Local bonding structure in mechanically activated TiH2 and TiH2 plus graphite mixture

ISSN
0925-8388
Date Issued
2005
Author(s)
Kurmaev, Ernst Z.
Morozova, Olga S.
Khomenko, T. I.
Nemnonov, S. N.
Harada, Y.
Tokushima, T.
Osawa, H.
Takeuchi, T.
Shin, S.
DOI
10.1016/j.jallcom.2004.11.031
Abstract
The local bonding structure of mechanically activated TiH2 and TiH2/graphite mixture is studied by means of temperature-programmed desorption (TPD), X-ray emission- and absorption-spectroscopy. Ball milling of TiH2 in the presence of graphite results in a modification of the hydrogen occupation sites. Additional Ti-C bonds from chemical bonding of Ti with carbon, which occupies octahedral interstitials, appears in TiH2 due to intimate contact between graphite and TiH2 nanoparticles embedded into an amorphous graphite matrix. Mixed configurations around Ti atoms with proportional combination of local Ti-H and Ti-C bonds significantly decrease the thermal stability of TiH2. © 2004 Elsevier B.V. All rights reserved.