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New External Calibration Curves (ECCs) for the Estimation of Molecular Weights in Various Common NMR Solvents
ISSN
1521-3765
0947-6539
Date Issued
2016
Author(s)
DOI
10.1002/chem.201601145
Abstract
New external calibration curves (ECCs) for the estimation of aggregation states of small molecules in solution by DOSY NMR spectroscopy for a range of different common NMR solvents ([D-6]DMSO, C6D12, C6D6, CDCl3, and CD2Cl2) are introduced and applied. ECCs are of avail to estimate molecular weights (MWs) from diffusion coefficients of previously unknown aggregates. This enables a straightforward and elaborate examination of (de)aggregation phenomena in solution.