Neculai, Dante

[["dc.bibliographiccitation.firstpage","3508"],["dc.bibliographiccitation.issue","17"],["dc.bibliographiccitation.journal","European Journal of Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","3512"],["dc.contributor.author","Jancik, Vojtech"],["dc.contributor.author","Moya Cabrera, Monica M."],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Neculai, Dante"],["dc.contributor.author","Neculai, Ana M."],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Schmidt, Hans-Georg"],["dc.date.accessioned","2018-11-07T10:45:39Z"],["dc.date.available","2018-11-07T10:45:39Z"],["dc.date.issued","2004"],["dc.description.abstract","Addition of catalytic amounts of a phosphane to a reaction mixture containing LAlH2 [2; L = HC{C(Me)N(Ar)}(2), Ar = 2,6-iPr(2)C(6)H(3)] and elemental Se or Te resulted in the formation of poorly soluble [LAl(mu-Se)(2)AiL] (3) and [LAl(mu-Te)(2)AlL] (4), respectively. The sulfur analogue [LAl(mu-S)(2)AlL] (5) could not be obtained from the direct reaction of 2 with elemental sulfur; consequently, its synthesis was successfully achieved from the reaction of [LAlH2] and [LAl(SH)(2)]. A possible mechanism for the formation of [LAl(mu-Se)(2)AlL] and [LAl(mu-Te)(2)AlL] is discussed. The molecular structures of compounds 3-5 were determined by X-ray structure analyses. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004)."],["dc.identifier.doi","10.1002/ejic.200400062"],["dc.identifier.isi","000223940100013"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/47552"],["dc.language.iso","en"],["dc.notes.status","final"],["dc.notes.submitter","Najko"],["dc.relation.issn","1434-1948"],["dc.title","Phosphane-catalyzed reactions of LAlH2 with elemental chalcogens; preparation of [LAl(mu-E)(2)AlL] [E = S, Se, Te, L = HC{C(Me)N(Ar)}(2), Ar=2,6-iPr(2)C(6)H(3)]"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","8803"],["dc.bibliographiccitation.issue","26"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","8810"],["dc.bibliographiccitation.volume","42"],["dc.contributor.author","Neculai, A. M."],["dc.contributor.author","Cummins, C. C."],["dc.contributor.author","Neculai, D."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Bunkoczi, G."],["dc.contributor.author","Walfort, B."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T10:33:58Z"],["dc.date.available","2018-11-07T10:33:58Z"],["dc.date.issued","2003"],["dc.description.abstract","Sc(BrMgL)(2)Br (L = (R2NCH2CH2NCMe)(2)CH, R = H) was studied by DFT methods leading to the conclusion that this diamagnetic formal scandium(I) system enjoys stabilization of its Sc-based filled d(yz) orbital by a delta-acceptor linear combination of BrMgL ring orbitals. Investigation of the reactivity of Sc(BrMgL)2Br (L = (R2NCH2CH2NCMe)2CH, R = Et) with H2O.B(C6F5)(3) and (HOCH2)(2)CMe2, respectively, led to decomposition, with LMgBr being isolated in the latter case."],["dc.identifier.doi","10.1021/ic034947o"],["dc.identifier.isi","000187740100031"],["dc.identifier.pmid","14686860"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/44750"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0020-1669"],["dc.title","Elucidation of a Sc(I) complex by DFT calculations and reactivity studies"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1452"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","Journal of the American Chemical Society"],["dc.bibliographiccitation.lastpage","1453"],["dc.bibliographiccitation.volume","125"],["dc.contributor.author","Jancik, V."],["dc.contributor.author","Peng, Y."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Li, J. Y."],["dc.contributor.author","Neculai, D."],["dc.contributor.author","Neculai, A. M."],["dc.contributor.author","Herbst-Irmer, R."],["dc.date.accessioned","2018-11-07T10:40:55Z"],["dc.date.available","2018-11-07T10:40:55Z"],["dc.date.issued","2003"],["dc.identifier.doi","10.1021/ja028801k"],["dc.identifier.isi","000180842200005"],["dc.identifier.pmid","12568585"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/46420"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0002-7863"],["dc.title","The first structurally characterized aluminum compound with two SH groups: [LAI(SH)(2)] (L=N(Ar)C(Me)CHC(Me)N(Ar), Ar=2,6-i-Pr2C6H3) and the catalytic properties of the sulfur P(NMe2)(3) system"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2142"],["dc.bibliographiccitation.issue","16"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","2145"],["dc.bibliographiccitation.volume","43"],["dc.contributor.author","Jancik, V."],["dc.contributor.author","Pineda, Leslie W."],["dc.contributor.author","Pinkas, J."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Neculai, D."],["dc.contributor.author","Neculai, A. M."],["dc.contributor.author","Herbst-Irmer, R."],["dc.date.accessioned","2018-11-07T10:49:40Z"],["dc.date.available","2018-11-07T10:49:40Z"],["dc.date.issued","2004"],["dc.identifier.doi","10.1002/anie.200353541"],["dc.identifier.isi","000221005400021"],["dc.identifier.pmid","15083467"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/48480"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1433-7851"],["dc.title","Preparation of monomeric [LAl(NH2)(2)] - A main-group metal diamide containing two terminal NH2 groups"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2831"],["dc.bibliographiccitation.issue","14"],["dc.bibliographiccitation.journal","Dalton Transactions"],["dc.bibliographiccitation.lastpage","2834"],["dc.contributor.author","Neculai, D."],["dc.contributor.author","Neculai, A. M."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Herbst-Irmer, R."],["dc.contributor.author","Walfort, B."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2018-11-07T10:42:18Z"],["dc.date.available","2018-11-07T10:42:18Z"],["dc.date.issued","2003"],["dc.description.abstract","The reaction of LLi (where L = N, N'-bis(2-diethylaminoethyl)-2,4-pentanediimine- ate(-1)) with VCl3.3THF yielded LVCl2, which was characterized by EI-MS and elemental analysis. Subsequent reactions of LVCl2 with AgOSO2CF3 and KPPh2 afforded two new complexes, LV(OSO2CF3)(2) and LVPPh2 which were characterized by F-19, P-31 NMR spectroscopy, EI-MS, elemental analysis, and single crystal X-ray structural analysis."],["dc.identifier.doi","10.1039/b303196a"],["dc.identifier.isi","000184049700008"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/46763"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Royal Soc Chemistry"],["dc.relation.issn","1477-9226"],["dc.title","Vanadium complexes incorporating the beta-diketiminato ligand L. Syntheses and structures of LV(OSO2CF3)(2) and LVPPh2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","3120"],["dc.bibliographiccitation.issue","17"],["dc.bibliographiccitation.journal","European Journal of Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","3126"],["dc.contributor.author","Neculai, A. M."],["dc.contributor.author","Neculai, D."],["dc.contributor.author","Nikiforov, G. B."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Schlicker, C."],["dc.contributor.author","Herbst-Irmer, R."],["dc.contributor.author","Magull, Joerg"],["dc.contributor.author","Noltemeyer, M."],["dc.date.accessioned","2018-11-07T10:36:11Z"],["dc.date.available","2018-11-07T10:36:11Z"],["dc.date.issued","2003"],["dc.description.abstract","The reaction of LScBr2 (1), LYI2 (3), LHoI2 (4), or LErI2 (5) [L = N,N\"-(1,3-dimethyl-1,3-propanediylidene)bis(N',N'-diethyl-1,2-ethanediamine)] with Me3SnF was investigated. Treatment of 1 with Me3SnF results in the formation of (Me3BrSn-mu-F)(2)LSc (2) while compounds 3-5 give [LSnMe2][Me3SnI2] (6) as the only product that could be isolated and characterized. Metathesis reactions of 1 with AgSO3CF3 led to LSc(SO3CF3)(2) (7). Compounds 1, 2, 6 and 7 were characterized by single-crystal X-ray structural analysis. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)."],["dc.identifier.doi","10.1002/ejic.200300213"],["dc.identifier.isi","000185327500007"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/45267"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1434-1948"],["dc.title","Partially fluorinated rare earth metal complexes"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","433"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","European Journal of Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","436"],["dc.contributor.author","Nikiforov, G. B."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Labalm, T."],["dc.contributor.author","Vidovic, D."],["dc.contributor.author","Neculai, D."],["dc.date.accessioned","2018-11-07T10:41:12Z"],["dc.date.available","2018-11-07T10:41:12Z"],["dc.date.issued","2003"],["dc.description.abstract","Two new diiodide complexes of stoichiometry LLnI(2) [Ln = Ho (1), Er (2)] with the beta-diketiminato ligand 2-{[2-(diethylamino) ethyl]amino}-4-{[2-(diethylamino)ethyl]imino}pent-2-ene have been synthesized by the reaction of the lithium salt of the ligand with the corresponding. triiodides. The complexes are thermally stable and soluble in common organic solvents. The X-ray structural and elemental analysis show that LLnI(2) is neutral, and as well free of solvent and lithium salt. The complexes adopt a pseudo-octahedral geometry with the two iodine atoms arranged in trans position to each other. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)."],["dc.identifier.isi","000181789800007"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/46481"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1434-1948"],["dc.title","Synthesis and structure of the first holmium and erbium diiodide complexes of composition LLnI(2) (Ln=Ho, Er)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.artnumber","PII S0022-1139(02)00222-1"],["dc.bibliographiccitation.firstpage","131"],["dc.bibliographiccitation.issue","1-2"],["dc.bibliographiccitation.journal","Journal of Fluorine Chemistry"],["dc.bibliographiccitation.lastpage","134"],["dc.bibliographiccitation.volume","118"],["dc.contributor.author","Neculai, D."],["dc.contributor.author","Neculai, A. M."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Magull, Joerg"],["dc.contributor.author","Bunkoczi, G."],["dc.date.accessioned","2018-11-07T09:45:54Z"],["dc.date.available","2018-11-07T09:45:54Z"],["dc.date.issued","2002"],["dc.description.abstract","The preparation and characterization of a new fluorinated beta-ketoiminato ligand and its lithium salt of composition [(Et2NCH2CH2NC(CF3)CHC(CF3)OLi)(2)] are described. The crystal structure of the latter was determined. The use of a Meerwein salt as a new route for obtaining fluorinated beta-ketoiminato ligands is also investigated. (C) 2002 Elsevier Science B.V. All rights reserved."],["dc.identifier.doi","10.1016/S0022-1139(02)00222-1"],["dc.identifier.isi","000179614100017"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/34738"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Elsevier Science Sa"],["dc.relation.issn","0022-1139"],["dc.title","Synthesis and structure of a new fluorinated beta-ketoiminato ligand and its lithium derivative"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2279"],["dc.bibliographiccitation.issue","11"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","2283"],["dc.bibliographiccitation.volume","22"],["dc.contributor.author","Neculai, D."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Neculai, A. M."],["dc.contributor.author","Magull, Joerg"],["dc.contributor.author","Herbst-Irmer, R."],["dc.date.accessioned","2018-11-07T10:38:53Z"],["dc.date.available","2018-11-07T10:38:53Z"],["dc.date.issued","2003"],["dc.description.abstract","Reaction of a new beta-diketiminato derivative of terbium, LTbBr2 (L = [N,N\"-(1,3-dimethyl-1,3-propanediylidene)bis[N'.N\"-diethyl-1,2-ethanediamine]]), in the molar ratio 1:2 with LiCH2SiMe3 gives the terbium complex LTb(CH2SiMe3)(2), whose structure was established by elemental and X-ray analyses."],["dc.identifier.doi","10.1021/om0209879"],["dc.identifier.isi","000182925600021"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/45914"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Amer Chemical Soc"],["dc.relation.issn","0276-7333"],["dc.title","The first beta-diketiminato complex of terbium containing two alkyl groups: A model compound for LLnR2 (Ln = lanthanide, R = alkyl) systems"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","6192"],["dc.bibliographiccitation.issue","45"],["dc.bibliographiccitation.journal","Angewandte Chemie International Edition"],["dc.bibliographiccitation.lastpage","6196"],["dc.bibliographiccitation.volume","43"],["dc.contributor.author","Jancik, V."],["dc.contributor.author","Roesky, H. W."],["dc.contributor.author","Neculai, D."],["dc.contributor.author","Neculai, A. M."],["dc.contributor.author","Herbst-Irmer, R."],["dc.date.accessioned","2018-11-07T10:52:00Z"],["dc.date.available","2018-11-07T10:52:00Z"],["dc.date.issued","2004"],["dc.identifier.doi","10.1002/anie.200461254"],["dc.identifier.isi","000225445200026"],["dc.identifier.pmid","15549751"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/49019"],["dc.notes.status","zu prüfen"],["dc.notes.submitter","Najko"],["dc.publisher","Wiley-v C H Verlag Gmbh"],["dc.relation.issn","1433-7851"],["dc.title","Preparation of [LAl(mu-S)(2)MCp2] (M = Ti, Zr) from the structurally characterized lithium complexes [{LAl(SH)[SLi(thf)(2)]}(2)] and [{LAl(SLi)(2)(thf)(3)]}(2)]center dot 2THF"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.status","published"],["dspace.entity.type","Publication"]]