Roesky, Herbert W.

[["dc.bibliographiccitation.firstpage","3508"],["dc.bibliographiccitation.issue","17"],["dc.bibliographiccitation.journal","European Journal of Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","3512"],["dc.contributor.author","Jancik, Vojtech"],["dc.contributor.author","Moya Cabrera, Monica M."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Neculai, Dante"],["dc.contributor.author","Neculai, Ana M."],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Schmidt, Hans-Georg"],["dc.date.accessioned","2018-11-07T10:45:39Z"],["dc.date.available","2018-11-07T10:45:39Z"],["dc.date.issued","2004"],["dc.description.abstract","Addition of catalytic amounts of a phosphane to a reaction mixture containing LAlH2 [2; L = HC{C(Me)N(Ar)}(2), Ar = 2,6-iPr(2)C(6)H(3)] and elemental Se or Te resulted in the formation of poorly soluble [LAl(mu-Se)(2)AiL] (3) and [LAl(mu-Te)(2)AlL] (4), respectively. The sulfur analogue [LAl(mu-S)(2)AlL] (5) could not be obtained from the direct reaction of 2 with elemental sulfur; consequently, its synthesis was successfully achieved from the reaction of [LAlH2] and [LAl(SH)(2)]. A possible mechanism for the formation of [LAl(mu-Se)(2)AlL] and [LAl(mu-Te)(2)AlL] is discussed. The molecular structures of compounds 3-5 were determined by X-ray structure analyses. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)."],["dc.identifier.doi","10.1002/ejic.200400062"],["dc.identifier.isi","000223940100013"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/47552"],["dc.language.iso","en"],["dc.notes.status","final"],["dc.notes.submitter","Najko"],["dc.relation.issn","1434-1948"],["dc.title","Phosphane-catalyzed reactions of LAlH2 with elemental chalcogens; preparation of [LAl(mu-E)(2)AlL] [E = S, Se, Te, L = HC{C(Me)N(Ar)}(2), Ar=2,6-iPr(2)C(6)H(3)]"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2425"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","2431"],["dc.bibliographiccitation.volume","51"],["dc.contributor.author","Yang, Y."],["dc.contributor.author","Zhao, N. A."],["dc.contributor.author","Wu, Y."],["dc.contributor.author","Zhu, Hongping"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2018-11-07T09:13:23Z"],["dc.date.available","2018-11-07T09:13:23Z"],["dc.date.issued","2012"],["dc.description.abstract","Reactions of LGeCl (L = CH[C(Me)N(Ar)](2); Ar = 2,6-iPr(2)C(6)H(3)) with KOtBu or LiR (R = 2-thienyl, N(H)Ar, PPh2) yielded the germanium(II) compounds LGeR [R = OtBu (1), 2-thienyl (2), N(H)Ar (3), PPh2 (4)]. The reduction of (2-thienyl)(2)PCl with lithium afforded the diphosphane [(2-thienyl)(2)P](2) (5). The treatment of (2-thienyl)(2)PCl with LiAlH4 or KHBtBu(3) led to the formation of (2-thienyl)(2)PH (6). The NHC-assisted reaction of LGeCl and 6 resulted in the isolation of LGeP(2-thienyl)(2) (7). This is the first example where NHC is used for eliminating HCl from compounds with P-H and Ge-Cl bonds. All solid products were characterized by elemental analysis, NMR and IR spectroscopy, and single-crystal X-ray structure determination."],["dc.identifier.doi","10.1021/ic202388d"],["dc.identifier.isi","000300466300056"],["dc.identifier.pmid","22320161"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/27161"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","Synthesis and Characterization of beta-Diketiminate Germanium(II) Compounds"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","12049"],["dc.bibliographiccitation.issue","39"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","12054"],["dc.bibliographiccitation.volume","129"],["dc.contributor.author","So, Cheuk-Wai"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Gurubasavaraj, Prabhuodeyara M."],["dc.contributor.author","Oswald, Rainer B."],["dc.contributor.author","Gamer, Michael T."],["dc.contributor.author","Jones, Peter G."],["dc.contributor.author","Blaurock, Steffen"],["dc.date.accessioned","2018-11-07T10:57:50Z"],["dc.date.available","2018-11-07T10:57:50Z"],["dc.date.issued","2007"],["dc.description.abstract","The reaction of benzamidinato silicon trichloride [{PhC(NR)(2)}SiCl3] [R = Bu-t (1), SiMe3 (2)] with 2 equiv of potassium in THF afforded mononuclear chlorosilylene [{PhC(NBu')(2)}SiCl] (3) and [{PhC(NSiMe3)(2)}(2)SiCl2] (4), respectively. Compound 4 was formed by the disproportionation of unstable [{PhC(NSiMe3)(2)}SiCl]. The reaction of [{PhC(NBu')(2)}SiCl3] (1) with 1 equiv of UR (R = NMe2, OBut, OPrj, PPr2i) in THF yielded [{PhC(NBut)(2)}SiCl2R] [R = NMe2 (5), OBut (6), OPrj (7), PPr2i (8)]. Treatment of 5-8 with 2 equiv of potassium in THF resulted in the novel heteroleptic silylene [{PhC(NBut)(2)}SiR] [R = NMe2 (9), OBut (10), OPri (11), PPr2i (12)]. Compounds 4, 9, and 12 have been analyzed by X-ray crystallography."],["dc.identifier.doi","10.1021/ja074019e"],["dc.identifier.isi","000249887700037"],["dc.identifier.pmid","17845044"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/50343"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0002-7863"],["dc.title","Synthesis and structures of heteroleptic silylenes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2343"],["dc.bibliographiccitation.issue","10"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","2347"],["dc.bibliographiccitation.volume","29"],["dc.contributor.author","Sen, Sakya S."],["dc.contributor.author","Tavcar, Gasper"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Kratzert, Daniel"],["dc.contributor.author","Hey, Jakob"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T08:43:09Z"],["dc.date.available","2018-11-07T08:43:09Z"],["dc.date.issued","2010"],["dc.description.abstract","The base-stabilized bis-silylene (LSi-SiL, L = PhC(NtBu)1) was reacted with benzophenone in a 1:2 ratio in THF, which afforded a Si2O2 four-membered ring, stabilized by bulky amidinato ligands. The most striking phenomenon is the abstraction of oxygen from benzophenone and the simultaneous formation of a silicon carbon bond. The four-membered Si2O2 ring is planar, and both the silicon atoms are five-coordinate. The two silicon atoms are arranged opposite each other in the four-membered Si2O2 ring. Moreover LSi-SiL was treated with N2O to afford two four-membered Si3O, rings connected with two oxygen atoms. In this structure also the silicon atoms are five-coordinate."],["dc.identifier.doi","10.1021/om100164u"],["dc.identifier.isi","000277597500017"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/19888"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0276-7333"],["dc.title","Synthesis of a Stable Four-Membered Si2O2 Ring and a Dimer with Two Four-Membered Si2O2 Rings Bridged by Two Oxygen Atoms, with Five-Coordinate Silicon Atoms in Both Ring Systems"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1365"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Angewandte Chemie"],["dc.bibliographiccitation.lastpage","1366"],["dc.bibliographiccitation.volume","106"],["dc.contributor.author","Storre, Jens"],["dc.contributor.author","Belgardt, Thomas"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2019-07-09T11:52:18Z"],["dc.date.available","2019-07-09T11:52:18Z"],["dc.date.issued","1994"],["dc.identifier.doi","10.1002/ange.19941061235"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3412"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60148"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Synthese und Struktur des ersten metallorganischen Galloxanhydroxids Mes6Ga6O4(OH)4"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2204"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","2211"],["dc.bibliographiccitation.volume","51"],["dc.contributor.author","Yang, Y."],["dc.contributor.author","Li, Haipu"],["dc.contributor.author","Wang, C."],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2018-11-07T09:13:23Z"],["dc.date.available","2018-11-07T09:13:23Z"],["dc.date.issued","2012"],["dc.description.abstract","Reactions of LH (L = HC[C(Me)N(2,6-Me2C6H3)](2)) with MenAlCl3-n, in diethyl ether afforded the adducts LH center dot AlMen(Cl)(3-n)(n = 2, 3; 1, 4; 0, 5) in good yields. Treatment of 3 at elevated temperatures in toluene resulted in LAlMeCl (2) by intramolecular elimination of methane. The controlled hydrolysis of LAlMeC1 (2) with equimolar amounts of water in the presence of N-heterocyclic carbene (NHC) gave a mixture of [LAl(Me)](2)(mu-O) (7) and dimeric [LAlMe(mu-OH)](2) (8). A convenient route for the preparation of [LAlMe(mu-OH)](2) (8) was the NHC-assisted controlled hydrolysis of LAlMeI (9). Stepwise hydrolysis of LAlH2 (11) gave dialuminoxane hydride [LAl(H)](2)(mu-O) (12) and dialuminoxane hydroxide [LAl(OH)](2)(mu-O) (13), respectively. Anhydrous treatment of LAlCl2 (1) or LAlMeCl (2) with Ag2O afforded chlorinated dialuminoxane [LAl(Cl)](2)(mu-O) (14) and [LAl(Me)](2)(mu-O) (7), respectively."],["dc.identifier.doi","10.1021/ic2021879"],["dc.identifier.isi","000300466300030"],["dc.identifier.pmid","22320206"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/27160"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","1520-510X"],["dc.relation.issn","0020-1669"],["dc.title","Studies of the Ligand Effect on the Synthesis of Dialuminoxanes by Various beta-Diketiminato Ligands"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1102"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","European Journal of Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","1104"],["dc.bibliographiccitation.volume","2014"],["dc.contributor.author","Yang, Zhi"],["dc.contributor.author","Li, Kai"],["dc.contributor.author","Ma, Xiaoli"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Hao, Pengfei"],["dc.contributor.author","Zhong, M."],["dc.date.accessioned","2018-11-07T09:44:13Z"],["dc.date.available","2018-11-07T09:44:13Z"],["dc.date.issued","2014"],["dc.description.abstract","The reaction of trimethylaluminum with a salen {salenH(2) = [N,N-bis(salicylidene)ethylenediamine]} ligand in toluene afforded the complex [Me2AlOC6H4CH=NCH2-](n). It shows a one-dimensional structure in the crystal state with pentacoordinate aluminum. This complex was characterized by H-1 and C-13 NMR spectroscopy, IR spectroscopy, single-crystal X-ray structure, and elemental analysis."],["dc.identifier.doi","10.1002/ejic.201301384"],["dc.identifier.isi","000331512000017"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/34342"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1099-0682"],["dc.relation.issn","1434-1948"],["dc.title","One-Dimensional Structure of an Aluminum Coordination Compound"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","3995"],["dc.bibliographiccitation.issue","18"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","3998"],["dc.bibliographiccitation.volume","39"],["dc.contributor.author","Chakraborty, D."],["dc.contributor.author","Horchler, S."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Noltemeyer, M."],["dc.contributor.author","Schmidt, H. G."],["dc.date.accessioned","2018-11-07T10:19:02Z"],["dc.date.available","2018-11-07T10:19:02Z"],["dc.date.issued","2000"],["dc.description.abstract","The first phosphonate anions of aluminum-containing fluorine and an anionic bridged fluoroalkoxy derivative of titanium have been realized using n-Bu4NHF2 as a fluorinating agent in organometallic synthesis. Reactions of [RPO3AlMe](4) [R = Ph (1), t-Bu] with n-Bu4NHF2 yield organic-soluble compounds of the type [n-Bu4N](2)[RPO3AlF2](2) [R = Ph (2), t-Bu (3)], whereas the reaction of Ti(O-i-Pr)(4) with n-Bu4NHF2 results in the formation of [n-Bu4N][(O-i-Pr)(3)Ti(mu-F)(2)(mu-O-i-Pr)Ti(O-i-Pr)(3)] (4). These compounds have been obtained in high yields and have been adequately characterized through spectroscopic techniques and X-ray diffraction studies."],["dc.identifier.doi","10.1021/ic991453b"],["dc.identifier.isi","000089234300008"],["dc.identifier.pmid","11198852"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/41580"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.title","Application of n-Bu4NHF2 as a fluorinating agent for the preparation of fluoroanions: Synthesis and crystal structure of the anions [t-BuPO3AlF2](2)(2-), [PhPO3AlF2](2)(2-), and [(O-i-Pr)(3)Ti(mu-F)(2)(mu-O-i-Pr)Ti(O-i-Pr)(3)](-)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2777"],["dc.bibliographiccitation.issue","15"],["dc.bibliographiccitation.journal","European Journal of Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","2781"],["dc.contributor.author","Azhakar, Ramachandran"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Holstein, Julian Jacob"],["dc.contributor.author","Dittrich, Birger"],["dc.date.accessioned","2018-11-07T09:25:02Z"],["dc.date.available","2018-11-07T09:25:02Z"],["dc.date.issued","2013"],["dc.description.abstract","The reaction of LSitBu [L = PhC(NtBu)2] (1) with 4,4-bis(dimethylamino)thiobenzophenone resulted in the [1+2]-cycloaddition product silathiacyclopropane 3, bearing a three-membered SiCS ring. The reaction of LSiC(SiMe3)3 (2) with 3,5-di-tert-butyl-o-benzoquinone leads to the [1+4]-cycloaddition product 4. In 3 the silicon atom is five- and in 4 it is four-coordinate. Compounds 3 and 4 were characterized by spectroscopic and spectrometric techniques. The molecular structures of 1, 3, and 4 were unequivocally established by single-crystal X-ray structure analysis."],["dc.description.sponsorship","Deutsche Forschungsgemeinschaft (DFG); Alexander von Humboldt Stiftung"],["dc.identifier.doi","10.1002/ejic.201300085"],["dc.identifier.isi","000318917700010"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/29977"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1434-1948"],["dc.title","Reaction of the Silylene PhC(NtBu)2SitBu with 4,4-Bis(dimethylamino)thiobenzophenone and Treatment of the Silylene PhC(NtBu)2SiC(SiMe3)3 with 3,5-Di-tert-butyl-o-benzoquinone"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","no"],["dc.bibliographiccitation.issue","26"],["dc.bibliographiccitation.journal","ChemInform"],["dc.bibliographiccitation.lastpage","no"],["dc.bibliographiccitation.volume","30"],["dc.contributor.author","Jagirdar, Balaji R."],["dc.contributor.author","Murphy, Eamonn F."],["dc.contributor.author","Roesky, Herbert W."],["dc.date.accessioned","2021-12-08T12:28:31Z"],["dc.date.available","2021-12-08T12:28:31Z"],["dc.date.issued","2010"],["dc.identifier.doi","10.1002/chin.199926282"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/95727"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-476"],["dc.relation.eissn","1522-2667"],["dc.relation.issn","0931-7597"],["dc.rights.uri","http://doi.wiley.com/10.1002/tdm_license_1.1"],["dc.title","ChemInform Abstract: Organometallic Fluorides of the Main Group Metals Containing the C-M-F Fragment"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]