Options
Cytenamide trifluoroacetic acid solvate
ISSN
1600-5368
Date Issued
2008
Author(s)
Johnston, Andrea
Florence, Alastair J.
Shankland, Kenneth
Bedford, Colin T.
Bardin, Julie
DOI
10.1107/S1600536808016577
Abstract
Cytenamide forms a 1:1 solvate with trifluoroacetic acid (systematic name: 5H-dibenzo[a, d] cycloheptatriene-5-carboxamide trifluoroacetic acid solvate), C(16)H(13)NO center dot C(2)HF(3)O(2). The compound crystallizes with one molecule of cytenamide and one of trifluoroacetic acid in the asymmetric unit; these are linked by O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonds to form an R(2)(2)(8) motif. The trifluoromethyl group of the solvent molecule displays rotational disorder over two sites, with site-occupancy factors of 0.964 (4) and 0.036 (4).
File(s)
No Thumbnail Available
Name
Johnsten_Florence_Fabbiani.pdf
Size
667.16 KB
Checksum (MD5)
ac381d8eb9f14e085fc3ee14f430bf9b