Water oxidation catalyzed by molecular di- and nonanuclear Fe complexes: importance of a proper ligand framework

ISSN
1477-9234
1477-9226
Date Issued
2016
Author(s)
Das, Biswanath
Lee, Bao-Lin
Karlsson, Erik A.
Akermark, Torbjorn
Shatskiy, Andrey
Liao, Rong-Zhen
Laine, Tanja M.
Haukka, Matti
Zeglio, Erica
Abdel-Magied, Ahmed F.
Siegbahn, Per E. M.
Karkas, Markus D.
Johnston, Eric V.
Nordlander, Ebbe
Akermark, Bjorn
DOI
10.1039/c6dt01554a
Abstract
The synthesis of two molecular iron complexes, a dinuclear iron(III,III) complex and a nonanuclear iron complex, based on the di-nucleating ligand 2,2'-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the one-electron oxidant [Ru(bpy)(3)](3+).
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