Now showing 1 - 6 of 6
  • 2022-11-28Journal Article
    [["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Crystals"],["dc.bibliographiccitation.volume","12"],["dc.contributor.affiliation","Ebrahimizadeh Abrishami, Majid; 1Institute of Materials Physics, University of Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen, Germany"],["dc.contributor.affiliation","Mohammadi, Mojtaba; 3Department of Physics, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran"],["dc.contributor.affiliation","Sotoudeh, Mohsen; 4Institute of Theoretical Chemistry, Ulm University, Albert-Einstein-Allee 11, 89081 Ulm, Germany"],["dc.contributor.author","Ebrahimizadeh Abrishami, Majid"],["dc.contributor.author","Mohammadi, Mojtaba"],["dc.contributor.author","Sotoudeh, Mohsen"],["dc.date.accessioned","2022-12-07T15:55:08Z"],["dc.date.available","2022-12-07T15:55:08Z"],["dc.date.issued","2022-11-28"],["dc.date.updated","2022-12-07T13:32:26Z"],["dc.description.abstract","In the field of environmental sustainability, the development of highly efficient photocatalytic under a wide wavelength range with band engineering is regarded as a promising strategy to enhance photocatalytic dye degradation. Here, we report on CaMnO3−δ and Pr0.5Ca0.5MnO3 perovskite materials prepared by a sol-gel combustion method. From X-ray photoelectron spectroscopy (XPS), the particle surfaces of both compounds are oxygen deficient, while the surface hydroxyl and carbonyl groups’ adsorption on the surface of Pr0.5Ca0.5MnO3 particles is more pronounced. FT-FIR spectroscopy has been used to investigate the covalent bonds and oxygen vacancy characteristics. Photocatalytic activities were investigated by the degradation of methylene blue and methyl orange under UV light. It was observed that both dye molecules are more degraded over CaMnO3−δ. The underlying mechanisms behind the photoexcitation and degradation process are established via the Spin-polarized Density Functional Theory (DFT)."],["dc.identifier.doi","10.3390/cryst12121728"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/118486"],["dc.language.iso","en"],["dc.relation.eissn","2073-4352"],["dc.rights","CC BY 4.0"],["dc.title","Photocatalytic Dye Decomposition over CaMnO3−δ and Pr0.5Ca0.5MnO3: A Combined XPS and DFT Study"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]
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  • 2017Journal Article Research Paper
    [["dc.bibliographiccitation.firstpage","1700109"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Advanced sustainable systems"],["dc.bibliographiccitation.volume","1"],["dc.contributor.author","Mierwaldt, Daniel"],["dc.contributor.author","Roddatis, Vladimir"],["dc.contributor.author","Risch, Marcel"],["dc.contributor.author","Scholz, Julius"],["dc.contributor.author","Geppert, Janis"],["dc.contributor.author","Abrishami, Majid Ebrahimizadeh"],["dc.contributor.author","Jooss, Christian"],["dc.date.accessioned","2020-12-10T14:06:44Z"],["dc.date.available","2020-12-10T14:06:44Z"],["dc.date.issued","2017"],["dc.identifier.doi","10.1002/adsu.201700109"],["dc.identifier.issn","2366-7486"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/70006"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C02 In situ hochauflösende Untersuchung des aktiven Zustands bei der photo- und elektrochemischen Wasserspaltung"],["dc.relation.orgunit","Institut für Materialphysik"],["dc.rights","CC BY-NC 4.0"],["dc.title","Environmental TEM Investigation of Electrochemical Stability of Perovskite and Ruddlesden-Popper Type Manganite Oxygen Evolution Catalysts"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.subtype","original_ja"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]
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  • 2017Journal Article Research Paper
    [["dc.bibliographiccitation.firstpage","4479"],["dc.bibliographiccitation.issue","22"],["dc.bibliographiccitation.journal","ChemSusChem"],["dc.bibliographiccitation.lastpage","4490"],["dc.bibliographiccitation.volume","10"],["dc.contributor.author","Köhler, Lennart"],["dc.contributor.author","Abrishami, Majid Ebrahimizadeh"],["dc.contributor.author","Roddatis, Vladimir"],["dc.contributor.author","Geppert, Janis"],["dc.contributor.author","Risch, Marcel"],["dc.date.accessioned","2018-10-17T06:32:18Z"],["dc.date.available","2018-10-17T06:32:18Z"],["dc.date.issued","2017"],["dc.description.abstract","Targeted improvement of the low efficiency of water oxidation during the oxygen evolution reaction (OER) is severely hindered by insufficient knowledge of the electrocatalytic mechanism on heterogeneous surfaces. We chose LiMn2 O4 as a model system for mechanistic investigations as it shares the cubane structure with the active site of photosystem II and the valence of Mn3.5+ with the dark-stable S1 state in the mechanism of natural photosynthesis. The investigated LiMn2 O4 nanoparticles are electrochemically stable in NaOH electrolytes and show respectable activity in any of the main metrics. At low overpotential, the key mechanistic parameters of Tafel slope, Nernst slope, and reaction order have constant values on the RHE scale of 62(1) mV dec-1 , 1(1) mV pH-1 , -0.04(2), respectively. These values are interpreted in the context of the well-studied mechanism of natural photosynthesis. The uncovered difference in the reaction sequence is important for the design of efficient bio-inspired electrocatalysts."],["dc.identifier.doi","10.1002/cssc.201701582"],["dc.identifier.pmid","28921902"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/14992"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/16065"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","final"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C05 Kontrolle Elektronen-getriebener Chemie durch Interkalation"],["dc.relation","SFB 1073 | Topical Area Z | Z02 Hochauflösende Charakterisierung von Grenzflächen"],["dc.relation.eissn","1864-564X"],["dc.relation.orgunit","Fakultät für Physik"],["dc.relation.orgunit","Institut für Materialphysik"],["dc.rights","CC BY-NC 4.0"],["dc.rights.uri","http://creativecommons.org/licenses/by-nc/4.0"],["dc.title","Mechanistic Parameters of Electrocatalytic Water Oxidation on LiMn2 O4 in Comparison to Natural Photosynthesis"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.subtype","original_ja"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]
    Details DOI PMID PMC
  • 2017Journal Article
    [["dc.bibliographiccitation.firstpage","4224"],["dc.bibliographiccitation.issue","22"],["dc.bibliographiccitation.journal","ChemSusChem"],["dc.bibliographiccitation.lastpage","4224"],["dc.bibliographiccitation.volume","10"],["dc.contributor.author","Köhler, Lennart"],["dc.contributor.author","Ebrahimizadeh Abrishami, Majid"],["dc.contributor.author","Roddatis, Vladimir"],["dc.contributor.author","Geppert, Janis"],["dc.contributor.author","Risch, Marcel"],["dc.date.accessioned","2021-12-08T12:30:28Z"],["dc.date.available","2021-12-08T12:30:28Z"],["dc.date.issued","2017"],["dc.identifier.doi","10.1002/cssc.201701810"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/96447"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-476"],["dc.relation.issn","1864-5631"],["dc.rights.uri","http://doi.wiley.com/10.1002/tdm_license_1.1"],["dc.title","Cover Feature: Mechanistic Parameters of Electrocatalytic Water Oxidation on LiMn 2 O 4 in Comparison to Natural Photosynthesis (ChemSusChem 22/2017)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]
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  • 2016Journal Article Research Paper
    [["dc.bibliographiccitation.artnumber","921"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","Materials"],["dc.bibliographiccitation.volume","9"],["dc.contributor.author","Abrishami, Majid Ebrahimizadeh"],["dc.contributor.author","Risch, Marcel"],["dc.contributor.author","Scholz, Julius"],["dc.contributor.author","Roddatis, Vladimir"],["dc.contributor.author","Osterthun, Norbert"],["dc.contributor.author","Jooss, Christian"],["dc.date.accessioned","2018-11-07T10:06:08Z"],["dc.date.available","2018-11-07T10:06:08Z"],["dc.date.issued","2016"],["dc.description.abstract","An improved understanding of the correlation between the electronic properties of Mn-O bonds, activity and stability of electro-catalysts for the oxygen evolution reaction (OER) is of great importance for an improved catalyst design. Here, an in-depth study of the relation between lattice structure, electronic properties and catalyst performance of the perovskite Ca1-xPrxMnO3 and the first-order RP-system Ca2-xPrxMnO4 at doping levels of x = 0, 0.25 and 0.5 is presented. Lattice structure is determined by X-ray powder diffraction and Rietveld refinement. X-ray absorption spectroscopy of Mn-L and O-K edges gives access to Mn valence and covalency of the Mn-O bond. Oxygen evolution activity and stability is measured by rotating ring disc electrode studies. We demonstrate that the highest activity and stability coincidences for systems with a Mn-valence state of +3.7, though also requiring that the covalency of the Mn-O bond has a relative minimum. This observation points to an oxygen evolution mechanism with high redox activity of Mn. Covalency should be large enough for facile electron transfer from adsorbed oxygen species to the MnO6 network; however, it should not be hampered by oxidation of the lattice oxygen, which might cause a crossover to material degradation. Since valence and covalency changes are not entirely independent, the introduction of the energy position of the e(g)(up arrow) pre-edge peak in the O-K spectra as a new descriptor for oxygen evolution is suggested, leading to a volcano-like representation of the OER activity."],["dc.identifier.doi","10.3390/ma9110921"],["dc.identifier.isi","000390114400007"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/14105"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/39033"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C02 In situ hochauflösende Untersuchung des aktiven Zustands bei der photo- und elektrochemischen Wasserspaltung"],["dc.relation.issn","1996-1944"],["dc.relation.orgunit","Fakultät für Physik"],["dc.relation.orgunit","Institut für Materialphysik"],["dc.rights","CC BY 4.0"],["dc.title","Oxygen Evolution at Manganite Perovskite Ruddlesden-Popper Type Particles: Trends of Activity on Structure, Valence and Covalence"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.subtype","original_ja"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]
    Details DOI WOS
  • 2021Journal Article
    [["dc.bibliographiccitation.firstpage","5165"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Journal of Materials Science. Materials in Electronics"],["dc.bibliographiccitation.lastpage","5175"],["dc.bibliographiccitation.volume","32"],["dc.contributor.author","Soleimani Varaki, M."],["dc.contributor.author","Jafari, A."],["dc.contributor.author","Ebrahimizadeh Abrishami, M."],["dc.date.accessioned","2021-04-14T08:30:37Z"],["dc.date.available","2021-04-14T08:30:37Z"],["dc.date.issued","2021"],["dc.identifier.doi","10.1007/s10854-021-05248-3"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/83312"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-399"],["dc.relation.eissn","1573-482X"],["dc.relation.issn","0957-4522"],["dc.title","Nonstoichiometric perovskite CaMnO3-δ nanomaterial for photocatalytic reduction of CO2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]
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