenous carboxylate ligands in a single crystal structure. Temperature dependent X-ray data reveal thermally induced disorder due to carboxylate dynamics that resemble the carboxylate shift, as it is known from various diiron enzyme active sites.
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