Edelmann, Frank Thomas

[["dc.bibliographiccitation.firstpage","347"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","356"],["dc.bibliographiccitation.volume","411"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Pieper, Ursula"],["dc.contributor.author","Schmidt, Hans-Georg"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-26T07:40:17Z"],["dc.date.accessioned","2021-10-27T13:12:24Z"],["dc.date.available","2009-06-26T07:40:17Z"],["dc.date.available","2021-10-27T13:12:24Z"],["dc.date.issued","1991"],["dc.description.abstract","Das THF-Addukt des Decamethylsamarocens, Cp2 Sm(THF)2, reagiert mit Disulfiden, Diseleniden und Ditelluriden zu Organosamarium(III)komplexen, die eine Sm–E-Bindung enthalten (E = p. Se, Te). Die Molekülstrukturen der Komplexe Cp2 Sm(S2CNMe2) (1), Cp2 Sm[TeC6H2Me3-2,4,6](THF) (4) und Cp2 Sm[SeC6H2(CF3)3-2,4,6](THF) (5) wurden röntgenographisch bestimmt. Abstract: The THF adduct of decamethylsamarocene, CP2Sm(THF)2, reacts with disulfides, diselenides and ditellurides to give organosamarium(III) complexes containing a Sm---E bond (E = S, Se, Te). The molecular structures of the complexes CP2Sm(S2CNMe2) (1), Cp2Sm[TeC6H2Me3-2,4,6](THF) (4) and Cp2Sm[SeC6H2(CF3)3-2,4,6](THF) (5 have been determined by X-ray diffraction."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(91)83040-B"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3328"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91688"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Monomere Organosamarium(III) Chalkogenolate durch reduktive Spaltung von E–E-Bindungen (E = S, Se, Te)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","217"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","335"],["dc.bibliographiccitation.volume","414"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Noltemeyer, Mathias"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-25T08:13:02Z"],["dc.date.accessioned","2021-10-27T13:12:33Z"],["dc.date.available","2009-06-25T08:13:02Z"],["dc.date.available","2021-10-27T13:12:33Z"],["dc.date.issued","1991"],["dc.description.abstract","Die Molekülstruktur von Li[Ph2P(NSiMe3)2](THF)2 (2) wurde durch Röntgenstrukturanalyse bestimmt. Ein viergliedriger LiNPN-Ring bildet die zentrale Einheit des monomeren Moleküls. YbI2 reagiert mit zwei Äquivalenten Li[Ph2P(NSiMe3)2] (1) zum neuartigen Ytterbium(II)diiminophosphinat [Ph2P(NSiMe3)2]2Yb(THF)2 (3). Die analoge Reaktion von 1 mit SmI2 liefert das Samarium(III)derivat [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2 (4), dessen Struktur ebenfalls röntgenographisch bestimmt wurde. Abstract: The molecular structure of Li[Ph2P(NSiMe3)2](THF)2 (2) has been determined by an X-ray diffraction study. A four-membered LiNPN ring forms the central unit of the monomeric molecule. YbI2 reacts with two equivalents of Li[Ph2P(NSiMe3)2] (1) to give the novel ytterbium(II)diiminophosphinate [Ph2P(NSiMe3)2]2Yb(THF)2 (3). A similar reaction of 1 with SmI2 affords the samarium(III) derivative [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2 (4) whose structure has also been determined by an X-ray diffraction study."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(91)86331-J"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3325"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91702"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Diiminophosphinate des Lithiums, Samariums und Ytterbiums: Molekülstrukturen von Li[Ph2P(NSiMe3)2](THF)2 und [Ph2P(NSiMe3)2]2Sm(μ-I)2Li(THF)2"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","539"],["dc.bibliographiccitation.issue","4"],["dc.bibliographiccitation.journal","Polyhedron"],["dc.bibliographiccitation.lastpage","546"],["dc.bibliographiccitation.volume","13"],["dc.contributor.author","Edelmann, Frank T."],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Gilje, John W."],["dc.contributor.author","Jagner, Susan"],["dc.contributor.author","Håkanssons, Mikael"],["dc.date.accessioned","2009-07-03T12:01:19Z"],["dc.date.accessioned","2021-10-27T13:12:05Z"],["dc.date.available","2009-07-03T12:01:19Z"],["dc.date.available","2021-10-27T13:12:05Z"],["dc.date.issued","1994"],["dc.description.abstract","Tetracoordinate anionic neodymium(III) alkoxides and amides are obtained by adduct formation of Nd[OC(tBu)3]3 (1) and Nd[N(SiMe3)2]3 (2) with either LiCl or LiOSiMe3. The compounds (THF)3Li(μ-Cl)Nd[OC(tBu)3]3 (3), (THF)3Li(μ-Cl)Nd [N(SiMe3)2]3 (4) and [Li(THF)4][(Me3Si)2N3Nd(OSiMe3)] (5) have been characterized by single-crystal X-ray analyses."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/S0277-5387(00)84729-4"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3402"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91657"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Lanthanide alkoxides—III. Four-coordinate anionic neodymium(III) alkoxides and amides 1"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","2527"],["dc.bibliographiccitation.issue","12"],["dc.bibliographiccitation.journal","Acta Crystallographica / C"],["dc.bibliographiccitation.lastpage","2529"],["dc.bibliographiccitation.volume","47"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Edelmann, Frank T."],["dc.contributor.author","Stalke, Dietmar"],["dc.date.accessioned","2009-06-25T06:43:02Z"],["dc.date.accessioned","2021-10-27T13:11:52Z"],["dc.date.available","2009-06-25T06:43:02Z"],["dc.date.available","2021-10-27T13:11:52Z"],["dc.date.issued","1991"],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1107/S0108270191006352"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3320"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91634"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Structure of (Rf)2(Cl)SnIV(μ2-O)SnIV(Cl)(Rf)2; Rf = 2,4,6-tris(trifluoromethyl)phenyl"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","C6"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","C10"],["dc.bibliographiccitation.volume","439"],["dc.contributor.author","Gornitzka, Heinz"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Kilimann, Ulrike"],["dc.contributor.author","Edelmann, Frank T."],["dc.contributor.author","Jacob, Klaus"],["dc.contributor.author","Thiele, Karl-Heinz"],["dc.date.accessioned","2009-06-30T05:20:06Z"],["dc.date.accessioned","2021-10-27T13:11:59Z"],["dc.date.available","2009-06-30T05:20:06Z"],["dc.date.available","2021-10-27T13:11:59Z"],["dc.date.issued","1992"],["dc.description.abstract","Dark red crystalline [(FcN)2Yb(μ-Cl)2 Li(THF)2] (2) has been prepared by treatment of anhydrous YbCl3 with 2-(dimethylaminome"],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(92)80059-7"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3351"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91647"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Ferrocenliganden in der lanthanid-chemie: Chelatstabilisierung des ersten diorganyllanthanid(III)-halogenids"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","1"],["dc.bibliographiccitation.issue","1/2"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","10"],["dc.bibliographiccitation.volume","438"],["dc.contributor.author","Edelmann, Frank T."],["dc.contributor.author","Knösel, Friederich"],["dc.contributor.author","Pauer, Frank"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Bauer, Walter"],["dc.date.accessioned","2009-06-29T10:52:36Z"],["dc.date.accessioned","2021-10-27T13:11:59Z"],["dc.date.available","2009-06-29T10:52:36Z"],["dc.date.available","2021-10-27T13:11:59Z"],["dc.date.issued","1992"],["dc.description.abstract","The bidentate sulfinimidamide ligand has almost the same bulk as the cyclopentadienyl l&and. Two distinct structural types of highly reactive lithium sulfinimidamides, commonly used reagents, have been identified by X-ray diffraction and solution NMR studies. In the crystalline state the diethyl ether adducts [(Me,SiN),S(C,H,)Li],.Et,O and [(Me,S~X’BuN)S(C,H,)Lil,.EtzO adopt a twisted tricyclic structure with both a four coordinate and a three coordinate lithium atom in the same aggregate. The ‘H NMR spectra at various temperatures and the low temperature phase-sensitive 6Li, ‘H HOEp. NMR experiment show that this structure is essentially retained in solution. The smaller bulk and higher polarity of tetrahydrofuran compared with diethyl ether results in the coordination of two solvent molecules to give [(Me,S~) S(C,H,)Li.THF],, which has a centrosymmetric stair-shaped tricyclic structure consisting of three fused four-membered rings."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(92)88001-Y"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3346"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91646"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Solid-state and solution structures of three lithiumsulfinimidamides: Identification of two distinct structural types"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","315"],["dc.bibliographiccitation.issue","3"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","326"],["dc.bibliographiccitation.volume","415"],["dc.contributor.author","Recknagel, Anja"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Brooker, Sally"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-25T08:07:43Z"],["dc.date.accessioned","2021-10-27T13:11:55Z"],["dc.date.available","2009-06-25T08:07:43Z"],["dc.date.available","2021-10-27T13:11:55Z"],["dc.date.issued","1991"],["dc.description.abstract","Li[Me2Si(OtBu)(NtBu)] (1) reagiert mit YbI2 zum Ytterbium(II)alkoxysilylamid [Me2Si(OtBu(NtBu)]2Yb(THF)2 (2). Die analoge Reaktion von 1 mit SmI2 liefert das Samarium(III)derivat [Me2Si(OtBu)(NtBu)]2Sm(μ-I)2Li(THF)2 (3). Däruber hinaus wird die Darstellung von [Me2Si(O)tBu)(NtBu)] Nd (4) und [Me2Si(OtBu)(NtBu)]2Yb(μ-Cl)2Li(THF)2 (5) beschrieden. Die Molekülstrukturen von 4 und 5 wurden röntgenographisch bestimmt. Abstract: Li[Me2Si(OtBu)(NtBu)](1) reacts with YbI2 to give the ytterbium(II)alkoxysilylamide [Me2Si(OtBu)-(NtBu)]2Yb (THF)2 (2). The analogous reactio of 1 with SmI2 yields the samarium(III) derivative [Me2Si(OtBu)(NtBu)]2Sm(μ-I)2Li(THF)2 (3). Moreover, the preparation of [Me2Si(OtBu)(NtBu)]3Nd (4) and [Me2Si(OtBu)(NtBu)]2Yb(μ-Cl)2Li(THF)2 (5) is described. The molecular structures of 4 and 5 have been determined by X-ray crystallography."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(91)80131-3"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3324"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91639"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Alkoxysilylamide des Neodyms, Samariums und Ytterbiums: Viergliedrige anorganische Ringsysteme in der Lanthanidchemie"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","73"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","85"],["dc.bibliographiccitation.volume","366"],["dc.contributor.author","Scholz, Mario"],["dc.contributor.author","Roesky, Herbert W."],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Keller, Klaus"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-23T12:31:05Z"],["dc.date.accessioned","2021-10-27T13:12:33Z"],["dc.date.available","2009-06-23T12:31:05Z"],["dc.date.available","2021-10-27T13:12:33Z"],["dc.date.issued","1989"],["dc.description.abstract","Es wird über eine verbesserte Synthese von 1,3,5-Tris(trifluormethyl)benzol (1) berichtet. Ausgehend von [2,4,6-(CF3)3C6H2]Li (2) (= RFLi) sind RFPCl2 (3), RFPH2 (4) und das ungewöhnlich stabile Diphosphen RFP=PRF (5) leicht zugänglich. Die Umsetzung von Me2S(O)=NPCl2 (6) mit 4 liefert das gemischt substituierte Cyclotetraphosphan [Me2S(O)=N]2(RF)2P4 (7), das durch eine Röntgenstrukturanalyse charakterisiert wurde. (Raumgruppe: P21/n, Gitterkonstanten: a 1569.7(2), b 2293.6(3), c 1823.1(2) pm, β 94.94(1)°). Das intermediär auftretende unsymmetrisch substituierte Diphosphen [Me2S(O)=N]P=PRF läßt sich als Addukt mit [Pt(PPh3)2] abfangen. Weiterhin wird die Synthese von (RF)2AsF (9) und (RF)2AsH (10) beschrieben. Abstract: An improved synthesis of 1,3,5-tris(trifluoromethyl)benzene (1) is reported. RFPCl2 (3), RFPH2 (4) and the unusually stable diphosphene RFP=PRF (5) are readily accessible starting from [2,4,6-(CF3)3C6H2]Li (2) (= RFLi). Treatment of Me2S(O)=NPCl2 (6) with 4 yields the cyclotetraphosphine derivative [Me2S(O)=N]2(RF)2P4 (7) which was characterized by an X-ray structure determination (space group: P21/n with a 1569.7(2), b 2293.6(3), c 1823.1(2) pm, β 94.94(1)°). The unsymmetrically substituted diphosphene intermediate [Me2S(O)=N]P=PRF can be trapped as an adduct with [Pt(PPh3)2]. The syntheses of (RF)2AsF (9) and (RF)2AsH (10) are also described."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(89)87317-6"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3287"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91701"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Der 2,4,6-Tris(trifluormethyl)phenylsubstituent; Beispiele für elektronisch und sterisch stabilisierte niederkoordinierte Hauptgruppenelemente"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","C21"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","C25"],["dc.bibliographiccitation.volume","431"],["dc.contributor.author","Steiner, Alexander"],["dc.contributor.author","Gornitzka, Heinz"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-30T05:15:03Z"],["dc.date.accessioned","2021-10-27T13:12:23Z"],["dc.date.available","2009-06-30T05:15:03Z"],["dc.date.available","2021-10-27T13:12:23Z"],["dc.date.issued","1992"],["dc.description.abstract","The molecular structure of di-μ-carbonyl-bis[carbonyl(η5-pentamethylcyclopentadienyl)ruthenium] (Ru---Ru) has been determined by a single-crystal X-ray diffraction study (monoclinic, space group P21/n,a = 979.90(9), b = 831.91(7), c = 1427.75(12) pm, β = 100.026(9)°, R = 0.018). In the solid state the complex exists solely as the trans-carbonyl bridged isomer. The Ru---Ru bond length is 275.2(1) pm."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(92)83295-S"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3350"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91687"],["dc.language.iso","en"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Struktur von [CPRu(C0)2]2 (Cp = η5-pentamethylcyclopentadienyl)"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]

[["dc.bibliographiccitation.firstpage","C15"],["dc.bibliographiccitation.issue","1"],["dc.bibliographiccitation.journal","Journal of Organometallic Chemistry"],["dc.bibliographiccitation.lastpage","C5"],["dc.bibliographiccitation.volume","431"],["dc.contributor.author","Stalke, Dietmar"],["dc.contributor.author","Wedler, Michael"],["dc.contributor.author","Edelmann, Frank T."],["dc.date.accessioned","2009-06-30T05:25:07Z"],["dc.date.accessioned","2021-10-27T13:12:00Z"],["dc.date.available","2009-06-30T05:25:07Z"],["dc.date.available","2021-10-27T13:12:00Z"],["dc.date.issued","1992"],["dc.description.abstract","The molecular structures of two N-silylated alkali metal benzamidinates, [MeC6H4C(NSiMe3)2-Li(THF)]2 1 and [PhC(NSiMe3)2Na(Et2O)]2·Et2O 2, have been determined by low temperature X-ray diffraction studies. Both compounds are dimeric in the solid state but the molecular structures are strongly influenced by the alkali metal used. The Na---Na distance in 2 is unusually short (274.1 pm). The preparation of K[PhC(NSiMe3)2] (3) is also described."],["dc.format.mimetype","application/pdf"],["dc.identifier.doi","10.1016/0022-328X(92)83291-O"],["dc.identifier.purl","https://resolver.sub.uni-goettingen.de/purl?goescholar/3352"],["dc.identifier.uri","https://resolver.sub.uni-goettingen.de/purl?gro-2/91649"],["dc.language.iso","de"],["dc.notes.intern","Migrated from goescholar"],["dc.relation.orgunit","Fakultät für Chemie"],["dc.rights","Goescholar"],["dc.rights.access","openAccess"],["dc.rights.uri","https://goescholar.uni-goettingen.de/licenses"],["dc.subject","anorganische Chemie"],["dc.subject.ddc","540"],["dc.title","Dimere Alkalimetallbenzamidinate: Einfluß des Metallions auf die Struktur"],["dc.type","journal_article"],["dc.type.internalPublication","yes"],["dc.type.peerReviewed","yes"],["dc.type.version","published_version"],["dspace.entity.type","Publication"]]