Chemical Non-Innocence of an aliphatic PNP Pincer Ligand

Date Issued
2016
Author(s)
Tromp, Moniek
DOI
10.1002/chem.201604407
Abstract
The synthesis of the divinylamido PNP nickel(II) complex [NiBr{N(CHCHPtBu2)2}] is reported. This compound exhibits reversible, ligand centered oxidation and protonation reactions. The resulting pincer chemical non-innocence can be utilized for benzylic C-H hydrogen atom abstraction. The thermochemistry and kinetics of hydrogen atom transfer were examined.
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