Geppert, Janis

[["dc.bibliographiccitation.firstpage","1700109"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Advanced sustainable systems"],["dc.bibliographiccitation.volume","1"],["dc.contributor.author","Mierwaldt, Daniel"],["dc.contributor.author","Roddatis, Vladimir"],["dc.contributor.author","Risch, Marcel"],["dc.contributor.author","Scholz, Julius"],["dc.contributor.author","Geppert, Janis"],["dc.contributor.author","Abrishami, Majid Ebrahimizadeh"],["dc.contributor.author","Jooss, Christian"],["dc.date.accessioned","2020-12-10T14:06:44Z"],["dc.date.available","2020-12-10T14:06:44Z"],["dc.date.issued","2017"],["dc.identifier.doi","10.1002/adsu.201700109"],["dc.identifier.issn","2366-7486"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/70006"],["dc.language.iso","en"],["dc.notes.intern","DOI Import GROB-354"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C02 In situ hochauflösende Untersuchung des aktiven Zustands bei der photo- und elektrochemischen Wasserspaltung"],["dc.relation.orgunit","Institut für Materialphysik"],["dc.rights","CC BY-NC 4.0"],["dc.title","Environmental TEM Investigation of Electrochemical Stability of Perovskite and Ruddlesden-Popper Type Manganite Oxygen Evolution Catalysts"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.subtype","original_ja"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4479"],["dc.bibliographiccitation.issue","22"],["dc.bibliographiccitation.journal","ChemSusChem"],["dc.bibliographiccitation.lastpage","4490"],["dc.bibliographiccitation.volume","10"],["dc.contributor.author","Köhler, Lennart"],["dc.contributor.author","Abrishami, Majid Ebrahimizadeh"],["dc.contributor.author","Roddatis, Vladimir"],["dc.contributor.author","Geppert, Janis"],["dc.contributor.author","Risch, Marcel"],["dc.date.accessioned","2018-10-17T06:32:18Z"],["dc.date.available","2018-10-17T06:32:18Z"],["dc.date.issued","2017"],["dc.description.abstract","Targeted improvement of the low efficiency of water oxidation during the oxygen evolution reaction (OER) is severely hindered by insufficient knowledge of the electrocatalytic mechanism on heterogeneous surfaces. We chose LiMn2 O4 as a model system for mechanistic investigations as it shares the cubane structure with the active site of photosystem II and the valence of Mn3.5+ with the dark-stable S1 state in the mechanism of natural photosynthesis. The investigated LiMn2 O4 nanoparticles are electrochemically stable in NaOH electrolytes and show respectable activity in any of the main metrics. At low overpotential, the key mechanistic parameters of Tafel slope, Nernst slope, and reaction order have constant values on the RHE scale of 62(1) mV dec-1 , 1(1) mV pH-1 , -0.04(2), respectively. These values are interpreted in the context of the well-studied mechanism of natural photosynthesis. The uncovered difference in the reaction sequence is important for the design of efficient bio-inspired electrocatalysts."],["dc.identifier.doi","10.1002/cssc.201701582"],["dc.identifier.pmid","28921902"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?gs-1/14992"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/16065"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.notes.status","final"],["dc.relation","SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen"],["dc.relation","SFB 1073 | Topical Area C | C05 Kontrolle Elektronen-getriebener Chemie durch Interkalation"],["dc.relation","SFB 1073 | Topical Area Z | Z02 Hochauflösende Charakterisierung von Grenzflächen"],["dc.relation.eissn","1864-564X"],["dc.relation.orgunit","Fakultät für Physik"],["dc.relation.orgunit","Institut für Materialphysik"],["dc.rights","CC BY-NC 4.0"],["dc.rights.uri","http://creativecommons.org/licenses/by-nc/4.0"],["dc.title","Mechanistic Parameters of Electrocatalytic Water Oxidation on LiMn2 O4 in Comparison to Natural Photosynthesis"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.subtype","original_ja"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4224"],["dc.bibliographiccitation.issue","22"],["dc.bibliographiccitation.journal","ChemSusChem"],["dc.bibliographiccitation.lastpage","4224"],["dc.bibliographiccitation.volume","10"],["dc.contributor.author","Köhler, Lennart"],["dc.contributor.author","Ebrahimizadeh Abrishami, Majid"],["dc.contributor.author","Roddatis, Vladimir"],["dc.contributor.author","Geppert, Janis"],["dc.contributor.author","Risch, Marcel"],["dc.date.accessioned","2021-12-08T12:30:28Z"],["dc.date.available","2021-12-08T12:30:28Z"],["dc.date.issued","2017"],["dc.identifier.doi","10.1002/cssc.201701810"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/96447"],["dc.language.iso","en"],["dc.notes.intern","DOI-Import GROB-476"],["dc.relation.issn","1864-5631"],["dc.rights.uri","http://doi.wiley.com/10.1002/tdm_license_1.1"],["dc.title","Cover Feature: Mechanistic Parameters of Electrocatalytic Water Oxidation on LiMn 2 O 4 in Comparison to Natural Photosynthesis (ChemSusChem 22/2017)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dspace.entity.type","Publication"]]