Edelmann, Frank Thomas

[["dc.bibliographiccitation.firstpage","2171"],["dc.bibliographiccitation.issue","10"],["dc.bibliographiccitation.journal","Chemische Berichte"],["dc.bibliographiccitation.lastpage","2181"],["dc.bibliographiccitation.volume","125"],["dc.contributor.author","Wedler, Michael"],["dc.contributor.author","Knösel, Friederich"],["dc.contributor.author","Pieper, Ursula"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.contributor.author","Amberger, Hanns-Dieter"],["dc.date.accessioned","2019-07-09T11:52:12Z"],["dc.date.available","2019-07-09T11:52:12Z"],["dc.date.issued","1992"],["dc.description.abstract","Anhydrous lanthanide trichlorides react with N-silylated sodium benzamidinates, Na[4-RC6H4C(NSiMe3)2], (1a-d), to give the monomeric, homoleptic lanthanide(III) benzamidinates [4-RC6H4C(NSiMe3)2]3Ln (2-23, R = H, MeO, CF3, Ph). The molecular structure of [4-MeOC6H4C(NSiMe3)2]3Pr (11) has been determined by X-ray diffraction. Absorption and emission measurements reveal that the three benzamidinate ligands produce an unusually large crystal field which is comparable with that of cyclopentadienyl."],["dc.identifier.doi","10.1002/cber.19921251003"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3349"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60112"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Sterische Cyclopentadienyl-Äquivalente in der Chemie der f-Elemente: Monomere, homoleptische Lanthanid(III)-tris[N,N-bis(trimethylsilyl)-benzamidinate]"],["dc.title.alternative","Steric Cyclopentadienyl Equivalents in f-Element Chemistry: Monomeric, Homoleptic Lanthanide(III) Tris[N,N-bis(trimethylsilyl)benzamidinates]"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","496"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Angewandte Chemie"],["dc.bibliographiccitation.lastpage","497"],["dc.bibliographiccitation.volume","101"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2019-07-09T11:52:02Z"],["dc.date.available","2019-07-09T11:52:02Z"],["dc.date.issued","1989"],["dc.identifier.doi","10.1002/ange.1761010428"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3290"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60073"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Reduktive Dimerisierung eines Phosphaalkins unter Komlexierung an Samarium"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1373"],["dc.bibliographiccitation.issue","6"],["dc.bibliographiccitation.journal","Chemische Berichte"],["dc.bibliographiccitation.lastpage","1375"],["dc.bibliographiccitation.volume","124"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2019-07-09T11:52:06Z"],["dc.date.available","2019-07-09T11:52:06Z"],["dc.date.issued","1991"],["dc.description.abstract","The tetranuclear complex [Cp Sm(-OC)2FeCp ]2 (3) has been prepared by reaction of Cp 2Sm(THF)2 with [Cp Fe(CO)2]2 and structurally characterized by single-crystal X-ray diffraction."],["dc.identifier.doi","10.1002/cber.19911240611"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3329"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60098"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Organolanthanid(II)-Chemie: Synthese und Struktur von [Cp2 Sm(-OC)2FeCp ]2"],["dc.title.alternative","Organolanthanide(II) Chemistry: Synthesis and Structure of [Cp*Sm(-OC)2FeCp*]2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","347"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","356"],["dc.bibliographiccitation.volume","411"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Pieper, Ursula"],["dc.contributor.author","Schmidt, Hans-Georg"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-26T07:40:17Z"],["dc.date.accessioned","2021-10-27T13:12:24Z"],["dc.date.available","2009-06-26T07:40:17Z"],["dc.date.available","2021-10-27T13:12:24Z"],["dc.date.issued","1991"],["dc.description.abstract","Das THF-Addukt des Decamethylsamarocens, Cp2 Sm(THF)2, reagiert mit Disulfiden, Diseleniden und Ditelluriden zu Organosamarium(III)komplexen, die eine Sm–E-Bindung enthalten (E = p. Se, Te). Die Molekülstrukturen der Komplexe Cp2 Sm(S2CNMe2) (1), Cp2 Sm[TeC6H2Me3-2,4,6](THF) (4) und Cp2 Sm[SeC6H2(CF3)3-2,4,6](THF) (5) wurden röntgenographisch bestimmt. Abstract: The THF adduct of decamethylsamarocene, CP2Sm(THF)2, reacts with disulfides, diselenides and ditellurides to give organosamarium(III) complexes containing a Sm---E bond (E = S, Se, Te). The molecular structures of the complexes CP2Sm(S2CNMe2) (1), Cp2Sm[TeC6H2Me3-2,4,6](THF) (4) and Cp2Sm[SeC6H2(CF3)3-2,4,6](THF) (5 have been determined by X-ray diffraction."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(91)83040-B"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3328"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91688"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Monomere Organosamarium(III) Chalkogenolate durch reduktive Spaltung von E–E-Bindungen (E = S, Se, Te)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","4143"],["dc.bibliographiccitation.issue","20"],["dc.bibliographiccitation.journal","Inorganic Chemistry"],["dc.bibliographiccitation.lastpage","4146"],["dc.bibliographiccitation.volume","31"],["dc.contributor.author","Pauer, Frank"],["dc.contributor.author","Wedler, Michael"],["dc.contributor.author","Edelmann, Frank"],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2019-07-09T11:52:12Z"],["dc.date.available","2019-07-09T11:52:12Z"],["dc.date.issued","1992"],["dc.description.abstract","Unsolvated RbN(SiMe3)z (1) and CsN(SiMe3)z (2) have been prepared from rubidium and cesium metal respectively and excess hexamethyldisilazane. The molecular structures of the polymeric dioxane adducts NaN(SiMes) .C4HsO2 (3) and [MN(S~M~~)~~.~C~H~(4O, M~ ]=. ROb; .5, ~MC =~ CHs)~ haOveZ been determined by low-temperature single-crystal X-ray diffraction."],["dc.identifier.doi","10.1021/ic00046a028"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3344"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60109"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Preparation and structural characterization of dioxane-coordinated alkali metal bis(trimethylsilyl)amides"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","192"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Organometallics"],["dc.bibliographiccitation.lastpage","195"],["dc.bibliographiccitation.volume","11"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Bertel, Norbert"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Sheldrick, George M."],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2019-07-09T11:52:11Z"],["dc.date.available","2019-07-09T11:52:11Z"],["dc.date.issued","1992"],["dc.description.abstract","The molecular structures of (RF)2Zn( 3), (RF)2Cd(MeCN()4 a), and (RF)2Hg (5) have_b een determined by X-ray crystallography (RF = 2,4,6-tris(trifluoromethyl)phenyl). For 3: triclinic, P1, a = 8.339 (3) A, b = 9.064 (2) A, c = 13.499 (4) A, CY = 88.38 (3)O, @ = 87.79 (4)O, y = 76.85 (2)O, V = 992.6 (5) A3, 2 = 2,and R = 3.92%. For 4a: monoclinic, P21/c, a = 10.876 (3) A, b = 16.79 (1) A, c = 13.865 (5) A, @ = 112.81 = 15.294 (3) A, @ = 92.20 (3)O, V = 1066.3 (4) A3, Z = 2, and R = 5.73%. A characteristic structural feature of all three derivatives is weak metal-fluorine interactions. (R&Zn and (RJ2Cd(MeCN) represent the first examples of structurally characterized two- and three-coordinate monomeric diarylzinc and -cadmium."],["dc.identifier.doi","10.1021/om00037a037"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3342"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60107"],["dc.language.iso","en"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Main-group chemistry of the 2,4,6-tris(trifluoromethyl)phenyl substituent: x-ray crystal structures of [2,4,6-(CF3)3C6H2]2Zn, [2,4,6-(CF3)3C6H2]2Cd(MeCN) and [2,4,6-(CF3)3C6H3]2Hg"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","217"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","335"],["dc.bibliographiccitation.volume","414"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-25T08:13:02Z"],["dc.date.accessioned","2021-10-27T13:12:33Z"],["dc.date.available","2009-06-25T08:13:02Z"],["dc.date.available","2021-10-27T13:12:33Z"],["dc.date.issued","1991"],["dc.description.abstract","Die Molekülstruktur von Li[Ph2P(NSiMe3)2](THF)2 (2) wurde durch Röntgenstrukturanalyse bestimmt. Ein viergliedriger LiNPN-Ring bildet die zentrale Einheit des monomeren Moleküls. YbI2 reagiert mit zwei Äquivalenten Li[Ph2P(NSiMe3)2] (1) zum neuartigen Ytterbium(II)diiminophosphinat [Ph2P(NSiMe3)2]2Yb(THF)2 (3). Die analoge Reaktion von 1 mit SmI2 liefert das Samarium(III)derivat [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2 (4), dessen Struktur ebenfalls röntgenographisch bestimmt wurde. Abstract: The molecular structure of Li[Ph2P(NSiMe3)2](THF)2 (2) has been determined by an X-ray diffraction study. A four-membered LiNPN ring forms the central unit of the monomeric molecule. YbI2 reacts with two equivalents of Li[Ph2P(NSiMe3)2] (1) to give the novel ytterbium(II)diiminophosphinate [Ph2P(NSiMe3)2]2Yb(THF)2 (3). A similar reaction of 1 with SmI2 affords the samarium(III) derivative [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2 (4) whose structure has also been determined by an X-ray diffraction study."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(91)86331-J"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3325"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91702"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Diiminophosphinate des Lithiums, Samariums und Ytterbiums: Molekülstrukturen von Li[Ph2P(NSiMe3)2](THF)2 und [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","539"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Polyhedron"],["dc.bibliographiccitation.lastpage","546"],["dc.bibliographiccitation.volume","13"],["dc.contributor.author","Edelmann, Frank T."],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Gilje, John W."],["dc.contributor.author","Jagner, Susan"],["dc.contributor.author","Håkanssons, Mikael"],["dc.date.accessioned","2009-07-03T12:01:19Z"],["dc.date.accessioned","2021-10-27T13:12:05Z"],["dc.date.available","2009-07-03T12:01:19Z"],["dc.date.available","2021-10-27T13:12:05Z"],["dc.date.issued","1994"],["dc.description.abstract","Tetracoordinate anionic neodymium(III) alkoxides and amides are obtained by adduct formation of Nd[OC(tBu)3]3 (1) and Nd[N(SiMe3)2]3 (2) with either LiCl or LiOSiMe3. The compounds (THF)3Li(μ-Cl)Nd[OC(tBu)3]3 (3), (THF)3Li(μ-Cl)Nd [N(SiMe3)2]3 (4) and [Li(THF)4][(Me3Si)2N3Nd(OSiMe3)] (5) have been characterized by single-crystal X-ray analyses."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/S0277-5387(00)84729-4"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3402"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91657"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Lanthanide alkoxides—III. Four-coordinate anionic neodymium(III) alkoxides and amides 1"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2527"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Acta Crystallographica / C"],["dc.bibliographiccitation.lastpage","2529"],["dc.bibliographiccitation.volume","47"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Edelmann, Frank T."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2009-06-25T06:43:02Z"],["dc.date.accessioned","2021-10-27T13:11:52Z"],["dc.date.available","2009-06-25T06:43:02Z"],["dc.date.available","2021-10-27T13:11:52Z"],["dc.date.issued","1991"],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1107/S0108270191006352"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3320"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91634"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Structure of (Rf)2(Cl)SnIV(μ2-O)SnIV(Cl)(Rf)2; Rf = 2,4,6-tris(trifluoromethyl)phenyl"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1684"],["dc.bibliographiccitation.issue","15/16"],["dc.bibliographiccitation.journal","Angewandte Chemie"],["dc.bibliographiccitation.lastpage","1687"],["dc.bibliographiccitation.volume","106"],["dc.contributor.author","Kilimann, Ulrike"],["dc.contributor.author","Herbst-Irmer, Regine"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2019-07-09T11:52:19Z"],["dc.date.available","2019-07-09T11:52:19Z"],["dc.date.issued","1994"],["dc.identifier.doi","10.1002/ange.19941061522"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3415"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/60151"],["dc.language.iso","de"],["dc.notes.intern","Merged from goescholar"],["dc.rights","Goescholar"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject.ddc","540"],["dc.title","Ein effizienter Zugang zu Organocer(IV)-Komplexen: Synthese und Struktur von Bis[1,3,6-tris(trimethylsilyl)-cyclooctatetraen]cer(IV)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]